Acta Cryst. (2001). E57, m441-m443  [ doi:10.1107/S1600536801014817 ]

Aqua(N,N'-disalicylideneethylenediamino-N,N',O,O')(4,5-imidazoledicarboxylato-O)manganese(III) monohydrate

D.-G. Huang, X.-F. Zhang, H.-P. Zhu, C.-N. Chen and Q.-T. Liu

Abstract: In the title compound, [Mn^III(salen)(OCOC₃H₂N₂COOH)(H₂O)]·H₂O, (H₂salen = N,N'-disalicylideneethylenediamine, C₁₆H₁₄N₂O₂), two N and two O atoms from salen chelate to the Mn^III ion, forming a distorted octahedral coordination sphere together with two other axial O atoms from a carboxyl group and a water molecule. Extended intermolecular hydrogen bonds are observed to link the complex molecules, forming a one-dimensional chain structure.

Online 20 September 2001

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