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Acta Cryst. (2013). C69, 1467-1471  [ doi:10.1107/S0108270113027947 ]

Distorted octa­hedral environments in tri­carbonyl­rhenium(I) complexes of 5-[2-(2,4,6-tri­methyl­phenyl)diazen-1-yl]quinolin-8-olate and 5,7-bis­[2-(2-methyl­phenyl)diazen-1-yl]quinolin-8-olate

M. Schutte-Smith, T. J. Muller, H. G. Visser and A. Roodt

Synopsis: The ReI centres of the tri­carbonyl­rhenium(I) complexes of 5-[2-(2,4,6-tri­methyl­phenyl)diazen-1-yl]quinolin-8-olate and 5,7-bis­[2-(2-methyl­phenyl)diazen-1-yl]quinolin-8-olate are facially surrounded by the ligands in a slightly distorted octa­hedral environment. Both structures exhibit inter­molecular C-H...O inter­actions.

Formula: [Re(C23H21N4O)(CO)3] and [Re(C28H23N6O)(CO)3]


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