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Acta Cryst. (2001). E57, m428-m430    [ doi:10.1107/S1600536801014428 ]

Bis([mu]-1-acetimido-4-phenylpyrazolone-N2:O)-[mu]-oxo-tetraoxodimolybdenum(VI) as its diacetonitrile adduct: a novel dinuclear molybdenum complex bridged by a 1-acetimido-4-phenylpyrazolone ligand

S.-L. Guo, M. Wagner and M. Bolte

Abstract: The title compound, [Mo2O5(C11H10N3O)2]·2CH3CN, is a dinuclear molybdenum complex. It has crystallographic C2 symmetry with the central O atom located on a twofold rotation axis. The Mo atoms, octahedrally coordinated by four O and two N atoms, are bridged by a [mu]-O and two [mu]-pyrazolonyl groups. An intermolecular N-H...O hydrogen bond stabilizes the crystal packing.

Online 20 September 2001


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