A donor-acceptor adduct: sterically encumbered ter­phenyl di­chloro[2,6-bis(2,4,6-triiso­propyl­phenyl)phenyl]di­chloro­(pyridine)­gallium benzene hemi­solvate

The molecular structure of the benzene-solvated donor-acceptor complex di­chloro­[2,2'',4,4'',6,6''-hexaiso­propyl-1,1':3',1''-ter­phenyl-C^2'](pyridine)­gallium benzene hemi­solvate, henceforth known as 2,6-Trip₂-C₆H₃GaCl₂-pyridine benzene hemi­solvate or (1) + 0.5 C₆H₆ (Trip = 2,4,6-triiso­propyl­phenyl), [GaCl₂(C₃₆H₄₉)(C₅H₅N)]·0.5C₆H₆, has been determined. The asymmetric unit consists of four independent mol­ecules of (1) and two benzene solvent mol­ecules. The Ga-C, Ga-N and Ga-Cl bond lengths span the ranges 1.979 (7)-1.983 (2), 2.028 (6)-2.040 (7) and 2.179 (2)-2.212 (2) Å, respectively. All independent mol­ecules of (1) have essentially the same geometry with slight differences in the orientation of the peripheral phenyl rings and iso­propyl groups in the ter­phenyl moiety.

Key indicators

• Single-crystal X-ray study
• T = 90 K
• Mean [sigma](C-C) = 0.011 Å
• R factor = 0.078
• wR factor = 0.228
• Data-to-parameter ratio = 16.1

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



RINTA_01  Alert C The value of Rint is greater than 0.10
          Rint given   0.137

PLAT_213  Alert C Atom  C15    has ADP max/min ratio ...........       3.20

PLAT_213  Alert C Atom  C73    has ADP max/min ratio ...........       3.50

PLAT_213  Alert C Atom  C101   has ADP max/min ratio ...........       3.10


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 4 Alert Level C = Please check

---

S1. Comment

The addition of pyridine to 2,6-Trip₂—C₆H₃GaCl₂ (Trip = 2,4,6-triisopropylphenyl) in benzene results in the adduct 2,6-Trip₂—C₆H₃GaCl₂-pyridine, (1). (1) is an air-sensitive pale yellow high-melting solid that crystallizes in the monoclinic system with four crystallographically independent, chemically identical and geometrically similar adducts and two benzene solvent molecules in the asymmetric unit [descriptor (I) represents the full benzene-solvated title compound]. One of the independent molecules of the adduct is shown in Fig. 1.

The average Ga—C and Ga—Cl bonds [1.985 (7) and 2.195 (2) Å, respectively; Table 1] are slightly longer than analogous bonds in the base-free chloride 2,6-Trip₂—C₆H₃GaCl₂ [Twamley & Power, 1999; 1.930 (8) Å, and 2.124 (3) and 2.113 (4) Å, respectively] obviously due to the electronic effect of the pyridine donation. The Ga—N distances in (1) [2.028 (6)–2.040 (7) Å] are in good agreement with the corresponding bonds in previously reported gallium chloride complexes that have coordination Ga—N bonds in chelate cycles [Ga—N 2.034 (8)–2.071 (2) Å; Al-Juaid et al., 1999; Jutzi et al., 1999; Isom et al., 1995]. The torsion angles about the four rotatable bonds in each of the independent molecules [Ga—N, Ga—C_ipso, two ortho-C—C (ipso pendant phenyl group); see Table 1] show that all four molecules have essentially similar geometry. Although these core torsion angles are similar, the pendant phenyl and isopropyl-group orientations are slightly different from molecule to molecule. This difference may be seen in Fig. 2, which shows the superposition of two molecules in the case of the the best and worst pairwise overlap (in case of Ga2/Ga1 and Ga3/Ga2 pairs of molecules) of the central aromatic terphenyl core and the GaCl₂^.pyridine moiety. This is also reflected in the weighted r.m.s. fit values as calculated by the OFIT procedure (Sheldrick, 1998b; Table 2), which performs the best possible fit of the similar molecular fragments.

The crystal packing (Fig. 3) in the structure of (1) features pairs of stacks of the adduct molecules running along the [010] direction with the GaCl₂^.pyridine moieties facing each other within each pair of stacks. The benzene solvent molecules fill in the voids between the stack pairs. There are no specific intermolecular interactions between the molecules or the solvent.

S2. Experimental

Dry pyridine (0.22 ml, 2.60 mmol) was added via syringe to a suspension of 2,6-Trip₂—C₆H₃GaCl₂ (Twamley & Power, 1999) in benzene (50 ml). The mixture was stirred overnight and then the solvent concentrated under reduced pressure to ca 10 ml. The suspension was warmed to redissolve precipitates and allowed to cool slowly to room temperature under an N₂ gas flow. The product crystallized after ca 10 min as pale yellow needles. Yield 1.21 g, 62%, m.p. 477–478 K. ¹H NMR (C₆D₆, 300 MHz): δ 1.20 [d, 12H, o-CH(CH₃)₂, ³J_HH = 6.9 Hz], 1.24 [d, 12H, o-CH(CH₃)₂, ³J_HH = 6.9 Hz], 1.35 [d, 12H, p-CH(CH₃)₂, ³J_HH = 6.6 Hz], 2.85 (sept., 3H, o,p-CH, ³J_HH = 6.9 Hz), 6.97 (t, 1H, p-C₆H₃, ³J_HH = 6.6 Hz), 7.07, (d, 2H, m-C₆H₃, ³J_HH = 7.35 Hz), 7.23 (s, 4H, m-Trip). ¹³C {¹H} NMR (C₆D₆, 75 MHz): δ 24.3, 24.5, 24.9, 31.6, 34.9, 121.1 (m-Trip), 126.4 (p-C₆H₃), 130.5 (m-C₆H₃), 135.1 (o-C₆H₃), 135.7 (ipso C), 140.8 (i-Trip), 146.6 (o-Trip), 148.9 (p-Trip).

S3. Refinement

There is a high positive residual density of 1.02 e %A^-3 near the Ga4 center. Several of the C atoms (C16, C39, C48, C125, C125 and C133) were restrained during the refinement to approximate isotropic behaviour using the ISOR SHELXTL command.

Computing details

Data collection: SMART (Bruker, 1997); cell refinement: SMART; data reduction: SAINT-Plus (Bruker, 1998); program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures

	Fig. 1. An ORTEP diagram of one of the independent molecules of (1) with 30% probability displacement displacement ellipsoids. H atoms have been omitted for clarity.
	Fig. 2. OFIT-generated superimposition diagram of (a) the best fit, Ga2 and Ga1 molecules and (b) the worst fit, Ga3 and Ga2 molecules. H atoms have been omitted. The numbering scheme is given for only the first molecule in each pair. Deviations from overlap are represented by dashed lines.
	Fig. 3. Packing diagram of (1) viewed down [010]. Isopropyl groups and H atoms have been omitted for clarity.

(1)

Crystal data

[GaCl2(C36H49)(C5H5N)]·0.5C6H6	F(000) = 6288
Mr = 740.52	Dx = 1.211 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
a = 24.334 (2) Å	Cell parameters from 6390 reflections
b = 20.954 (2) Å	θ = 2.4–30.9°
c = 32.936 (3) Å	µ = 0.84 mm^−1
β = 104.706 (2)°	T = 90 K
V = 16244 (3) Å^3	Needle, pale yellow
Z = 16	0.52 × 0.25 × 0.07 mm

Data collection

Bruker SMART 1000 diffractometer	28585 independent reflections
Radiation source: normal-focus sealed tube	13485 reflections with I > 2σ(I)'
Graphite monochromator	Rint = 0.137
ω scans	θmax = 25.0°, θmin = 0.9°
Absorption correction: empirical (using intensity measurements) (SADABS; Sheldrick, 1998a)	h = −28→27
Tmin = 0.670, Tmax = 0.944	k = 0→24
163360 measured reflections	l = 0→39

