forthcoming articles

The following articles are a selection of those recently accepted for publication in Acta Crystallographica Section C: Structural Chemistry.

See also Forthcoming articles in all IUCr journals.

Accepted 5 February 2016

Conformational studies on heteroleptic tri­fluoro­methyl-substituted phenyl­boranes

The mol­ecular structures of tri­fluoro­methyl-substituted tri­phenyl­boranes are analysed for systematic trends and compared with structure retrieved from the Cambridge Structural Database.

Accepted 21 January 2016

An unusual bis-heteroscorpionate complex with anomalous ligands: [tris­(3,4-di­bromo-5-phenyl­pyrazol­yl)hydro­borato][hydro­tris­(3-neo­pentyl­pyrazol­yl)borato]nickel(II)

Two atypical tris­pyrazolylborate ligands were selected to make a heteroscorpionate complex in order to showcase the flexibility of steric and electronic effects easily afforded by this class of facial tridentate ligands.

Accepted 10 December 2015

Comparison of thallium(I) complexes with mesityl-substituted tris­(pyrazolyl)hydroborate ligands, [Tl{HB(3-Ms-5-Mepz)3}] and [Tl{HB(3-Ms-5-Mepz)2(3-Me-5-Mspz)}]

The structures of thallium(I) complexes with two different mesityl-substituted ligands, i.e. tris(3-mesityl-5-methylpyrazol-1-yl)hydroborate and bis(3-mesityl-5-methylpyrazol-1-yl)(3-methyl-5-mesitylpyrazol-1-yl)hydroborate, are compared. The shape of the former thallium(I) complex can be considered as a vase and the latter as a baseball glove.

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