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Acta Cryst. (2001). E57, m480-m482 [ doi:10.1107/S1600536801015318 ]
Abstract: In the crystal structure of the title compound, [ZnCl2{(C6H5)3PO}2]·2THF (THF is tetrahydrofuran, C4H8O), the ZnII ion is four-coordinated by two Cl atoms and two O atoms in a distorted tetrahedral geometry. Additionally, two solvent THF molecules occupy the open space in the unit cell, not bonding to the Zn atom. The Zn-Cl distances are 2.2108 (6) and 2.2165 (6) Å, and the Zn-O distances are 1.9851 (15) and 1.9751 (15) Å. Within the tetrahedral coordination sphere around the central Zn atom, the bond angles are O1-Zn-O2 98.16 (6)° and Cl1-Zn-Cl2 120.55 (2)°; the four Cl-Zn-O bond angles range from 107.43 (4) to 110.55 (4)°.
Online 29 September 2001
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