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Acta Cryst. (2013). C69, 1104-1107  [ doi:10.1107/S0108270113023263 ]

Chlorido­bis­[2-(di­phenyl­phosphanyl)ethanamine-[kappa]2P,N](tri­phenylphos­phane-[kappa]P)ruthenium(II) chloride toluene monosolvate

R. J. Brown, D. S. Amenta, J. W. Gilje and G. P. A. Yap

Synopsis: The chiral stereochemistry and the mer-P and cis-N coordination of the chlorido­bis­[2-(di­phenyl­phosphanyl)ethanamine-[kappa]2P,N](tri­phenyl­phosphane-[kappa]P)ruthenium(II) cation, [RuCl(PPh3){Ph2P(CH2)2NH2-[kappa]2P,N}2]+, is unique in ruthenium-amino­phosphane chemistry.

Formula: [RuCl(C18H15P)(C14H16NP)2]Cl·C7H8


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