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Acta Cryst. (2014). C70, 194-197  [ doi:10.1107/S2053229614000047 ]

Poly[tetra­chlorido­{[mu]4-tetra­kis­[(imidazol-1-yl)methyl]methane-[kappa]4N3:N3':N3'':N3'''}dizinc(II)] exhibiting a three-dimensional diamond topology

J. Su, L.-D. Yao, J. Zhang, J.-Y. Wu and Y.-P. Tian

Synopsis: The title novel noncentrosymmetric metal-organic framework was prepared solvothermally using the tetra­dentate linker tetra­kis­[(imidazol-1-yl)methyl]methane (tiym) in the presence of zinc nitrate under acidic conditions. With its four peripheral imidazole N atoms, the tiym linkers are bridged by four [ZnCl2] subunits to generate a three-dimensional diamond topological framework.

Formula: [Zn2Cl4(C17H20N8)]


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