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Acta Cryst. (2013). C69, 1116-1119  [ doi:10.1107/S0108270113023524 ]

Bis{[mu]-2,2'-[(butane-2,3-diyl­idene)bis­(aza­nylyl­idene)]di­benzene­thiol­ato}dizinc(II)-dimethyl sulfoxide-methanol (2/0.18/0.82)

R. L. Luck, T. A. Olds and M. Zeller

Synopsis: The title compound has a metallic cluster structure with a rhomboidal Zn2S2 arrangement. Each ZnII atom is five-coordinated and exhibits distorted trigonal bipyramidal geometry. The structure may be of inter­est with respect to zinc-thiol­ate bonds, the coordination chemistry of Schiff bases and the folding of proteins.

Formula: [Zn2(C16H14N2S2)2]2·0.18C2H6OS·0.82CH4O


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