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Acta Cryst. (2001). E57, m603-m604  [ doi:10.1107/S1600536801019833 ]

(N,N-Diethyldithiocarbamato)(tricyclohexylphosphine)gold(I)

S. Y. Ho and E. R. T. Tiekink

Abstract: The Au atom in the title compound, (c-C6H11)3PAu(S2CNEt2) or [Au(C18H33P)(C5H10NS2)], exists in a linear geometry so that Au-S is 2.3340  (11), Au-P is 2.2599  (10)  Å and the angle at gold is 171.61  (4)°. The distortion from linearity may be traced to the close approach of the non-coordinating S atom which is separated from the Au atom by 3.0859  (13)  Å.

Online 30 November 2001


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