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Acta Cryst. (2014). C70, 312-314  [ doi:10.1107/S2053229614003349 ]

Masking of Lewis acidity trends in the solid-state structures of tri­chlorido- and tri­bromido­(2,2':6',2''-terpyridine-[kappa]3N,N',N'')gallium(III)

I. V. Kazakov, M. Bodensteiner and A. Y. Timoshkin

Synopsis: The monoclinic P21/n crystal structure of complexes of GaCl3 and GaBr3 with 2,2':6',2''-terpyridine (terpy) were determined using single-crystal X-ray diffraction. It is shown that the Ga-N distances in GaCl3(terpy) and GaBr3(terpy) are similar within experimental error.

Formula: [GaCl3(C15H11N3)] and [GaBr3(C15H11N3)]

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