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Acta Cryst. (2014). C70, 292-296  [ doi:10.1107/S205322961400312X ]

A one-dimensional silver(I) coordination polymer based on an asymmetric flexible N-donor carboxyl­ate ligand: catena-poly[([mu]3-4-{[(1-phenyl-1H-tetra­zol-5-yl)sulfanyl]­methyl}­benzo­ato-[kappa]3O:O':N4)silver(I)]

H.-N. Zhang, Q.-F. Zhang, J.-J. Wang, A.-J. Geng and C. Zhang

Synopsis: A one-dimensional silver(I) coordination polymer based on an asymmetric [mu]3-bridging flexible carboxyl­ate ligand is reported. The structure displays intrachain [pi]-[pi] contacts and in addition forms a three-dimensional supramolecular framework. Thermogravimetric analysis and fluorescence spectroscopy reveal good thermal stability and a strong green luminescence at room temperature.

Formula: [Ag(C15H11N4O2S)]


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