Acta Cryst. (2001). E57, m352-m354  [ doi:10.1107/S1600536801011448 ]

Carbonyl(ferrocenyldiphenylphosphine)(tropolonato)rhodium(I)

G. Steyl, S. Otto and A. Roodt

Abstract: The square-planar Rh^I complex, [Rh(trop)(PFcPh₂)(CO)] (tropH = 2-hydroxy-2,4,6-cycloheptatrienone, C₇H₆O₂, and PFcPh₂ = ferrocenyldiphenylphosphine, C₂₂H₁₉FeP), contains a five-membered chelate ring. The most important bond lengths and angles include Rh-O 2.0838 (14) Å (trans to P) and Rh-O 2.0487 (14) Å (trans to CO), Rh-P 2.2395 (5) Å, Rh-C 1.803 (2) Å, and O-Rh-O 77.56 (6)° and P-Rh-C 89.73 (7)°.

Online 13 July 2001

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