Acta Cryst. (2013). C69, 1482-1484 [ doi:10.1107/S0108270113029776 ]
Abstract: The distorted octahedral title complex, [VV(C3H7O)(C3H8O)2F2O], was synthesized via ligand exchange at [VVO(OiPr)3] with aqueous hydrogen fluoride in propan-2-ol and crystallized from (D)chloroform at 238 K after a few weeks. Crystal structure determination shows two C1-symmetric moieties to be present in the asymmetric unit, forming infinite chains along  via hydrogen bonds. The compound provides the first crystal structure containing the [VF2O(OiPr)] motif.
CCDC reference: 969480
Keywords: crystal structure; vanadium complexes; alcoholates; hydrogen fluoride; hydrogen bonds.
MDL mol file (4.1 kbytes)
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