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full with fixed elements per cycle	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.078	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.228	H-atom parameters constrained
S = 1.13	w = 1/[σ^2(Fo^2) + (0.0626P)^2 + 88.0236P] where P = (Fo^2 + 2Fc^2)/3
28585 reflections	(Δ/σ)max = 0.001
1777 parameters	Δρmax = 1.02 e Å^−3
36 restraints	Δρmin = −1.38 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ga1	0.17152 (3)	0.72365 (4)	0.90537 (2)	0.01305 (19)
Cl1	0.26354 (8)	0.73792 (10)	0.92180 (6)	0.0212 (4)
Cl2	0.13179 (9)	0.81774 (9)	0.90889 (6)	0.0217 (5)
N1	0.1665 (3)	0.6901 (3)	0.96245 (19)	0.0214 (16)
C1	0.1330 (3)	0.6775 (3)	0.8535 (2)	0.0112 (16)
C2	0.1568 (3)	0.6799 (3)	0.8178 (2)	0.0134 (16)
C3	0.1263 (3)	0.6531 (3)	0.7793 (2)	0.0145 (17)
H3A	0.1421	0.6545	0.7557	0.017*
C4	0.0737 (3)	0.6248 (4)	0.7755 (2)	0.0190 (18)
H4A	0.0530	0.6081	0.7492	0.023*
C5	0.0516 (3)	0.6212 (3)	0.8101 (2)	0.0143 (17)
H5A	0.0163	0.6004	0.8079	0.017*
C6	0.0809 (3)	0.6478 (3)	0.8488 (2)	0.0094 (15)
C7	0.0523 (3)	0.6379 (3)	0.8841 (2)	0.0138 (17)
C8	0.0679 (3)	0.5846 (4)	0.9107 (2)	0.0154 (17)
C9	0.0360 (3)	0.5708 (4)	0.9390 (2)	0.0172 (18)
H9A	0.0461	0.5348	0.9568	0.021*
C10	−0.0106 (3)	0.6081 (4)	0.9423 (2)	0.0182 (18)
C11	−0.0243 (3)	0.6605 (4)	0.9167 (2)	0.0174 (17)
H11A	−0.0554	0.6866	0.9188	0.021*
C12	0.0068 (3)	0.6765 (3)	0.8872 (2)	0.0127 (16)
C13	0.2154 (3)	0.7023 (3)	0.8209 (2)	0.0097 (15)
C14	0.2272 (3)	0.7677 (4)	0.8153 (2)	0.0158 (17)
C15	0.2831 (3)	0.7859 (3)	0.8191 (2)	0.0143 (17)
H15A	0.2911	0.8295	0.8150	0.017*
C16	0.3279 (3)	0.7426 (4)	0.8285 (2)	0.0157 (16)
C17	0.3148 (3)	0.6788 (4)	0.8321 (2)	0.0176 (18)
H17A	0.3448	0.6485	0.8374	0.021*
C18	0.2599 (3)	0.6572 (4)	0.8283 (2)	0.0142 (17)
C19	0.2479 (3)	0.5867 (4)	0.8310 (2)	0.0163 (17)
H19A	0.2066	0.5815	0.8297	0.020*
C20	0.2602 (4)	0.5511 (4)	0.7930 (2)	0.026 (2)
H20A	0.2362	0.5686	0.7669	0.039*
H20B	0.2519	0.5056	0.7948	0.039*
H20C	0.3003	0.5566	0.7932	0.039*
C21	0.2824 (4)	0.5574 (4)	0.8723 (2)	0.0232 (19)
H21A	0.2741	0.5803	0.8960	0.035*
H21B	0.3230	0.5608	0.8738	0.035*
H21C	0.2721	0.5123	0.8735	0.035*
C22	0.3879 (3)	0.7674 (4)	0.8361 (2)	0.0220 (18)
H22A	0.3875	0.8040	0.8165	0.026*
C23	0.4091 (4)	0.7924 (4)	0.8810 (3)	0.029 (2)
H23A	0.3849	0.8278	0.8854	0.044*
H23B	0.4483	0.8073	0.8855	0.044*
H23C	0.4076	0.7580	0.9008	0.044*
C24	0.4299 (4)	0.7180 (5)	0.8282 (3)	0.038 (2)
H24A	0.4152	0.6991	0.8003	0.057*
H24B	0.4349	0.6844	0.8496	0.057*
H24C	0.4665	0.7385	0.8297	0.057*
C25	0.1792 (3)	0.8157 (3)	0.8037 (2)	0.0167 (17)
H25A	0.1464	0.7986	0.8135	0.020*
C26	0.1952 (4)	0.8806 (4)	0.8246 (3)	0.026 (2)
H26A	0.2097	0.8748	0.8550	0.039*
H26B	0.1615	0.9082	0.8190	0.039*
H26C	0.2246	0.9005	0.8133	0.039*
C27	0.1600 (4)	0.8229 (4)	0.7558 (2)	0.028 (2)
H27A	0.1496	0.7810	0.7430	0.042*
H27B	0.1910	0.8411	0.7455	0.042*
H27C	0.1269	0.8514	0.7484	0.042*
C28	−0.0125 (3)	0.7337 (4)	0.8579 (2)	0.0159 (17)
H28A	0.0184	0.7430	0.8438	0.019*
C29	−0.0223 (4)	0.7942 (4)	0.8810 (2)	0.026 (2)
H29A	−0.0322	0.8295	0.8609	0.039*
H29B	0.0124	0.8049	0.9025	0.039*
H29C	−0.0535	0.7871	0.8944	0.039*
C30	−0.0657 (3)	0.7176 (4)	0.8239 (2)	0.0230 (19)
H30A	−0.0601	0.6771	0.8106	0.035*
H30B	−0.0732	0.7515	0.8028	0.035*
H30C	−0.0980	0.7137	0.8364	0.035*
C31	−0.0465 (3)	0.5868 (4)	0.9719 (2)	0.0214 (19)
H31A	−0.0199	0.5733	0.9990	0.026*
C32	−0.0818 (4)	0.5282 (4)	0.9531 (2)	0.030 (2)
H32A	−0.0570	0.4966	0.9448	0.045*
H32B	−0.1115	0.5412	0.9284	0.045*
H32C	−0.0993	0.5095	0.9740	0.045*
C33	−0.0847 (4)	0.6387 (5)	0.9820 (3)	0.037 (2)
H33A	−0.0633	0.6787	0.9881	0.055*
H33B	−0.0981	0.6260	1.0064	0.055*
H33C	−0.1174	0.6449	0.9578	0.055*
C34	0.1158 (3)	0.5404 (4)	0.9074 (2)	0.0189 (18)
H34A	0.1436	0.5663	0.8966	0.023*
C35	0.0936 (4)	0.4871 (4)	0.8752 (3)	0.031 (2)
H35A	0.1255	0.4607	0.8721	0.047*
H35B	0.0748	0.5062	0.8481	0.047*
H35C	0.0664	0.4606	0.8850	0.047*
C36	0.1482 (3)	0.5102 (4)	0.9487 (2)	0.0221 (19)
H36A	0.1575	0.5431	0.9705	0.033*
H36B	0.1833	0.4908	0.9451	0.033*
H36C	0.1245	0.4774	0.9570	0.033*
C37	0.1194 (4)	0.6985 (4)	0.9760 (2)	0.0233 (19)
H37A	0.0874	0.7186	0.9579	0.028*
C38	0.1158 (4)	0.6791 (5)	1.0154 (3)	0.042 (3)
H38A	0.0817	0.6854	1.0240	0.051*
C39	0.1624 (4)	0.6504 (4)	1.0421 (3)	0.035 (2)
H39A	0.1607	0.6365	1.0692	0.043*
C40	0.2115 (4)	0.6421 (4)	1.0289 (2)	0.032 (2)
H40A	0.2443	0.6233	1.0469	0.038*
C41	0.2114 (4)	0.6621 (4)	0.9887 (2)	0.024 (2)
H41A	0.2448	0.6556	0.9792	0.028*
Ga2	0.32667 (4)	0.53078 (4)	0.59037 (2)	0.0133 (2)
Cl3	0.36810 (8)	0.43844 (9)	0.58572 (6)	0.0221 (5)
Cl4	0.23515 (8)	0.51398 (9)	0.57570 (6)	0.0205 (4)
N2	0.3283 (3)	0.5659 (3)	0.53311 (17)	0.0140 (14)
C43	0.3657 (3)	0.5774 (4)	0.6420 (2)	0.0125 (16)
C44	0.3430 (3)	0.5758 (3)	0.6779 (2)	0.0121 (16)
C45	0.3740 (3)	0.6012 (4)	0.7156 (2)	0.0164 (17)
H45A	0.3583	0.6001	0.7392	0.020*
C46	0.4268 (3)	0.6277 (4)	0.7198 (2)	0.0161 (17)
H46A	0.4480	0.6433	0.7462	0.019*
C47	0.4485 (3)	0.6315 (3)	0.6850 (2)	0.0151 (17)
H47A	0.4836	0.6526	0.6872	0.018*
C48	0.4191 (3)	0.6044 (3)	0.6461 (2)	0.0094 (15)
C49	0.4478 (3)	0.6129 (3)	0.6108 (2)	0.0116 (16)
C50	0.4330 (3)	0.6653 (3)	0.5833 (2)	0.0138 (17)
C51	0.4659 (3)	0.6774 (4)	0.5546 (2)	0.0169 (18)
H51A	0.4565	0.7124	0.5359	0.020*
C52	0.5117 (3)	0.6388 (4)	0.5533 (2)	0.0169 (18)
C53	0.5235 (3)	0.5860 (4)	0.5798 (2)	0.0167 (17)
H53A	0.5534	0.5581	0.5777	0.020*
C54	0.4928 (3)	0.5730 (4)	0.6091 (2)	0.0151 (17)
C55	0.2835 (3)	0.5551 (3)	0.6752 (2)	0.0111 (16)
C56	0.2398 (3)	0.5999 (3)	0.6678 (2)	0.0128 (16)
C57	0.1844 (3)	0.5808 (3)	0.6642 (2)	0.0132 (16)
H57A	0.1550	0.6119	0.6580	0.016*
C58	0.1705 (3)	0.5177 (4)	0.6693 (2)	0.0179 (18)
C59	0.2142 (3)	0.4743 (4)	0.6783 (2)	0.0176 (18)
H59A	0.2055	0.4311	0.6828	0.021*
C60	0.2701 (3)	0.4898 (4)	0.6812 (2)	0.0142 (17)
C61	0.3170 (3)	0.4399 (4)	0.6916 (2)	0.0193 (18)
H61A	0.3509	0.4571	0.6833	0.023*
C62	0.3000 (4)	0.3774 (4)	0.6685 (3)	0.029 (2)
H62A	0.2944	0.3842	0.6383	0.043*
H62B	0.2646	0.3619	0.6741	0.043*
H62C	0.3301	0.3457	0.6783	0.043*
C63	0.3338 (4)	0.4285 (4)	0.7393 (2)	0.026 (2)
H63A	0.3471	0.4686	0.7538	0.039*
H63B	0.3643	0.3967	0.7463	0.039*
H63C	0.3008	0.4129	0.7483	0.039*
C64	0.5113 (3)	0.5183 (3)	0.6397 (2)	0.0153 (17)
H64A	0.4802	0.5101	0.6540	0.018*
C65	0.5224 (4)	0.4558 (4)	0.6184 (2)	0.0239 (19)
H65A	0.4884	0.4442	0.5965	0.036*
H65B	0.5314	0.4217	0.6394	0.036*
H65C	0.5544	0.4619	0.6058	0.036*
C66	0.5651 (3)	0.5357 (4)	0.6736 (2)	0.0185 (18)
H66A	0.5581	0.5743	0.6884	0.028*
H66B	0.5964	0.5436	0.6604	0.028*
H66C	0.5753	0.5005	0.6936	0.028*
C67	0.5468 (3)	0.6552 (4)	0.5220 (2)	0.0204 (18)
H67A	0.5509	0.7027	0.5217	0.024*
C68	0.5156 (4)	0.6344 (5)	0.4775 (2)	0.035 (2)
H68A	0.5376	0.6475	0.4578	0.053*
H68B	0.4781	0.6546	0.4697	0.053*
H68C	0.5113	0.5879	0.4767	0.053*
C69	0.6062 (4)	0.6269 (4)	0.5341 (2)	0.030 (2)
H69A	0.6255	0.6401	0.5627	0.044*
H69B	0.6278	0.6420	0.5145	0.044*
H69C	0.6036	0.5802	0.5328	0.044*
C70	0.3846 (3)	0.7104 (4)	0.5854 (2)	0.0175 (17)
H70A	0.3553	0.6849	0.5947	0.021*
C71	0.3555 (3)	0.7411 (4)	0.5432 (2)	0.0245 (19)
H71A	0.3200	0.7615	0.5453	0.037*
H71B	0.3470	0.7082	0.5214	0.037*
H71C	0.3807	0.7733	0.5360	0.037*
C72	0.4053 (4)	0.7631 (4)	0.6181 (2)	0.029 (2)
H72A	0.3735	0.7915	0.6187	0.044*
H72B	0.4355	0.7876	0.6105	0.044*
H72C	0.4199	0.7437	0.6458	0.044*
C73	0.2517 (3)	0.6720 (3)	0.6639 (2)	0.0142 (17)
H73A	0.2932	0.6769	0.6661	0.017*
C74	0.2196 (4)	0.6989 (4)	0.6213 (2)	0.027 (2)
H74A	0.2297	0.7439	0.6194	0.041*
H74B	0.1786	0.6953	0.6183	0.041*
H74C	0.2299	0.6748	0.5988	0.041*
C75	0.2388 (4)	0.7078 (4)	0.7003 (2)	0.027 (2)
