Figure 6
Time-resolved difference absorption spectra of crystalline slurry at 273 K (a) and 303 K (c) (black, earliest time point; blue, last time point). (b, d) Right singular vectors (rSVs) from SVD analysis of the difference spectra. Solid lines, global fit by sums of three exponentials identifying three processes. Processes 1-3 are labeled with their respective relaxation times and are marked with thin vertical lines; relaxation times from crystallography are shown in red brackets (n.o., not observed). The gray line in (d) is the fit of the final relaxation with only one exponential.  [article HTML]