Acta Crystallographica Section C

Structural Chemistry

Volume 70, Part 4 (April 2014)


metal-organic compounds



qs3037 scheme

Acta Cryst. (2014). C70, 375-378    [ doi:10.1107/S2053229614005762 ]

Synthesis, crystal structures and characterizations of two homochiral coordination polymers based on a chiral reduced Schiff base ligand

S.-M. Ying, X.-H. Huang, W.-K. Luo and Y.-C. Xiao

Abstract: Two homochiral coordination polymers based on a chiral reduced Schiff base ligand, namely poly[([mu]5-4-{[(NR,1S)-(1-carboxyl­ato-2-phenyl­ethyl)amino]­methyl}benzoato)zinc(II)], [Zn(C17H15NO4)]n, (1), and poly[([mu]5-4-{[(NR,1S)-(1-car­boxyl­­ato-2-phenyl­ethyl)amino]­methyl}benzoato)cobalt(II)], [Co(C17H15NO4)]n, (2), have been obtained by hydro­thermal methods and studied by single-crystal X-ray diffraction, elemental analyses, powder X-ray diffraction, thermogravimetric analysis, IR spectroscopy and fluorescence spectroscopy. Compounds (1) and (2) are isostructural and crystallize in the P212121 space group. Both display a three-dimensional network structure with a one-dimensional channel, with the benzyl group of the ligand directed towards the channel. An investigation of photoluminescence properties shows that compound (1) displays a strong emission in the purple region.

CCDC references: 919642 and 918217

Formula: [Zn(C17H15NO4)] and [Co(C17H15NO4)]

Keywords: crystal structure; homochiral coordination polymers; 4-{[(1-carboxyl­ato-2-phenyl­ethyl)amino]­methyl}benzoate; zinc complex; cobalt complex; photoluminescence properties.


hkldisplay filedownload file

Structure factor file (CIF format) (142.4 kbytes)
[ doi:10.1107/S2053229614005762/qs30371sup2.hkl ]
Contains datablock 1


hkldisplay filedownload file

Structure factor file (CIF format) (160.7 kbytes)
[ doi:10.1107/S2053229614005762/qs30372sup3.hkl ]
Contains datablock 2


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