H75A	0.2598	0.6884	0.7267	0.041*
H75B	0.1980	0.7058	0.6982	0.041*
H75C	0.2504	0.7525	0.6994	0.041*
C76	0.2805 (4)	0.5938 (4)	0.5083 (2)	0.024 (2)
H76A	0.2491	0.6018	0.5199	0.029*
C77	0.2765 (4)	0.6107 (4)	0.4671 (3)	0.036 (3)
H77A	0.2428	0.6298	0.4506	0.044*
C78	0.3215 (4)	0.5996 (4)	0.4504 (3)	0.038 (3)
H78A	0.3193	0.6111	0.4222	0.046*
C79	0.3708 (4)	0.5713 (4)	0.4748 (2)	0.031 (2)
H79A	0.4026	0.5633	0.4637	0.037*
C80	0.3718 (4)	0.5552 (4)	0.5160 (2)	0.024 (2)
H80A	0.4051	0.5356	0.5328	0.029*
C81	0.1096 (3)	0.4947 (4)	0.6629 (2)	0.0212 (19)
H81A	0.1090	0.4629	0.6854	0.025*
C82	0.0679 (3)	0.5473 (4)	0.6654 (3)	0.029 (2)
H82A	0.0815	0.5707	0.6918	0.043*
H82B	0.0307	0.5285	0.6644	0.043*
H82C	0.0645	0.5766	0.6418	0.043*
C83	0.0897 (4)	0.4607 (4)	0.6204 (3)	0.035 (2)
H83A	0.1147	0.4243	0.6195	0.052*
H83B	0.0911	0.4905	0.5978	0.052*
H83C	0.0507	0.4455	0.6168	0.052*
Ga3	0.67674 (4)	0.52475 (4)	0.91065 (2)	0.0142 (2)
Cl5	0.76883 (8)	0.51390 (10)	0.92779 (6)	0.0250 (5)
Cl6	0.63867 (9)	0.42969 (9)	0.91251 (6)	0.0253 (5)
N3	0.6687 (3)	0.5557 (3)	0.96730 (17)	0.0121 (14)
C84	0.6390 (3)	0.5707 (3)	0.8585 (2)	0.0127 (16)
C85	0.5855 (3)	0.5993 (3)	0.8538 (2)	0.0118 (16)
C86	0.5565 (3)	0.6239 (4)	0.8146 (2)	0.0163 (17)
H86A	0.5206	0.6437	0.8117	0.020*
C87	0.5788 (3)	0.6198 (4)	0.7802 (2)	0.0191 (18)
H87A	0.5579	0.6349	0.7536	0.023*
C88	0.6320 (3)	0.5935 (4)	0.7850 (2)	0.0157 (17)
H88A	0.6479	0.5916	0.7615	0.019*
C89	0.6633 (3)	0.5695 (3)	0.8238 (2)	0.0132 (17)
C90	0.7235 (3)	0.5513 (4)	0.8267 (2)	0.0144 (17)
C91	0.7647 (3)	0.5994 (3)	0.8340 (2)	0.0147 (17)
C92	0.8208 (3)	0.5844 (4)	0.8352 (2)	0.0182 (18)
H92A	0.8487	0.6170	0.8414	0.022*
C93	0.8369 (3)	0.5228 (4)	0.8276 (2)	0.0209 (19)
C94	0.7956 (4)	0.4768 (4)	0.8194 (2)	0.024 (2)
H94A	0.8061	0.4347	0.8136	0.029*
C95	0.7390 (3)	0.4882 (3)	0.8190 (2)	0.0139 (17)
C96	0.5557 (3)	0.6079 (4)	0.8882 (2)	0.0127 (16)
C97	0.5697 (3)	0.6619 (3)	0.9152 (2)	0.0119 (16)
C98	0.5356 (3)	0.6752 (3)	0.9427 (2)	0.0153 (17)
H98A	0.5443	0.7110	0.9609	0.018*
C99	0.4894 (3)	0.6371 (4)	0.9440 (2)	0.0158 (17)
C100	0.4783 (3)	0.5835 (4)	0.9181 (2)	0.0146 (17)
H10A	0.4478	0.5562	0.9198	0.018*
C101	0.5103 (3)	0.5688 (3)	0.8902 (2)	0.0151 (17)
C102	0.4933 (3)	0.5114 (4)	0.8611 (2)	0.0147 (17)
H10B	0.5255	0.5023	0.8481	0.018*
C103	0.4412 (3)	0.5272 (4)	0.8253 (2)	0.024 (2)
H10C	0.4496	0.5640	0.8096	0.036*
H10D	0.4090	0.5373	0.8370	0.036*
H10E	0.4316	0.4903	0.8065	0.036*
C104	0.4825 (4)	0.4511 (4)	0.8835 (2)	0.0227 (19)
H10F	0.5169	0.4397	0.9050	0.034*
H10G	0.4722	0.4162	0.8632	0.034*
H10H	0.4513	0.4586	0.8968	0.034*
C105	0.6957 (4)	0.4349 (4)	0.8094 (2)	0.024 (2)
H10I	0.6601	0.4502	0.8163	0.028*
C106	0.7161 (4)	0.3750 (4)	0.8355 (3)	0.029 (2)
H10J	0.7241	0.3855	0.8654	0.044*
H10K	0.7509	0.3590	0.8291	0.044*
H10L	0.6866	0.3421	0.8287	0.044*
C107	0.6816 (4)	0.4192 (4)	0.7625 (3)	0.034 (2)
H10M	0.6665	0.4573	0.7463	0.051*
H10N	0.6532	0.3850	0.7563	0.051*
H10O	0.7162	0.4052	0.7550	0.051*
C108	0.8969 (3)	0.5100 (4)	0.8256 (3)	0.026 (2)
H10P	0.9212	0.5448	0.8414	0.031*
C109	0.9214 (4)	0.4463 (4)	0.8451 (3)	0.031 (2)
H10Q	0.9192	0.4445	0.8744	0.047*
H10R	0.9611	0.4427	0.8440	0.047*
H10S	0.8994	0.4110	0.8294	0.047*
C110	0.9015 (4)	0.5131 (5)	0.7793 (3)	0.037 (2)
H11B	0.8905	0.5557	0.7679	0.055*
H11C	0.8763	0.4812	0.7625	0.055*
H11D	0.9408	0.5045	0.7785	0.055*
C111	0.7493 (3)	0.6698 (4)	0.8389 (2)	0.0195 (18)
H11E	0.7085	0.6712	0.8396	0.023*
C112	0.7842 (4)	0.6988 (4)	0.8799 (3)	0.031 (2)
H11F	0.7720	0.7429	0.8822	0.047*
H11G	0.8245	0.6982	0.8801	0.047*
H11H	0.7785	0.6738	0.9036	0.047*
C113	0.7548 (4)	0.7080 (4)	0.8009 (3)	0.029 (2)
H11I	0.7296	0.6900	0.7755	0.043*
H11J	0.7942	0.7063	0.7987	0.043*
H11K	0.7441	0.7525	0.8041	0.043*
C114	0.6184 (3)	0.7061 (4)	0.9131 (2)	0.0190 (18)
H11L	0.6475	0.6800	0.9039	0.023*
C115	0.6478 (3)	0.7363 (4)	0.9557 (2)	0.025 (2)
H11M	0.6591	0.7026	0.9768	0.037*
H11N	0.6215	0.7657	0.9642	0.037*
H11O	0.6816	0.7597	0.9531	0.037*
C116	0.5987 (4)	0.7585 (4)	0.8806 (2)	0.033 (2)
H11P	0.6305	0.7872	0.8806	0.049*
H11Q	0.5678	0.7827	0.8875	0.049*
H11R	0.5851	0.7393	0.8527	0.049*
C117	0.4531 (3)	0.6558 (4)	0.9737 (2)	0.0208 (18)
H11S	0.4544	0.7033	0.9764	0.025*
C118	0.3906 (3)	0.6363 (4)	0.9578 (2)	0.0239 (19)
H11T	0.3753	0.6534	0.9294	0.036*
H11U	0.3689	0.6535	0.9766	0.036*
H11V	0.3877	0.5897	0.9571	0.036*
C119	0.6222 (3)	0.5414 (4)	0.9810 (2)	0.0195 (18)
H11W	0.5914	0.5199	0.9625	0.023*
C120	0.6179 (4)	0.5567 (4)	1.0205 (2)	0.0235 (19)
H12A	0.5844	0.5472	1.0290	0.028*
C121	0.6630 (4)	0.5861 (4)	1.0475 (2)	0.030 (2)
H12B	0.6610	0.5966	1.0751	0.036*
C122	0.7103 (4)	0.6002 (4)	1.0348 (3)	0.036 (2)
H12C	0.7416	0.6205	1.0536	0.043*
C123	0.7131 (3)	0.5849 (4)	0.9943 (2)	0.0222 (19)
H12D	0.7463	0.5950	0.9854	0.027*
C124	0.4773 (4)	0.6281 (4)	1.0171 (2)	0.030 (2)
H12H	0.5176	0.6394	1.0268	0.046*
H12I	0.4733	0.5815	1.0159	0.046*
H12J	0.4566	0.6454	1.0365	0.046*
Ga4	0.18355 (3)	0.27110 (4)	0.41440 (2)	0.01313 (19)
Cl7	0.14634 (8)	0.17625 (9)	0.41972 (6)	0.0208 (4)
Cl8	0.27560 (8)	0.25859 (9)	0.42971 (5)	0.0203 (4)
N4	0.1801 (3)	0.3084 (3)	0.47053 (18)	0.0148 (14)
C125	0.1423 (3)	0.3137 (3)	0.36180 (19)	0.0066 (14)
C126	0.1632 (3)	0.3095 (3)	0.3257 (2)	0.0129 (16)
C127	0.1287 (3)	0.3278 (4)	0.2865 (2)	0.0158 (17)
H12E	0.1431	0.3258	0.2623	0.019*
C128	0.0740 (3)	0.3487 (4)	0.2830 (2)	0.0192 (18)
H12F	0.0502	0.3589	0.2562	0.023*
C129	0.0535 (3)	0.3549 (4)	0.3183 (2)	0.0175 (17)
H12G	0.0167	0.3721	0.3158	0.021*
C130	0.0871 (3)	0.3357 (3)	0.3581 (2)	0.0140 (16)
C131	0.0601 (3)	0.3493 (3)	0.3938 (2)	0.0115 (16)
C132	0.0730 (3)	0.4062 (3)	0.4171 (2)	0.0138 (17)
C133	0.0398 (3)	0.4229 (3)	0.4442 (2)	0.0136 (16)
H13A	0.0483	0.4614	0.4598	0.016*
C134	−0.0052 (3)	0.3857 (4)	0.4494 (2)	0.0178 (18)
C135	−0.0155 (3)	0.3287 (4)	0.4281 (2)	0.0169 (17)
H13B	−0.0444	0.3014	0.4328	0.020*
C136	0.0153 (3)	0.3097 (3)	0.3997 (2)	0.0124 (16)
C137	0.2241 (3)	0.2949 (3)	0.3286 (2)	0.0123 (16)
C138	0.2636 (3)	0.3451 (4)	0.3363 (2)	0.0167 (17)
C139	0.3204 (3)	0.3313 (4)	0.3419 (2)	0.0201 (18)
H13C	0.3473	0.3650	0.3482	0.024*
C140	0.3395 (3)	0.2693 (4)	0.3387 (2)	0.0190 (18)
C141	0.2996 (3)	0.2211 (4)	0.3278 (2)	0.0173 (16)
H14A	0.3118	0.1792	0.3234	0.021*
C142	0.2417 (3)	0.2326 (4)	0.3233 (2)	0.0170 (17)
C143	0.1990 (3)	0.1787 (4)	0.3113 (2)	0.0171 (17)
H14B	0.1633	0.1926	0.3185	0.021*
C144	0.2190 (4)	0.1173 (4)	0.3355 (2)	0.026 (2)
H14C	0.2258	0.1254	0.3657	0.038*
H14D	0.2543	0.1029	0.3293	0.038*
H14E	0.1898	0.0843	0.3270	0.038*
C145	0.1844 (4)	0.1666 (4)	0.2637 (2)	0.026 (2)
H14F	0.1679	0.2053	0.2487	0.038*
H14G	0.1570	0.1315	0.2566	0.038*
H14H	0.2191	0.1552	0.2553	0.038*
C146	0.4028 (3)	0.2567 (4)	0.3485 (3)	0.026 (2)
H14I	0.4229	0.2984	0.3555	0.031*
C147	0.4205 (3)	0.2135 (4)	0.3873 (2)	0.028 (2)
H14J	0.4122	0.2349	0.4114	0.042*
H14K	0.4613	0.2046	0.3932	0.042*
H14L	0.3994	0.1732	0.3819	0.042*
C148	0.4205 (4)	0.2284 (5)	0.3112 (3)	0.046 (3)
H14N	0.4082	0.2567	0.2869	0.069*
H14O	0.4027	0.1864	0.3045	0.069*
H14P	0.4619	0.2238	0.3182	0.069*
C149	0.2444 (3)	0.4144 (4)	0.3367 (2)	0.0204 (19)
H14M	0.2027	0.4146	0.3348	0.024*
C150	0.2747 (4)	0.4495 (4)	0.3770 (3)	0.032 (2)
H15B	0.2691	0.4262	0.4014	0.048*
H15C	0.2590	0.4927	0.3767	0.048*
H15D	0.3154	0.4522	0.3786	0.048*
C151	0.2541 (4)	0.4495 (4)	0.2979 (3)	0.030 (2)
H15E	0.2388	0.4929	0.2969	0.045*
H15F	0.2348	0.4264	0.2724	0.045*
H15G	0.2949	0.4514	0.2998	0.045*
C152	0.1211 (3)	0.4504 (4)	0.4118 (2)	0.0158 (17)
H15H	0.1506	0.4232	0.4040	0.019*
C153	0.1498 (4)	0.4869 (4)	0.4514 (2)	0.024 (2)
H15I	0.1553	0.4586	0.4757	0.036*
H15J	0.1259	0.5231	0.4549	0.036*
