Acta Crystallographica Section C

Crystal Structure Communications

Volume 69, Part 12 (December 2013)

metal-organic compounds

Acta Cryst. (2013). C69, 1482-1484    [ doi:10.1107/S0108270113029776 ]


J. Kohl and D. Wiedemann

Abstract: The distorted octa­hedral title complex, [VV(C3H7O)(C3H8O)2F2O], was synthesized via ligand exchange at [VVO(OiPr)3] with aqueous hydrogen fluoride in propan-2-ol and crystallized from (D)chloro­form at 238 K after a few weeks. Crystal structure determination shows two C1-symmetric moieties to be present in the asymmetric unit, forming infinite chains along [100] via hydrogen bonds. The compound provides the first crystal structure containing the [VF2O(OiPr)] motif.

CCDC reference: 969480

Formula: [V(C3H7O)(C3H8O)2F2O]

Keywords: crystal structure; vanadium complexes; alcoholates; hydrogen fluoride; hydrogen bonds.

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MDL mol file (4.1 kbytes)
[ doi:10.1107/S0108270113029776/eg3138Isup3.mol ]
Supplementary material


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