[HTML version][PDF version][CIF][3d view][Structure Factors][Issue contents]  [Buy article online]

[Contents scheme]

Acta Cryst. (2014). C70, 312-314  [ doi:10.1107/S2053229614003349 ]

Masking of Lewis acidity trends in the solid-state structures of tri­chlorido- and tri­bromido­(2,2':6',2''-terpyridine-[kappa]3N,N',N'')gallium(III)

I. V. Kazakov, M. Bodensteiner and A. Y. Timoshkin

Synopsis: The monoclinic P21/n crystal structure of complexes of GaCl3 and GaBr3 with 2,2':6',2''-terpyridine (terpy) were determined using single-crystal X-ray diffraction. It is shown that the Ga-N distances in GaCl3(terpy) and GaBr3(terpy) are similar within experimental error.

Formula: [GaCl3(C15H11N3)] and [GaBr3(C15H11N3)]


Copyright © International Union of Crystallography
IUCr Webmaster