H15K	0.1868	0.5027	0.4490	0.036*
C154	0.0989 (4)	0.4975 (4)	0.3759 (2)	0.026 (2)
H15L	0.1303	0.5242	0.3721	0.040*
H15M	0.0696	0.5246	0.3825	0.040*
H15N	0.0827	0.4738	0.3499	0.040*
C155	−0.0410 (3)	0.4080 (4)	0.4789 (2)	0.0192 (18)
H15O	−0.0397	0.4557	0.4796	0.023*
C156	−0.1033 (3)	0.3883 (5)	0.4649 (3)	0.031 (2)
H15P	−0.1181	0.3976	0.4349	0.047*
H15Q	−0.1252	0.4123	0.4810	0.047*
H15R	−0.1067	0.3425	0.4697	0.047*
C157	−0.0153 (4)	0.3843 (5)	0.5239 (2)	0.039 (3)
H15S	−0.0396	0.3974	0.5420	0.059*
H15T	0.0227	0.4026	0.5345	0.059*
H15U	−0.0125	0.3376	0.5238	0.059*
C158	0.0001 (3)	0.2476 (4)	0.3754 (2)	0.0181 (17)
H15V	0.0314	0.2371	0.3619	0.022*
C159	−0.0552 (3)	0.2545 (4)	0.3406 (2)	0.025 (2)
H15W	−0.0510	0.2889	0.3215	0.038*
H15X	−0.0866	0.2646	0.3532	0.038*
H15Y	−0.0633	0.2143	0.3250	0.038*
C160	−0.0056 (4)	0.1925 (4)	0.4042 (3)	0.0247 (19)
H16A	0.0289	0.1897	0.4273	0.037*
H16B	−0.0108	0.1525	0.3883	0.037*
H16C	−0.0385	0.1998	0.4157	0.037*
C161	0.1362 (3)	0.2969 (4)	0.4872 (2)	0.0193 (18)
H16D	0.1046	0.2735	0.4711	0.023*
C162	0.1349 (4)	0.3174 (4)	0.5267 (2)	0.025 (2)
H16E	0.1029	0.3083	0.5373	0.030*
C163	0.1796 (4)	0.3507 (4)	0.5504 (2)	0.028 (2)
H16F	0.1793	0.3653	0.5777	0.033*
C164	0.2258 (4)	0.3629 (4)	0.5338 (2)	0.026 (2)
H16G	0.2579	0.3859	0.5496	0.031*
C165	0.2241 (4)	0.3407 (3)	0.4940 (2)	0.0203 (19)
H16H	0.2557	0.3489	0.4827	0.024*
C200	0.5280 (4)	0.4392 (5)	0.7704 (3)	0.036 (2)
H20D	0.5418	0.4772	0.7852	0.043*
C201	0.5482 (4)	0.3803 (5)	0.7861 (3)	0.037 (2)
H20E	0.5755	0.3779	0.8124	0.044*
C202	0.5299 (4)	0.3262 (4)	0.7649 (3)	0.036 (2)
H20F	0.5448	0.2861	0.7759	0.044*
C203	0.4890 (4)	0.3293 (5)	0.7266 (3)	0.043 (3)
H20G	0.4759	0.2913	0.7115	0.051*
C204	0.4680 (4)	0.3875 (5)	0.7108 (3)	0.040 (3)
H20H	0.4400	0.3898	0.6849	0.048*
C205	0.4871 (4)	0.4419 (5)	0.7325 (3)	0.037 (2)
H20I	0.4723	0.4821	0.7214	0.045*
C207	0.0131 (4)	0.8109 (4)	0.7643 (3)	0.034 (2)
H20J	0.0301	0.7706	0.7724	0.041*
C208	−0.0254 (4)	0.8177 (4)	0.7259 (3)	0.031 (2)
H20K	−0.0355	0.7815	0.7083	0.038*
C209	−0.0492 (4)	0.8753 (5)	0.7128 (3)	0.036 (3)
H20L	−0.0745	0.8797	0.6858	0.043*
C212	0.0268 (4)	0.8617 (5)	0.7905 (3)	0.036 (2)
H21D	0.0530	0.8566	0.8171	0.043*
C211	0.0027 (4)	0.9212 (5)	0.7787 (3)	0.037 (2)
H21E	0.0125	0.9569	0.7969	0.044*
C210	−0.0360 (4)	0.9278 (4)	0.7398 (3)	0.035 (2)
H21F	−0.0534	0.9679	0.7315	0.042*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ga1	0.0137 (4)	0.0126 (4)	0.0127 (4)	0.0003 (4)	0.0031 (3)	−0.0010 (3)
Cl1	0.0131 (9)	0.0283 (11)	0.0224 (9)	−0.0035 (8)	0.0047 (8)	−0.0042 (8)
Cl2	0.0263 (11)	0.0140 (10)	0.0234 (9)	0.0068 (8)	0.0037 (8)	−0.0020 (8)
N1	0.025 (4)	0.016 (4)	0.021 (3)	−0.003 (3)	0.002 (3)	0.001 (3)
C1	0.012 (4)	0.011 (4)	0.013 (3)	0.005 (3)	0.006 (3)	0.004 (3)
C2	0.021 (4)	0.009 (4)	0.011 (3)	0.006 (3)	0.006 (3)	0.001 (3)
C3	0.016 (4)	0.016 (4)	0.012 (3)	0.003 (3)	0.005 (3)	0.006 (3)
C4	0.021 (4)	0.023 (5)	0.012 (4)	−0.002 (4)	0.003 (3)	0.002 (3)
C5	0.013 (4)	0.011 (4)	0.018 (4)	−0.001 (3)	0.002 (3)	−0.001 (3)
C6	0.011 (4)	0.009 (4)	0.011 (3)	0.007 (3)	0.007 (3)	0.003 (3)
C7	0.013 (4)	0.014 (4)	0.014 (3)	−0.003 (3)	0.003 (3)	0.002 (3)
C8	0.014 (4)	0.018 (4)	0.015 (4)	−0.005 (3)	0.004 (3)	0.001 (3)
C9	0.021 (4)	0.019 (4)	0.011 (3)	0.002 (3)	0.002 (3)	0.010 (3)
C10	0.022 (4)	0.019 (4)	0.015 (4)	0.000 (3)	0.006 (3)	0.003 (3)
C11	0.014 (4)	0.020 (4)	0.021 (4)	0.001 (3)	0.010 (3)	0.002 (3)
C12	0.014 (4)	0.011 (4)	0.012 (3)	−0.002 (3)	0.000 (3)	0.004 (3)
C13	0.013 (4)	0.009 (4)	0.008 (3)	−0.005 (3)	0.004 (3)	0.002 (3)
C14	0.024 (4)	0.014 (4)	0.011 (3)	0.002 (3)	0.007 (3)	0.000 (3)
C15	0.025 (4)	0.009 (4)	0.012 (3)	−0.007 (3)	0.011 (3)	0.001 (3)
C16	0.0163 (19)	0.0156 (18)	0.0152 (18)	−0.0003 (10)	0.0040 (10)	0.0007 (10)
C17	0.013 (4)	0.020 (4)	0.017 (4)	0.004 (3)	0.000 (3)	0.003 (3)
C18	0.017 (4)	0.016 (4)	0.012 (3)	−0.001 (3)	0.008 (3)	0.001 (3)
C19	0.013 (4)	0.015 (4)	0.020 (4)	−0.001 (3)	0.002 (3)	0.003 (3)
C20	0.041 (5)	0.015 (4)	0.020 (4)	−0.005 (4)	0.005 (4)	−0.002 (3)
C21	0.029 (5)	0.020 (4)	0.018 (4)	0.003 (4)	0.003 (4)	−0.001 (3)
C22	0.024 (4)	0.012 (4)	0.030 (4)	−0.003 (4)	0.006 (4)	−0.002 (3)
C23	0.026 (5)	0.025 (5)	0.037 (5)	−0.011 (4)	0.009 (4)	−0.009 (4)
C24	0.020 (5)	0.042 (6)	0.054 (6)	−0.011 (4)	0.013 (4)	−0.010 (5)
C25	0.025 (4)	0.012 (4)	0.015 (4)	0.003 (3)	0.009 (3)	0.005 (3)
C26	0.029 (5)	0.014 (4)	0.038 (5)	0.001 (4)	0.014 (4)	−0.003 (4)
C27	0.026 (5)	0.036 (5)	0.021 (4)	0.014 (4)	0.006 (4)	0.007 (4)
C28	0.016 (4)	0.018 (4)	0.013 (3)	−0.002 (3)	0.002 (3)	0.003 (3)
C29	0.026 (5)	0.020 (5)	0.029 (4)	0.003 (4)	0.002 (4)	0.000 (4)
C30	0.018 (4)	0.029 (5)	0.018 (4)	0.001 (4)	−0.002 (3)	0.007 (4)
C31	0.017 (4)	0.037 (5)	0.012 (4)	−0.002 (4)	0.008 (3)	0.003 (3)
C32	0.028 (5)	0.043 (6)	0.021 (4)	−0.005 (4)	0.009 (4)	0.006 (4)
C33	0.048 (6)	0.045 (6)	0.024 (4)	0.013 (5)	0.021 (4)	0.005 (4)
C34	0.019 (4)	0.021 (4)	0.020 (4)	0.005 (4)	0.010 (3)	0.006 (3)
C35	0.039 (6)	0.024 (5)	0.026 (4)	0.015 (4)	0.001 (4)	−0.003 (4)
C36	0.021 (4)	0.021 (4)	0.024 (4)	0.006 (4)	0.005 (4)	0.010 (3)
C37	0.025 (5)	0.033 (5)	0.014 (4)	−0.011 (4)	0.010 (3)	−0.008 (3)
C38	0.050 (6)	0.058 (7)	0.023 (5)	−0.018 (5)	0.016 (5)	−0.004 (4)
C39	0.036 (2)	0.036 (2)	0.035 (2)	−0.0010 (10)	0.0089 (11)	0.0003 (10)
C40	0.054 (6)	0.015 (4)	0.019 (4)	−0.006 (4)	−0.003 (4)	0.003 (3)
C41	0.033 (5)	0.021 (4)	0.015 (4)	0.000 (4)	0.003 (4)	0.004 (3)
Ga2	0.0161 (4)	0.0125 (4)	0.0114 (4)	0.0001 (3)	0.0036 (3)	−0.0012 (3)
Cl3	0.0247 (11)	0.0158 (10)	0.0248 (10)	0.0042 (8)	0.0046 (9)	−0.0027 (8)
Cl4	0.0165 (10)	0.0256 (11)	0.0191 (9)	−0.0016 (8)	0.0043 (8)	−0.0064 (8)
N2	0.022 (4)	0.007 (3)	0.012 (3)	0.000 (3)	0.004 (3)	−0.002 (2)
C43	0.005 (4)	0.018 (4)	0.013 (3)	0.004 (3)	0.000 (3)	0.002 (3)
C44	0.016 (4)	0.007 (4)	0.014 (3)	−0.001 (3)	0.006 (3)	0.006 (3)
C45	0.016 (4)	0.020 (4)	0.016 (4)	0.002 (3)	0.008 (3)	−0.002 (3)
C46	0.019 (4)	0.017 (4)	0.011 (3)	−0.003 (3)	0.002 (3)	−0.006 (3)
C47	0.016 (4)	0.013 (4)	0.016 (4)	0.003 (3)	0.002 (3)	−0.002 (3)
C48	0.0099 (17)	0.0090 (17)	0.0096 (17)	0.0004 (10)	0.0030 (10)	0.0008 (10)
C49	0.011 (4)	0.017 (4)	0.007 (3)	−0.008 (3)	0.002 (3)	−0.002 (3)
C50	0.019 (4)	0.016 (4)	0.006 (3)	−0.001 (3)	0.001 (3)	−0.003 (3)
C51	0.024 (4)	0.019 (4)	0.006 (3)	0.000 (4)	0.001 (3)	0.001 (3)
C52	0.021 (4)	0.023 (4)	0.008 (3)	−0.005 (4)	0.005 (3)	0.002 (3)
C53	0.015 (4)	0.019 (4)	0.014 (4)	−0.002 (3)	0.000 (3)	−0.006 (3)
C54	0.016 (4)	0.016 (4)	0.013 (4)	0.002 (3)	0.004 (3)	−0.008 (3)
C55	0.010 (4)	0.010 (4)	0.014 (3)	−0.003 (3)	0.005 (3)	0.003 (3)
C56	0.017 (4)	0.010 (4)	0.011 (3)	−0.001 (3)	0.004 (3)	−0.003 (3)
C57	0.013 (4)	0.010 (4)	0.017 (4)	−0.001 (3)	0.006 (3)	0.000 (3)
C58	0.020 (4)	0.019 (4)	0.016 (4)	−0.006 (3)	0.007 (3)	−0.001 (3)
C59	0.019 (4)	0.013 (4)	0.021 (4)	−0.006 (3)	0.006 (3)	0.000 (3)
C60	0.021 (4)	0.016 (4)	0.007 (3)	0.007 (3)	0.006 (3)	0.001 (3)
C61	0.023 (4)	0.013 (4)	0.024 (4)	−0.002 (3)	0.011 (4)	0.001 (3)
C62	0.033 (5)	0.019 (5)	0.038 (5)	0.007 (4)	0.014 (4)	0.005 (4)
C63	0.027 (5)	0.026 (5)	0.026 (4)	0.012 (4)	0.008 (4)	0.006 (4)
C64	0.015 (4)	0.018 (4)	0.015 (4)	−0.001 (3)	0.006 (3)	−0.004 (3)
C65	0.026 (5)	0.018 (4)	0.030 (4)	0.004 (4)	0.012 (4)	−0.003 (4)
C66	0.016 (4)	0.017 (4)	0.020 (4)	0.004 (3)	0.000 (3)	0.003 (3)
C67	0.028 (5)	0.022 (4)	0.012 (4)	−0.003 (4)	0.005 (3)	−0.001 (3)
C68	0.045 (6)	0.052 (6)	0.015 (4)	−0.011 (5)	0.016 (4)	−0.007 (4)
C69	0.027 (5)	0.040 (6)	0.024 (4)	−0.001 (4)	0.011 (4)	0.005 (4)
C70	0.018 (4)	0.014 (4)	0.021 (4)	0.003 (3)	0.006 (3)	0.003 (3)
C71	0.020 (4)	0.020 (4)	0.031 (4)	0.005 (4)	0.002 (4)	0.006 (4)
