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Acta Cryst. (2001). E57, o1102-o1104 [ doi:10.1107/S1600536801017391 ]
Abstract: In the title compound, C5H12NO2+·C4H3O4-, the amino acid exists in the cationic form and the maleic acid molecule in the mono-ionized state. The intramolecular hydrogen bond observed between atoms O3 and O5 in the semimaleate anion is found to be asymmetric. The non-polar side chains of the DL-valinium cations form alternating hydrophobic columns down the a axis. The crystal structure is stabilized by O-H
O and N-H
O hydrogen bonds.
Online 27 October 2001
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