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Acta Cryst. (2001). E57, m97-m99  [ doi:10.1107/S160053680100263X ]

Diazido[bis(2-pyridyl)amine-N,N']cobalt(III) perchlorate

M. Du, Y.-M. Guo, X.-B. Leng and X.-H. Bu

Abstract: The title complex, [Co(C10H9N3)2(N3)2]ClO4, consists of discrete cations and anions. The central CoIII ion has an approximate octahedral geometry, coordinated with four N atoms of the pyridine rings of the bis(2-pyridyl)amine ligands in a trans-trans mode, and with two terminal N atoms of the azide anions. The crystal structure is stabilized by N-H...O hydrogen bonds between the amino groups and the perchlorate anions.


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