C72	0.035 (5)	0.029 (5)	0.024 (4)	0.009 (4)	0.009 (4)	0.001 (4)
C73	0.012 (4)	0.004 (4)	0.026 (4)	−0.002 (3)	0.003 (3)	0.005 (3)
C74	0.040 (5)	0.014 (4)	0.028 (4)	−0.007 (4)	0.007 (4)	0.011 (3)
C75	0.045 (6)	0.010 (4)	0.029 (4)	−0.005 (4)	0.012 (4)	−0.001 (3)
C76	0.027 (5)	0.011 (4)	0.031 (4)	−0.002 (4)	−0.001 (4)	0.004 (3)
C77	0.040 (6)	0.027 (5)	0.033 (5)	−0.011 (4)	−0.010 (5)	0.021 (4)
C78	0.054 (7)	0.040 (6)	0.016 (4)	−0.027 (5)	0.000 (4)	0.008 (4)
C79	0.043 (6)	0.036 (5)	0.019 (4)	−0.020 (5)	0.016 (4)	−0.007 (4)
C80	0.023 (5)	0.030 (5)	0.019 (4)	−0.005 (4)	0.004 (4)	−0.004 (4)
C81	0.013 (4)	0.027 (5)	0.022 (4)	−0.003 (4)	0.002 (3)	0.009 (4)
C82	0.020 (5)	0.035 (5)	0.032 (5)	−0.005 (4)	0.007 (4)	−0.006 (4)
C83	0.026 (5)	0.030 (5)	0.046 (6)	−0.012 (4)	0.006 (4)	−0.015 (4)
Ga3	0.0146 (5)	0.0140 (4)	0.0138 (4)	0.0015 (3)	0.0032 (3)	0.0024 (3)
Cl5	0.0165 (10)	0.0366 (12)	0.0220 (10)	0.0054 (9)	0.0053 (8)	0.0096 (9)
Cl6	0.0335 (12)	0.0146 (10)	0.0275 (10)	−0.0056 (9)	0.0072 (9)	0.0010 (8)
N3	0.022 (4)	0.005 (3)	0.008 (3)	−0.001 (3)	0.001 (3)	0.001 (2)
C84	0.009 (4)	0.014 (4)	0.015 (4)	−0.002 (3)	0.003 (3)	0.000 (3)
C85	0.019 (4)	0.009 (4)	0.007 (3)	−0.008 (3)	0.003 (3)	−0.003 (3)
C86	0.011 (4)	0.025 (4)	0.014 (4)	0.003 (3)	0.004 (3)	0.006 (3)
C87	0.025 (5)	0.019 (4)	0.013 (4)	0.004 (4)	0.003 (3)	0.005 (3)
C88	0.016 (4)	0.020 (4)	0.014 (4)	−0.001 (3)	0.009 (3)	0.002 (3)
C89	0.014 (4)	0.005 (4)	0.019 (4)	0.001 (3)	0.001 (3)	−0.006 (3)
C90	0.010 (4)	0.017 (4)	0.016 (4)	0.002 (3)	0.004 (3)	−0.004 (3)
C91	0.015 (4)	0.012 (4)	0.017 (4)	0.004 (3)	0.004 (3)	0.001 (3)
C92	0.017 (4)	0.017 (4)	0.020 (4)	−0.001 (3)	0.003 (3)	−0.002 (3)
C93	0.015 (4)	0.024 (5)	0.023 (4)	0.005 (4)	0.002 (3)	0.002 (3)
C94	0.031 (5)	0.020 (5)	0.022 (4)	0.010 (4)	0.007 (4)	−0.003 (3)
C95	0.014 (4)	0.008 (4)	0.019 (4)	0.003 (3)	0.003 (3)	−0.002 (3)
C96	0.009 (4)	0.021 (4)	0.008 (3)	0.003 (3)	0.001 (3)	0.003 (3)
C97	0.014 (4)	0.012 (4)	0.009 (3)	0.000 (3)	0.001 (3)	0.003 (3)
C98	0.027 (4)	0.012 (4)	0.006 (3)	−0.001 (3)	0.004 (3)	−0.001 (3)
C99	0.014 (4)	0.026 (5)	0.007 (3)	0.006 (3)	0.001 (3)	0.004 (3)
C100	0.019 (4)	0.017 (4)	0.008 (3)	−0.003 (3)	0.003 (3)	0.006 (3)
C101	0.021 (4)	0.013 (4)	0.010 (3)	0.002 (3)	0.002 (3)	0.009 (3)
C102	0.013 (4)	0.019 (4)	0.012 (3)	−0.005 (3)	0.003 (3)	−0.001 (3)
C103	0.016 (4)	0.032 (5)	0.020 (4)	0.003 (4)	−0.003 (3)	−0.004 (3)
C104	0.031 (5)	0.014 (4)	0.027 (4)	−0.007 (4)	0.015 (4)	0.001 (3)
C105	0.026 (5)	0.016 (4)	0.029 (4)	0.002 (4)	0.009 (4)	−0.001 (3)
C106	0.037 (5)	0.011 (4)	0.042 (5)	−0.004 (4)	0.016 (4)	−0.002 (4)
C107	0.037 (6)	0.032 (5)	0.032 (5)	−0.015 (4)	0.006 (4)	−0.008 (4)
C108	0.015 (4)	0.021 (5)	0.038 (5)	0.006 (4)	0.001 (4)	−0.007 (4)
C109	0.032 (5)	0.017 (5)	0.040 (5)	0.016 (4)	0.003 (4)	0.004 (4)
C110	0.028 (5)	0.041 (6)	0.046 (6)	0.006 (4)	0.018 (4)	0.012 (5)
C111	0.018 (4)	0.014 (4)	0.028 (4)	0.002 (3)	0.008 (4)	−0.006 (3)
C112	0.035 (5)	0.023 (5)	0.039 (5)	−0.002 (4)	0.013 (4)	−0.014 (4)
C113	0.030 (5)	0.016 (5)	0.039 (5)	0.005 (4)	0.007 (4)	0.003 (4)
C114	0.016 (4)	0.017 (4)	0.023 (4)	−0.004 (3)	0.003 (3)	0.001 (3)
C115	0.019 (4)	0.022 (5)	0.029 (4)	−0.010 (4)	−0.001 (4)	−0.004 (4)
C116	0.044 (6)	0.030 (5)	0.022 (4)	−0.016 (4)	0.005 (4)	0.004 (4)
C117	0.023 (4)	0.019 (4)	0.021 (4)	0.001 (4)	0.007 (4)	0.001 (3)
C118	0.029 (5)	0.030 (5)	0.016 (4)	0.004 (4)	0.010 (4)	−0.003 (3)
C119	0.013 (4)	0.022 (4)	0.023 (4)	0.001 (3)	0.002 (3)	0.005 (3)
C120	0.027 (5)	0.025 (5)	0.021 (4)	0.004 (4)	0.009 (4)	0.012 (3)
C121	0.055 (6)	0.019 (5)	0.015 (4)	0.011 (4)	0.007 (4)	−0.002 (3)
C122	0.037 (6)	0.030 (5)	0.032 (5)	−0.010 (4)	−0.008 (5)	−0.007 (4)
C123	0.021 (4)	0.014 (4)	0.028 (4)	−0.002 (3)	0.001 (4)	0.005 (3)
C124	0.034 (5)	0.040 (6)	0.020 (4)	0.011 (4)	0.011 (4)	0.004 (4)
Ga4	0.0146 (4)	0.0116 (4)	0.0129 (4)	−0.0014 (4)	0.0029 (3)	0.0007 (3)
Cl7	0.0247 (11)	0.0123 (9)	0.0245 (10)	−0.0025 (8)	0.0048 (8)	0.0018 (8)
Cl8	0.0150 (9)	0.0275 (11)	0.0180 (9)	0.0040 (8)	0.0035 (8)	0.0047 (8)
N4	0.013 (3)	0.009 (3)	0.019 (3)	0.002 (3)	−0.002 (3)	0.001 (3)
C125	0.0067 (16)	0.0064 (16)	0.0068 (16)	0.0005 (10)	0.0019 (10)	−0.0006 (10)
C126	0.015 (4)	0.013 (4)	0.010 (3)	−0.008 (3)	0.003 (3)	0.002 (3)
C127	0.018 (4)	0.018 (4)	0.014 (4)	0.006 (3)	0.008 (3)	−0.002 (3)
C128	0.019 (4)	0.026 (5)	0.010 (3)	0.010 (4)	0.000 (3)	0.002 (3)
C129	0.017 (4)	0.017 (4)	0.019 (4)	0.005 (3)	0.006 (3)	0.003 (3)
C130	0.015 (4)	0.010 (4)	0.017 (4)	0.003 (3)	0.005 (3)	0.003 (3)
C131	0.009 (4)	0.010 (4)	0.014 (3)	0.007 (3)	0.001 (3)	0.000 (3)
C132	0.015 (4)	0.009 (4)	0.016 (4)	0.003 (3)	0.001 (3)	0.001 (3)
C133	0.0140 (18)	0.0129 (18)	0.0138 (18)	0.0004 (10)	0.0033 (10)	−0.0006 (10)
C134	0.024 (4)	0.016 (4)	0.013 (4)	0.005 (3)	0.004 (3)	−0.001 (3)
C135	0.023 (4)	0.016 (4)	0.011 (3)	0.001 (3)	0.003 (3)	0.004 (3)
C136	0.019 (4)	0.012 (4)	0.004 (3)	0.000 (3)	0.000 (3)	0.001 (3)
C137	0.019 (4)	0.009 (4)	0.010 (3)	0.002 (3)	0.005 (3)	0.006 (3)
C138	0.017 (4)	0.024 (4)	0.013 (4)	−0.004 (3)	0.009 (3)	−0.001 (3)
C139	0.015 (4)	0.021 (4)	0.022 (4)	0.000 (3)	0.000 (3)	0.002 (3)
C140	0.014 (4)	0.031 (5)	0.013 (3)	0.003 (4)	0.005 (3)	0.007 (3)
C141	0.0174 (18)	0.0173 (19)	0.0173 (18)	0.0013 (10)	0.0048 (10)	0.0001 (10)
C142	0.020 (4)	0.015 (4)	0.014 (3)	0.003 (3)	0.001 (3)	0.003 (3)
C143	0.016 (4)	0.016 (4)	0.025 (4)	0.006 (3)	0.015 (3)	0.004 (3)
C144	0.034 (5)	0.017 (4)	0.028 (4)	−0.004 (4)	0.013 (4)	−0.002 (4)
C145	0.028 (5)	0.025 (5)	0.023 (4)	0.004 (4)	0.004 (4)	−0.001 (4)
C146	0.012 (4)	0.022 (5)	0.041 (5)	0.005 (3)	0.002 (4)	0.002 (4)
C147	0.018 (4)	0.030 (5)	0.033 (4)	0.008 (4)	0.001 (4)	0.000 (4)
C148	0.033 (5)	0.059 (7)	0.046 (6)	−0.006 (5)	0.008 (5)	−0.010 (5)
C149	0.023 (4)	0.011 (4)	0.025 (4)	0.000 (3)	0.002 (4)	0.003 (3)
C150	0.035 (5)	0.024 (5)	0.034 (5)	−0.001 (4)	0.003 (4)	−0.007 (4)
C151	0.029 (5)	0.015 (4)	0.045 (5)	0.004 (4)	0.007 (4)	0.009 (4)
C152	0.019 (4)	0.013 (4)	0.018 (4)	−0.004 (3)	0.010 (3)	0.000 (3)
C153	0.030 (5)	0.018 (4)	0.022 (4)	−0.003 (4)	0.003 (4)	−0.004 (3)
C154	0.026 (5)	0.022 (5)	0.032 (5)	−0.009 (4)	0.009 (4)	0.013 (4)
C155	0.027 (5)	0.018 (4)	0.017 (4)	0.000 (4)	0.013 (3)	−0.006 (3)
C156	0.020 (5)	0.040 (6)	0.038 (5)	−0.001 (4)	0.013 (4)	−0.015 (4)
C157	0.038 (6)	0.061 (7)	0.021 (4)	0.018 (5)	0.012 (4)	0.002 (4)
C158	0.018 (4)	0.019 (4)	0.020 (4)	−0.001 (3)	0.010 (3)	−0.009 (3)
C159	0.020 (4)	0.028 (5)	0.023 (4)	0.000 (4)	−0.003 (4)	−0.013 (4)
C160	0.026 (5)	0.013 (4)	0.035 (5)	−0.004 (4)	0.009 (4)	−0.006 (4)
C161	0.020 (4)	0.021 (4)	0.016 (4)	−0.004 (3)	0.004 (3)	−0.001 (3)
C162	0.024 (5)	0.031 (5)	0.024 (4)	0.007 (4)	0.013 (4)	0.002 (4)
C163	0.041 (6)	0.021 (5)	0.018 (4)	0.009 (4)	0.002 (4)	−0.007 (3)
C164	0.026 (5)	0.021 (5)	0.028 (4)	0.000 (4)	0.000 (4)	−0.011 (4)
C165	0.028 (5)	0.008 (4)	0.023 (4)	−0.007 (3)	0.004 (4)	−0.006 (3)
C200	0.052 (7)	0.030 (6)	0.031 (5)	−0.012 (5)	0.022 (5)	−0.008 (4)
C201	0.036 (6)	0.048 (7)	0.024 (5)	−0.013 (5)	0.002 (4)	0.002 (4)
C202	0.041 (6)	0.023 (5)	0.045 (5)	−0.002 (4)	0.011 (5)	0.011 (4)
C203	0.043 (6)	0.044 (6)	0.040 (5)	−0.010 (5)	0.008 (5)	−0.019 (5)
C204	0.032 (6)	0.062 (7)	0.023 (5)	0.009 (5)	0.000 (4)	−0.001 (5)
C205	0.050 (6)	0.032 (6)	0.039 (5)	0.014 (5)	0.026 (5)	0.014 (4)
C207	0.060 (7)	0.024 (5)	0.027 (5)	0.017 (5)	0.028 (5)	0.012 (4)
C208	0.049 (6)	0.025 (5)	0.027 (5)	−0.013 (5)	0.023 (4)	−0.005 (4)
C209	0.035 (6)	0.038 (6)	0.029 (5)	−0.014 (5)	−0.003 (4)	0.009 (4)
C212	0.038 (6)	0.046 (6)	0.024 (4)	0.000 (5)	0.007 (4)	0.004 (4)
C211	0.047 (6)	0.033 (6)	0.032 (5)	−0.007 (5)	0.013 (5)	−0.018 (4)
C210	0.035 (5)	0.024 (5)	0.042 (5)	0.006 (4)	0.007 (5)	0.004 (4)

