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Acta Cryst. (2014). C70, 267-271  [ doi:10.1107/S2053229614002277 ]

A new one-dimensional nickel metal-organic framework: catena-poly[[[di­aqua­bis­(4-{[(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]meth­yl}benzoato-[kappa]O)nickel(II)]-[mu]-4,4'-bi­pyridine-[kappa]2N:N'] monohydrate]

A. Geng, Q. Zhang, J. Wang, H. Zhang and D. Sun

Synopsis: A one-dimensional nickel coordination polymer incorporating 4-{[(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]meth­yl}benzoate and 4,4'-bi­pyridine ligands has an Ni...Ni separation of 11.361 (1) Å. The fishbone-like chains are linked by O-H...O, O-H...N and C-H...O hydrogen bonds and [pi]-[pi] stacking inter­actions to form a three-dimensional supra­molecular architecture.

Formula: [Ni(C15H11N4O2S)2(C10H8N2)(H2O)2]·H2O


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