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Acta Cryst. (2014). C70, 277-280  [ doi:10.1107/S2053229614001077 ]

A three-dimensional ZnII coordination framework: poly[[[mu]2-(E)-1,2-bis(pyri­din-4-yl)ethene][[mu]4-(E)-2,2'-(diazene-1,2-diyl)dibenzoato][[mu]2-(E)-2,2'-(di­azene-1,2-di­yl)dibenzoato]dizinc(II)]

C.-X. Yu, F. Zhao, M. Zhou, D.-F. Zhi and L.-L. Liu

Synopsis: The title zinc(II) complex, prepared by the reaction of Zn(OAc)2·2H2O with 2,2'-(diazene-1,2-diyl)di­benzoic acid and 1,2-bis­(pyridin-4-yl)ethene in MeOH/H2O at 393 K, possesses a three-dimensional framework with a 4664 topology. Powder X-ray diffraction and solid-state photoluminescent properties were also measured.

Formula: [Zn(C14H8N2O4)2(C12H10N2)]


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