Geometric parameters (Å, º)

Ga1—Cl1	2.187 (2)	C81—C82	1.515 (12)
Ga1—Cl2	2.212 (2)	C81—C83	1.535 (11)
Ga1—N1	2.040 (7)	N3—C119	1.352 (10)
Ga1—C1	1.980 (7)	N3—C123	1.358 (9)
Ga2—Cl3	2.205 (2)	C84—C85	1.405 (10)
Ga2—Cl4	2.184 (2)	C84—C89	1.417 (11)
Ga2—N2	2.034 (6)	C85—C86	1.404 (9)
Ga2—C43	1.983 (7)	C85—C96	1.502 (10)
Ga3—Cl5	2.179 (2)	C86—C87	1.378 (11)
Ga3—Cl6	2.204 (2)	C87—C88	1.379 (11)
Ga3—N3	2.032 (6)	C88—C89	1.403 (9)
Ga3—C84	1.979 (7)	C89—C90	1.493 (10)
Ga4—Cl7	2.209 (2)	C90—C91	1.398 (10)
Ga4—Cl8	2.183 (2)	C90—C95	1.416 (10)
Ga4—N4	2.028 (6)	C91—C92	1.391 (11)
Ga4—C125	1.981 (6)	C91—C111	1.540 (10)
N1—C41	1.342 (10)	C92—C93	1.390 (11)
N1—C37	1.345 (10)	C93—C94	1.370 (12)
C1—C6	1.386 (10)	C93—C108	1.503 (11)
C1—C2	1.436 (10)	C94—C95	1.394 (11)
C2—C3	1.413 (9)	C95—C105	1.513 (11)
C2—C13	1.480 (10)	C96—C101	1.389 (10)
C3—C4	1.387 (11)	C96—C97	1.428 (10)
C4—C5	1.382 (11)	C97—C98	1.402 (10)
C5—C6	1.407 (9)	C97—C114	1.520 (10)
C6—C7	1.514 (10)	C98—C99	1.387 (11)
C7—C12	1.397 (10)	C99—C100	1.393 (10)
C7—C8	1.411 (10)	C99—C117	1.527 (11)
C8—C9	1.383 (11)	C100—C101	1.383 (11)
C8—C34	1.516 (11)	C101—C102	1.529 (10)
C9—C10	1.404 (11)	C102—C104	1.520 (10)
C10—C11	1.375 (10)	C102—C103	1.531 (9)
C10—C31	1.532 (11)	C105—C107	1.530 (11)
C11—C12	1.413 (10)	C105—C106	1.532 (11)
C12—C28	1.534 (9)	C108—C109	1.536 (11)
C13—C18	1.411 (10)	C108—C110	1.557 (12)
C13—C14	1.422 (10)	C111—C113	1.520 (11)
C14—C15	1.388 (10)	C111—C112	1.526 (10)
C14—C25	1.516 (10)	C114—C116	1.524 (11)
C15—C16	1.389 (10)	C114—C115	1.538 (10)
C16—C17	1.387 (10)	C117—C124	1.515 (10)
C16—C22	1.509 (11)	C117—C118	1.532 (11)
C17—C18	1.385 (11)	C119—C120	1.371 (11)
C18—C19	1.514 (10)	C120—C121	1.370 (12)
C19—C21	1.534 (9)	C121—C122	1.353 (13)
C19—C20	1.549 (11)	C122—C123	1.391 (12)
C22—C24	1.524 (12)	N4—C165	1.335 (9)
C22—C23	1.529 (10)	N4—C161	1.341 (10)
C25—C26	1.529 (10)	C125—C130	1.397 (10)
C25—C27	1.534 (10)	C125—C126	1.410 (10)
C28—C30	1.519 (9)	C126—C127	1.401 (9)
C28—C29	1.529 (11)	C126—C137	1.492 (10)
C31—C33	1.519 (12)	C127—C128	1.378 (11)
C31—C32	1.535 (11)	C128—C129	1.382 (10)
C34—C36	1.527 (9)	C129—C130	1.416 (9)
C34—C35	1.540 (11)	C130—C131	1.511 (10)
C37—C38	1.383 (11)	C131—C132	1.409 (10)
C38—C39	1.385 (13)	C131—C136	1.424 (10)
C39—C40	1.381 (13)	C132—C133	1.393 (11)
C40—C41	1.391 (11)	C132—C152	1.537 (10)
N2—C80	1.340 (10)	C133—C134	1.389 (11)
N2—C76	1.371 (9)	C134—C135	1.377 (10)
C43—C48	1.391 (10)	C134—C155	1.533 (11)
C43—C44	1.427 (10)	C135—C136	1.396 (11)
C44—C45	1.384 (10)	C136—C158	1.522 (10)
C44—C55	1.492 (10)	C137—C142	1.399 (10)
C45—C46	1.375 (11)	C137—C138	1.403 (10)
C46—C47	1.378 (10)	C138—C139	1.380 (11)
C47—C48	1.419 (9)	C138—C149	1.526 (11)
C48—C49	1.511 (10)	C139—C140	1.392 (11)
C49—C54	1.387 (10)	C140—C141	1.385 (11)
C49—C50	1.412 (10)	C140—C146	1.515 (10)
C50—C51	1.404 (11)	C141—C142	1.400 (11)
C50—C70	1.526 (10)	C142—C143	1.517 (11)
C51—C52	1.386 (11)	C143—C144	1.526 (10)
C52—C53	1.392 (10)	C143—C145	1.540 (10)
C52—C67	1.538 (11)	C146—C148	1.519 (12)
C53—C54	1.392 (11)	C146—C147	1.535 (11)
C54—C64	1.518 (10)	C149—C150	1.533 (10)
C55—C56	1.391 (10)	C149—C151	1.544 (11)
C55—C60	1.433 (10)	C152—C153	1.519 (10)
C56—C57	1.384 (10)	C152—C154	1.531 (10)
C56—C73	1.549 (10)	C155—C156	1.527 (11)
C57—C58	1.385 (10)	C155—C157	1.536 (10)
C58—C59	1.375 (11)	C158—C160	1.524 (11)
C58—C81	1.520 (11)	C158—C159	1.537 (10)
C59—C60	1.377 (11)	C161—C162	1.377 (11)
C60—C61	1.523 (10)	C162—C163	1.360 (11)
C61—C62	1.518 (11)	C163—C164	1.394 (12)
C61—C63	1.539 (10)	C164—C165	1.384 (11)
C64—C66	1.533 (9)	C200—C201	1.380 (13)
C64—C65	1.542 (10)	C200—C205	1.386 (13)
C67—C69	1.519 (11)	C201—C202	1.347 (13)
C67—C68	1.531 (10)	C202—C203	1.396 (12)
C70—C71	1.532 (10)	C203—C204	1.373 (14)
C70—C72	1.534 (11)	C204—C205	1.363 (14)
C73—C75	1.512 (11)	C207—C212	1.358 (12)
C73—C74	1.530 (10)	C207—C208	1.375 (12)
C76—C77	1.382 (12)	C208—C209	1.360 (13)
C77—C78	1.365 (14)	C209—C210	1.400 (13)
C78—C79	1.394 (13)	C212—C211	1.391 (13)
C79—C80	1.393 (11)	C211—C210	1.390 (12)
C1—Ga1—N1	120.1 (3)	C119—N3—C123	118.4 (6)
C1—Ga1—Cl1	120.7 (2)	C119—N3—Ga3	121.2 (5)
N1—Ga1—Cl1	96.65 (19)	C123—N3—Ga3	119.9 (6)
C1—Ga1—Cl2	111.3 (2)	C85—C84—C89	118.9 (6)
N1—Ga1—Cl2	97.5 (2)	C85—C84—Ga3	121.1 (5)
Cl1—Ga1—Cl2	107.40 (8)	C89—C84—Ga3	119.7 (5)
C41—N1—C37	117.9 (7)	C86—C85—C84	119.6 (7)
C41—N1—Ga1	121.0 (6)	C86—C85—C96	115.0 (7)
C37—N1—Ga1	121.1 (5)	C84—C85—C96	125.4 (6)
C6—C1—C2	118.1 (6)	C87—C86—C85	121.6 (7)
C6—C1—Ga1	122.3 (5)	C86—C87—C88	119.0 (7)
C2—C1—Ga1	119.3 (5)	C87—C88—C89	121.7 (7)
C3—C2—C1	119.5 (7)	C88—C89—C84	119.1 (7)
C3—C2—C13	117.7 (7)	C88—C89—C90	116.6 (7)
C1—C2—C13	122.4 (6)	C84—C89—C90	123.8 (6)
C4—C3—C2	120.9 (7)	C91—C90—C95	119.5 (7)
C5—C4—C3	119.5 (7)	C91—C90—C89	118.4 (7)
C4—C5—C6	120.7 (7)	C95—C90—C89	121.8 (7)
C1—C6—C5	121.2 (7)	C92—C91—C90	119.8 (7)
C1—C6—C7	124.2 (6)	C92—C91—C111	118.5 (7)
C5—C6—C7	114.5 (6)	C90—C91—C111	121.7 (7)
C12—C7—C8	120.3 (7)	C93—C92—C91	121.6 (7)
C12—C7—C6	120.3 (6)	C94—C93—C92	117.6 (8)
C8—C7—C6	118.9 (7)	C94—C93—C108	122.5 (7)
C9—C8—C7	118.4 (7)	C92—C93—C108	119.7 (7)
C9—C8—C34	119.6 (7)	C93—C94—C95	123.6 (7)
C7—C8—C34	121.9 (7)	C94—C95—C90	117.7 (7)
C8—C9—C10	122.6 (7)	C94—C95—C105	120.6 (7)
C11—C10—C9	118.0 (7)	C90—C95—C105	121.6 (7)
C11—C10—C31	122.3 (7)	C101—C96—C97	120.3 (7)
C9—C10—C31	119.5 (7)	C101—C96—C85	120.5 (6)
C10—C11—C12	121.6 (7)	C97—C96—C85	118.8 (7)
C7—C12—C11	119.1 (7)	C98—C97—C96	118.2 (7)
C7—C12—C28	121.8 (7)	C98—C97—C114	120.4 (7)
C11—C12—C28	119.0 (7)	C96—C97—C114	121.3 (7)
C18—C13—C14	119.7 (7)	C99—C98—C97	121.5 (7)
C18—C13—C2	118.9 (6)	C98—C99—C100	118.5 (7)
C14—C13—C2	121.4 (7)	C98—C99—C117	118.5 (7)
C15—C14—C13	118.6 (7)	C100—C99—C117	123.0 (7)
C15—C14—C25	121.1 (7)	C101—C100—C99	122.2 (7)
C13—C14—C25	120.3 (7)	C100—C101—C96	119.3 (7)
C14—C15—C16	122.4 (7)	C100—C101—C102	119.0 (7)
C17—C16—C15	117.6 (7)	C96—C101—C102	121.8 (7)
C17—C16—C22	123.4 (7)	C104—C102—C101	113.7 (6)
C15—C16—C22	118.9 (7)	C104—C102—C103	110.0 (6)
C18—C17—C16	123.0 (7)	C101—C102—C103	110.6 (6)
C17—C18—C13	118.5 (7)	C95—C105—C107	109.5 (7)
C17—C18—C19	120.7 (7)	C95—C105—C106	112.2 (6)
C13—C18—C19	120.8 (7)	C107—C105—C106	110.3 (7)
C18—C19—C21	111.8 (6)	C93—C108—C109	114.5 (8)
C18—C19—C20	110.1 (6)	C93—C108—C110	110.4 (7)
C21—C19—C20	110.4 (6)	C109—C108—C110	109.2 (7)
C16—C22—C24	113.6 (7)	C113—C111—C112	111.8 (7)
C16—C22—C23	110.7 (7)	C113—C111—C91	110.1 (6)
C24—C22—C23	108.7 (7)	C112—C111—C91	112.3 (6)
C14—C25—C26	112.6 (6)	C97—C114—C116	111.1 (6)
C14—C25—C27	109.9 (6)	C97—C114—C115	113.3 (6)
C26—C25—C27	110.6 (6)	C116—C114—C115	109.6 (7)
C30—C28—C29	109.8 (6)	C124—C117—C99	110.8 (6)
C30—C28—C12	111.0 (6)	C124—C117—C118	109.6 (7)
C29—C28—C12	113.4 (6)	C99—C117—C118	113.4 (6)
C33—C31—C10	114.2 (7)	N3—C119—C120	122.4 (7)
C33—C31—C32	110.5 (7)	C121—C120—C119	118.7 (8)
C10—C31—C32	109.0 (6)	C122—C121—C120	120.2 (8)
C8—C34—C36	114.9 (6)	C121—C122—C123	119.8 (8)
C8—C34—C35	110.6 (6)	N3—C123—C122	120.5 (8)
C36—C34—C35	108.9 (7)	C125—Ga4—N4	119.7 (3)
N1—C37—C38	122.4 (8)	C125—Ga4—Cl8	121.2 (2)
C37—C38—C39	119.1 (10)	N4—Ga4—Cl8	96.52 (18)
C40—C39—C38	119.3 (9)	C125—Ga4—Cl7	110.4 (2)
C39—C40—C41	118.0 (8)	N4—Ga4—Cl7	99.28 (19)
N1—C41—C40	123.3 (9)	Cl8—Ga4—Cl7	106.90 (8)
C43—Ga2—N2	119.9 (3)	C165—N4—C161	117.4 (7)
