Acta Cryst. (2014). C70, 194-197 [ doi:10.1107/S2053229614000047 ]
Synopsis: The title novel noncentrosymmetric metal-organic framework was prepared solvothermally using the tetradentate linker tetrakis[(imidazol-1-yl)methyl]methane (tiym) in the presence of zinc nitrate under acidic conditions. With its four peripheral imidazole N atoms, the tiym linkers are bridged by four [ZnCl2] subunits to generate a three-dimensional diamond topological framework.
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