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Acta Cryst. (2001). E57, m501-m503  [ doi:10.1107/S1600536801015835 ]

catena-Poly[[[diaquabis[cis-2-methyl-but-2-enedioate(1-)-O]nickel(II)]-[mu]-4,4'-bipyridine-N:N'] dihydrate]

J.-H. Liao, C.-T. Su and C.-C. Hsu

Abstract: In the title compound, {[Ni(H2O)2(C10H8N2)(C5H5O4)2]·2H2O}n, (I), the NiII atom is located at a center of inversion, and the bridging 4,4'-bipyridine has a center of symmetry. Each NiII is in an octahedral environment, coordinated by two H2O, two cis-2-methyl-but-2-enedioate (citraconate) and two bridging 4,4'-bipyridine ligands to generate linear chains which interact with the water molecules of crystallization to form a hydrogen-bonding network.


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