C43—Ga2—Cl4	120.6 (2)	C165—N4—Ga4	120.6 (6)
N2—Ga2—Cl4	96.44 (19)	C161—N4—Ga4	121.8 (5)
C43—Ga2—Cl3	111.4 (2)	C130—C125—C126	119.4 (6)
N2—Ga2—Cl3	97.84 (18)	C130—C125—Ga4	119.2 (5)
Cl4—Ga2—Cl3	107.56 (8)	C126—C125—Ga4	120.0 (5)
C80—N2—C76	117.6 (7)	C127—C126—C125	120.0 (7)
C80—N2—Ga2	122.2 (5)	C127—C126—C137	118.0 (7)
C76—N2—Ga2	119.5 (6)	C125—C126—C137	121.5 (6)
C48—C43—C44	118.6 (6)	C128—C127—C126	120.3 (7)
C48—C43—Ga2	121.0 (5)	C127—C128—C129	120.4 (7)
C44—C43—Ga2	119.7 (5)	C128—C129—C130	120.3 (7)
C45—C44—C43	119.7 (7)	C125—C130—C129	119.4 (7)
C45—C44—C55	117.6 (7)	C125—C130—C131	126.3 (6)
C43—C44—C55	122.2 (6)	C129—C130—C131	113.8 (6)
C46—C45—C44	121.9 (7)	C132—C131—C136	119.4 (7)
C45—C46—C47	119.0 (7)	C132—C131—C130	120.2 (7)
C46—C47—C48	121.1 (7)	C136—C131—C130	119.7 (6)
C43—C48—C47	119.5 (7)	C133—C132—C131	118.6 (7)
C43—C48—C49	125.2 (6)	C133—C132—C152	120.2 (6)
C47—C48—C49	115.1 (6)	C131—C132—C152	121.2 (7)
C54—C49—C50	121.3 (7)	C134—C133—C132	122.7 (7)
C54—C49—C48	118.9 (6)	C135—C134—C133	118.1 (7)
C50—C49—C48	119.5 (7)	C135—C134—C155	122.0 (7)
C51—C50—C49	118.3 (7)	C133—C134—C155	119.9 (7)
C51—C50—C70	119.8 (7)	C134—C135—C136	122.1 (8)
C49—C50—C70	121.8 (7)	C135—C136—C131	119.0 (7)
C52—C51—C50	121.0 (7)	C135—C136—C158	119.7 (7)
C51—C52—C53	118.9 (7)	C131—C136—C158	121.3 (7)
C51—C52—C67	118.7 (7)	C142—C137—C138	120.3 (7)
C53—C52—C67	122.4 (7)	C142—C137—C126	121.0 (7)
C52—C53—C54	121.9 (7)	C138—C137—C126	118.7 (6)
C49—C54—C53	118.5 (7)	C139—C138—C137	119.0 (7)
C49—C54—C64	122.2 (7)	C139—C138—C149	119.8 (7)
C53—C54—C64	119.2 (7)	C137—C138—C149	121.2 (7)
C56—C55—C60	118.6 (7)	C138—C139—C140	121.9 (7)
C56—C55—C44	120.0 (6)	C141—C140—C139	118.4 (7)
C60—C55—C44	121.4 (6)	C141—C140—C146	122.4 (7)
C57—C56—C55	120.3 (7)	C139—C140—C146	119.2 (7)
C57—C56—C73	118.2 (7)	C140—C141—C142	121.5 (7)
C55—C56—C73	121.5 (7)	C137—C142—C141	118.7 (7)
C56—C57—C58	121.9 (7)	C137—C142—C143	121.0 (7)
C59—C58—C57	117.3 (7)	C141—C142—C143	120.3 (7)
C59—C58—C81	119.6 (7)	C142—C143—C144	112.6 (6)
C57—C58—C81	123.0 (7)	C142—C143—C145	110.7 (6)
C58—C59—C60	123.8 (7)	C144—C143—C145	110.7 (6)
C59—C60—C55	118.1 (7)	C140—C146—C148	112.2 (7)
C59—C60—C61	121.7 (7)	C140—C146—C147	109.6 (7)
C55—C60—C61	120.2 (7)	C148—C146—C147	111.4 (7)
C62—C61—C60	112.7 (6)	C138—C149—C150	112.5 (6)
C62—C61—C63	110.2 (6)	C138—C149—C151	109.6 (7)
C60—C61—C63	109.0 (6)	C150—C149—C151	110.2 (7)
C54—C64—C66	111.0 (6)	C153—C152—C154	109.5 (7)
C54—C64—C65	113.3 (6)	C153—C152—C132	113.9 (6)
C66—C64—C65	108.5 (6)	C154—C152—C132	110.3 (6)
C69—C67—C68	110.3 (7)	C156—C155—C134	113.9 (6)
C69—C67—C52	113.0 (6)	C156—C155—C157	109.6 (7)
C68—C67—C52	110.7 (7)	C134—C155—C157	110.8 (7)
C50—C70—C71	113.8 (6)	C136—C158—C160	111.6 (6)
C50—C70—C72	111.0 (6)	C136—C158—C159	111.2 (6)
C71—C70—C72	109.2 (6)	C160—C158—C159	109.6 (7)
C75—C73—C74	112.6 (6)	N4—C161—C162	122.8 (7)
C75—C73—C56	109.8 (6)	C163—C162—C161	119.8 (8)
C74—C73—C56	111.9 (6)	C162—C163—C164	118.4 (7)
N2—C76—C77	122.1 (9)	C165—C164—C163	118.4 (7)
C78—C77—C76	119.3 (8)	N4—C165—C164	123.1 (8)
C77—C78—C79	120.2 (8)	C201—C200—C205	118.7 (9)
C80—C79—C78	117.6 (9)	C202—C201—C200	121.3 (8)
N2—C80—C79	123.3 (8)	C201—C202—C203	119.7 (9)
C82—C81—C58	113.9 (7)	C204—C203—C202	119.6 (9)
C82—C81—C83	109.1 (6)	C205—C204—C203	120.1 (8)
C58—C81—C83	110.2 (7)	C204—C205—C200	120.6 (9)
C84—Ga3—N3	120.6 (3)	C212—C207—C208	120.2 (8)
C84—Ga3—Cl5	119.7 (2)	C209—C208—C207	121.3 (8)
N3—Ga3—Cl5	97.36 (18)	C208—C209—C210	119.0 (8)
C84—Ga3—Cl6	110.9 (2)	C207—C212—C211	120.4 (8)
N3—Ga3—Cl6	97.13 (18)	C210—C211—C212	119.1 (8)
Cl5—Ga3—Cl6	108.08 (9)	C211—C210—C209	120.0 (8)
C1—Ga1—N1—C37	−77.2 (6)	C77—C78—C79—C80	0.1 (13)
N1—Ga1—C1—C2	−149.6 (5)	C76—N2—C80—C79	0.5 (11)
C1—C2—C13—C14	−89.7 (8)	Ga2—N2—C80—C79	171.2 (6)
C1—C6—C7—C8	−83.8 (9)	C78—C79—C80—N2	−0.5 (13)
Cl1—Ga1—C1—C2	−29.6 (6)	C59—C58—C81—C82	163.7 (7)
Cl2—Ga1—C1—C2	97.6 (5)	C57—C58—C81—C82	−20.3 (10)
C43—Ga2—N2—C80	83.7 (6)	C59—C58—C81—C83	−73.4 (9)
N2—Ga2—C43—C44	147.1 (5)	C57—C58—C81—C83	102.7 (9)
C43—C48—C49—C50	81.2 (9)	Cl5—Ga3—N3—C119	−147.5 (5)
C43—C44—C55—C60	90.7 (8)	Cl6—Ga3—N3—C119	−38.2 (5)
Cl4—Ga2—C43—C44	27.7 (6)	C84—Ga3—N3—C123	−106.5 (6)
Cl3—Ga2—C43—C44	−99.7 (5)	Cl6—Ga3—N3—C123	134.0 (5)
C84—Ga3—N3—C119	81.3 (6)	N3—Ga3—C84—C85	−35.3 (7)
N3—Ga3—C84—C89	150.9 (5)	Cl5—Ga3—C84—C85	−156.0 (5)
C84—C85—C96—C97	83.9 (9)	Cl6—Ga3—C84—C85	77.1 (6)
C84—C89—C90—C95	94.2 (9)	C89—C84—C85—C86	2.5 (10)
Cl5—Ga3—C84—C89	30.2 (6)	Ga3—C84—C85—C86	−171.4 (5)
Cl6—Ga3—C84—C89	−96.7 (6)	C89—C84—C85—C96	−176.1 (7)
C125—Ga4—N4—C161	82.2 (6)	Ga3—C84—C85—C96	10.1 (10)
N4—Ga4—C125—C126	150.2 (5)	C84—C85—C86—C87	0.9 (11)
C125—C126—C137—C142	96.4 (8)	C96—C85—C86—C87	179.6 (7)
C125—C130—C131—C132	78.2 (9)	C85—C86—C87—C88	−2.9 (12)
Cl7—Ga4—C125—C126	−95.6 (5)	C86—C87—C88—C89	1.5 (12)
Cl8—Ga4—C125—C126	30.4 (6)	C87—C88—C89—C84	1.8 (11)
Cl1—Ga1—N1—C41	−24.7 (6)	C87—C88—C89—C90	−171.1 (7)
Cl3—Ga2—N2—C80	−36.5 (6)	C85—C84—C89—C88	−3.8 (10)
Cl5—Ga3—N3—C123	24.6 (5)	Ga3—C84—C89—C88	170.1 (5)
Cl8—Ga4—N4—C165	27.9 (6)	C85—C84—C89—C90	168.6 (7)
C1—Ga1—N1—C41	106.7 (6)	Ga3—C84—C89—C90	−17.5 (10)
Cl2—Ga1—N1—C41	−133.3 (6)	C88—C89—C90—C91	81.5 (8)
Cl1—Ga1—N1—C37	151.4 (6)	C84—C89—C90—C91	−91.1 (9)
Cl2—Ga1—N1—C37	42.8 (6)	C88—C89—C90—C95	−93.2 (9)
N1—Ga1—C1—C6	36.6 (7)	C95—C90—C91—C92	−2.6 (11)
Cl1—Ga1—C1—C6	156.6 (5)	C89—C90—C91—C92	−177.4 (7)
Cl2—Ga1—C1—C6	−76.2 (6)	C95—C90—C91—C111	174.9 (7)
C6—C1—C2—C3	1.1 (10)	C89—C90—C91—C111	0.0 (10)
Ga1—C1—C2—C3	−173.0 (5)	C90—C91—C92—C93	2.8 (11)
C6—C1—C2—C13	−171.3 (6)	C111—C91—C92—C93	−174.8 (7)
Ga1—C1—C2—C13	14.6 (9)	C91—C92—C93—C94	−0.9 (11)
C1—C2—C3—C4	0.2 (11)	C91—C92—C93—C108	174.7 (7)
C13—C2—C3—C4	173.0 (7)	C92—C93—C94—C95	−1.2 (12)
C2—C3—C4—C5	−1.9 (11)	C108—C93—C94—C95	−176.7 (7)
C3—C4—C5—C6	2.4 (11)	C93—C94—C95—C90	1.3 (12)
C2—C1—C6—C5	−0.6 (10)	C93—C94—C95—C105	179.8 (7)
Ga1—C1—C6—C5	173.3 (5)	C91—C90—C95—C94	0.6 (10)
C2—C1—C6—C7	175.9 (6)	C89—C90—C95—C94	175.3 (7)
Ga1—C1—C6—C7	−10.2 (10)	C91—C90—C95—C105	−177.8 (7)
C4—C5—C6—C1	−1.1 (11)	C89—C90—C95—C105	−3.2 (11)
C4—C5—C6—C7	−178.0 (7)	C86—C85—C96—C101	77.0 (9)
C1—C6—C7—C12	103.7 (8)	C84—C85—C96—C101	−104.3 (8)
C5—C6—C7—C12	−79.6 (8)	C86—C85—C96—C97	−94.7 (8)
C5—C6—C7—C8	93.0 (8)	C101—C96—C97—C98	−1.7 (10)
C12—C7—C8—C9	1.7 (10)	C85—C96—C97—C98	170.0 (6)
C6—C7—C8—C9	−170.9 (6)	C101—C96—C97—C114	−178.8 (6)
C12—C7—C8—C34	178.0 (7)	C85—C96—C97—C114	−7.1 (10)
C6—C7—C8—C34	5.4 (10)	C96—C97—C98—C99	0.1 (10)
C7—C8—C9—C10	−0.6 (11)	C114—C97—C98—C99	177.2 (6)
C34—C8—C9—C10	−177.0 (7)	C97—C98—C99—C100	2.1 (10)
C8—C9—C10—C11	−0.7 (11)	C97—C98—C99—C117	−178.0 (6)
C8—C9—C10—C31	175.3 (7)	C98—C99—C100—C101	−2.8 (10)
C9—C10—C11—C12	0.8 (11)	C117—C99—C100—C101	177.3 (6)
C31—C10—C11—C12	−175.0 (7)	C99—C100—C101—C96	1.2 (10)
C8—C7—C12—C11	−1.6 (10)	C99—C100—C101—C102	−176.4 (6)
C6—C7—C12—C11	170.9 (6)	C97—C96—C101—C100	1.1 (10)
C8—C7—C12—C28	−178.1 (6)	C85—C96—C101—C100	−170.5 (6)
C6—C7—C12—C28	−5.6 (10)	C97—C96—C101—C102	178.6 (6)
C10—C11—C12—C7	0.3 (11)	C85—C96—C101—C102	7.0 (10)
C10—C11—C12—C28	176.9 (7)	C100—C101—C102—C104	−48.7 (9)
C3—C2—C13—C18	−80.3 (8)	C96—C101—C102—C104	133.8 (7)
C1—C2—C13—C18	92.2 (9)	C100—C101—C102—C103	75.6 (8)
C3—C2—C13—C14	97.7 (8)	C96—C101—C102—C103	−101.9 (8)
C18—C13—C14—C15	−2.6 (10)	C94—C95—C105—C107	−73.5 (9)
C2—C13—C14—C15	179.4 (6)	C90—C95—C105—C107	104.9 (9)
C18—C13—C14—C25	174.7 (6)	C94—C95—C105—C106	49.4 (10)
C2—C13—C14—C25	−3.3 (10)	C90—C95—C105—C106	−132.2 (8)
C13—C14—C15—C16	−0.8 (10)	C94—C93—C108—C109	−42.5 (11)
C25—C14—C15—C16	−178.1 (6)	C92—C93—C108—C109	142.1 (8)
C14—C15—C16—C17	3.3 (11)	C94—C93—C108—C110	81.3 (10)
C14—C15—C16—C22	−174.1 (7)	C92—C93—C108—C110	−94.1 (9)
C15—C16—C17—C18	−2.6 (11)	C92—C91—C111—C113	67.9 (9)
C22—C16—C17—C18	174.7 (7)	C90—C91—C111—C113	−109.6 (8)
C16—C17—C18—C13	−0.7 (11)	C92—C91—C111—C112	−57.4 (10)
C16—C17—C18—C19	177.8 (7)	C90—C91—C111—C112	125.1 (8)
C14—C13—C18—C17	3.3 (10)	C98—C97—C114—C116	−89.8 (8)
C2—C13—C18—C17	−178.6 (6)	C96—C97—C114—C116	87.3 (9)
C14—C13—C18—C19	−175.2 (6)	C98—C97—C114—C115	34.2 (9)
C2—C13—C18—C19	2.9 (10)	C96—C97—C114—C115	−148.7 (7)
C17—C18—C19—C21	56.9 (10)	C98—C99—C117—C124	−86.8 (9)
C13—C18—C19—C21	−124.7 (7)	C100—C99—C117—C124	93.0 (8)
C17—C18—C19—C20	−66.3 (9)	C98—C99—C117—C118	149.4 (7)
C13—C18—C19—C20	112.2 (8)	C100—C99—C117—C118	−30.7 (10)
C17—C16—C22—C24	26.7 (11)	C123—N3—C119—C120	1.7 (11)
C15—C16—C22—C24	−156.1 (7)	Ga3—N3—C119—C120	174.0 (6)
C17—C16—C22—C23	−96.0 (9)	N3—C119—C120—C121	−1.8 (12)
C15—C16—C22—C23	81.3 (9)	C119—C120—C121—C122	0.8 (12)
C15—C14—C25—C26	−39.1 (10)	C120—C121—C122—C123	0.2 (13)
C13—C14—C25—C26	143.6 (7)	C119—N3—C123—C122	−0.7 (11)
C15—C14—C25—C27	84.6 (8)	Ga3—N3—C123—C122	−173.1 (6)
C13—C14—C25—C27	−92.7 (8)	C121—C122—C123—N3	−0.2 (13)
C7—C12—C28—C30	102.5 (8)	C125—Ga4—N4—C165	−103.8 (6)
C11—C12—C28—C30	−74.0 (8)	Cl7—Ga4—N4—C165	136.3 (5)
C7—C12—C28—C29	−133.3 (7)	Cl8—Ga4—N4—C161	−146.1 (5)
C11—C12—C28—C29	50.1 (9)	Cl7—Ga4—N4—C161	−37.7 (6)
C11—C10—C31—C33	−20.1 (10)	N4—Ga4—C125—C130	−43.5 (6)
C9—C10—C31—C33	164.1 (7)	Cl8—Ga4—C125—C130	−163.3 (5)
C11—C10—C31—C32	104.0 (9)	Cl7—Ga4—C125—C130	70.7 (6)
C9—C10—C31—C32	−71.8 (9)	C130—C125—C126—C127	0.5 (10)
C9—C8—C34—C36	−35.3 (10)	Ga4—C125—C126—C127	166.7 (5)
C7—C8—C34—C36	148.5 (7)	C130—C125—C126—C137	171.6 (7)
C9—C8—C34—C35	88.5 (8)	Ga4—C125—C126—C137	−22.1 (9)
C7—C8—C34—C35	−87.8 (9)	C125—C126—C127—C128	−1.3 (11)
C41—N1—C37—C38	−0.5 (12)	C137—C126—C127—C128	−172.8 (7)
Ga1—N1—C37—C38	−176.7 (7)	C126—C127—C128—C129	3.3 (12)
N1—C37—C38—C39	0.5 (14)	C127—C128—C129—C130	−4.4 (12)
C37—C38—C39—C40	0.4 (14)	C126—C125—C130—C129	−1.5 (10)
C38—C39—C40—C41	−1.3 (13)	Ga4—C125—C130—C129	−167.9 (5)
C37—N1—C41—C40	−0.5 (11)	C126—C125—C130—C131	−173.5 (7)
Ga1—N1—C41—C40	175.7 (6)	Ga4—C125—C130—C131	20.1 (10)
C39—C40—C41—N1	1.4 (12)	C128—C129—C130—C125	3.5 (11)
Cl4—Ga2—N2—C80	−145.3 (6)	C128—C129—C130—C131	176.5 (7)
C43—Ga2—N2—C76	−105.7 (6)	C129—C130—C131—C132	−94.2 (8)
Cl4—Ga2—N2—C76	25.3 (5)	C125—C130—C131—C136	−111.5 (8)
Cl3—Ga2—N2—C76	134.1 (5)	C129—C130—C131—C136	76.1 (8)
N2—Ga2—C43—C48	−41.9 (7)	C136—C131—C132—C133	−2.2 (10)
Cl4—Ga2—C43—C48	−161.3 (5)	C130—C131—C132—C133	168.1 (6)
Cl3—Ga2—C43—C48	71.3 (6)	C136—C131—C132—C152	179.9 (6)
C48—C43—C44—C45	0.3 (10)	C130—C131—C132—C152	−9.8 (10)
Ga2—C43—C44—C45	171.5 (5)	C131—C132—C133—C134	0.4 (10)
C48—C43—C44—C55	172.4 (7)	C152—C132—C133—C134	178.2 (6)
Ga2—C43—C44—C55	−16.4 (9)	C132—C133—C134—C135	2.9 (10)
C43—C44—C45—C46	−0.5 (11)	C132—C133—C134—C155	−178.3 (6)
C55—C44—C45—C46	−172.9 (7)	C133—C134—C135—C136	−4.4 (10)
C44—C45—C46—C47	2.6 (12)	C155—C134—C135—C136	176.9 (6)
C45—C46—C47—C48	−4.6 (11)	C134—C135—C136—C131	2.5 (10)
C44—C43—C48—C47	−2.2 (10)	C134—C135—C136—C158	−177.0 (6)
Ga2—C43—C48—C47	−173.3 (5)	C132—C131—C136—C135	0.9 (10)
C44—C43—C48—C49	−176.7 (7)	C130—C131—C136—C135	−169.5 (6)
Ga2—C43—C48—C49	12.2 (10)	C132—C131—C136—C158	−179.6 (6)
C46—C47—C48—C43	4.4 (11)	C130—C131—C136—C158	10.1 (10)
C46—C47—C48—C49	179.5 (7)	C127—C126—C137—C142	−92.2 (8)
C43—C48—C49—C54	−106.1 (8)	C127—C126—C137—C138	87.0 (8)
C47—C48—C49—C54	79.2 (8)	C125—C126—C137—C138	−84.3 (9)
C47—C48—C49—C50	−93.5 (8)	C142—C137—C138—C139	−5.1 (10)
C54—C49—C50—C51	−1.6 (10)	C126—C137—C138—C139	175.6 (6)
C48—C49—C50—C51	170.9 (6)	C142—C137—C138—C149	172.2 (6)
C54—C49—C50—C70	−178.6 (6)	C126—C137—C138—C149	−7.0 (10)
C48—C49—C50—C70	−6.0 (10)	C137—C138—C139—C140	2.2 (11)
C49—C50—C51—C52	0.0 (10)	C149—C138—C139—C140	−175.1 (7)
C70—C50—C51—C52	177.0 (6)	C138—C139—C140—C141	2.8 (11)
C50—C51—C52—C53	2.7 (11)	C138—C139—C140—C146	−175.4 (7)
C50—C51—C52—C67	−178.7 (6)	C139—C140—C141—C142	−5.0 (11)
C51—C52—C53—C54	−3.9 (11)	C146—C140—C141—C142	173.1 (7)
C67—C52—C53—C54	177.6 (6)	C138—C137—C142—C141	3.0 (10)
C50—C49—C54—C53	0.4 (10)	C126—C137—C142—C141	−177.8 (6)
C48—C49—C54—C53	−172.1 (6)	C138—C137—C142—C143	−174.8 (6)
C50—C49—C54—C64	177.0 (6)	C126—C137—C142—C143	4.5 (10)
C48—C49—C54—C64	4.4 (10)	C140—C141—C142—C137	2.1 (11)
C52—C53—C54—C49	2.4 (10)	C140—C141—C142—C143	179.9 (7)
C52—C53—C54—C64	−174.3 (6)	C137—C142—C143—C144	−138.3 (7)
C45—C44—C55—C56	81.4 (8)	C141—C142—C143—C144	44.0 (10)
C43—C44—C55—C56	−90.8 (9)	C137—C142—C143—C145	97.2 (8)
C45—C44—C55—C60	−97.1 (8)	C141—C142—C143—C145	−80.5 (8)
C60—C55—C56—C57	−3.2 (10)	C141—C140—C146—C148	61.5 (10)
C44—C55—C56—C57	178.3 (6)	C139—C140—C146—C148	−120.4 (8)
C60—C55—C56—C73	176.0 (6)	C141—C140—C146—C147	−62.7 (10)
C44—C55—C56—C73	−2.5 (10)	C139—C140—C146—C147	115.3 (8)
C55—C56—C57—C58	2.5 (11)	C139—C138—C149—C150	−55.7 (10)
C73—C56—C57—C58	−176.7 (6)	C137—C138—C149—C150	127.0 (8)
C56—C57—C58—C59	0.1 (11)	C139—C138—C149—C151	67.3 (9)
C56—C57—C58—C81	−176.1 (7)	C137—C138—C149—C151	−110.0 (8)
C57—C58—C59—C60	−1.9 (11)	C133—C132—C152—C153	32.7 (9)
C81—C58—C59—C60	174.4 (7)	C131—C132—C152—C153	−149.5 (7)
C58—C59—C60—C55	1.1 (11)	C133—C132—C152—C154	−90.9 (8)
C58—C59—C60—C61	179.5 (7)	C131—C132—C152—C154	87.0 (8)
C56—C55—C60—C59	1.5 (10)	C135—C134—C155—C156	−34.1 (10)
C44—C55—C60—C59	180.0 (7)	C133—C134—C155—C156	147.2 (7)
C56—C55—C60—C61	−176.9 (6)	C135—C134—C155—C157	89.9 (9)
C44—C55—C60—C61	1.6 (10)	C133—C134—C155—C157	−88.8 (9)
C59—C60—C61—C62	42.4 (10)	C135—C136—C158—C160	−48.6 (9)
C55—C60—C61—C62	−139.3 (7)	C131—C136—C158—C160	131.8 (7)
C59—C60—C61—C63	−80.3 (9)	C135—C136—C158—C159	74.1 (8)
C55—C60—C61—C63	98.0 (8)	C131—C136—C158—C159	−105.5 (8)
C49—C54—C64—C66	−102.7 (8)	C165—N4—C161—C162	0.6 (11)
C53—C54—C64—C66	73.8 (8)	Ga4—N4—C161—C162	174.8 (6)
C49—C54—C64—C65	134.9 (7)	N4—C161—C162—C163	−0.2 (12)
C53—C54—C64—C65	−48.6 (9)	C161—C162—C163—C164	−0.2 (12)
C51—C52—C67—C69	158.5 (7)	C162—C163—C164—C165	0.2 (12)
C53—C52—C67—C69	−22.9 (10)	C161—N4—C165—C164	−0.6 (11)
C51—C52—C67—C68	−77.1 (9)	Ga4—N4—C165—C164	−174.8 (6)
C53—C52—C67—C68	101.4 (8)	C163—C164—C165—N4	0.3 (12)
C51—C50—C70—C71	32.0 (9)	C205—C200—C201—C202	1.6 (15)
C49—C50—C70—C71	−151.0 (7)	C200—C201—C202—C203	−1.2 (16)
C51—C50—C70—C72	−91.6 (8)	C201—C202—C203—C204	0.2 (16)
C49—C50—C70—C72	85.3 (9)	C202—C203—C204—C205	0.3 (16)
C57—C56—C73—C75	65.7 (8)	C203—C204—C205—C200	0.1 (16)
C55—C56—C73—C75	−113.5 (8)	C201—C200—C205—C204	−1.1 (15)
C57—C56—C73—C74	−60.0 (9)	C212—C207—C208—C209	2.0 (15)
C55—C56—C73—C74	120.7 (8)	C207—C208—C209—C210	−2.7 (15)
C80—N2—C76—C77	−0.1 (11)	C208—C207—C212—C211	−0.9 (15)
Ga2—N2—C76—C77	−171.1 (6)	C207—C212—C211—C210	0.6 (15)
N2—C76—C77—C78	−0.2 (13)	C212—C211—C210—C209	−1.4 (15)
C76—C77—C78—C79	0.2 (13)	C208—C209—C210—C211	2.4 (15)