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Acta Cryst. (2002). E58, m58-m60 [ doi:10.1107/S1600536802001125 ]
Abstract: Diaquadichlorodiphenyltin(IV) 18-crown-6, [SnCl2(C6H5)2(H2O)2]·C12H24O6, adopts an all-trans octahedral configuration at the Sn atom. The coordinated water molecule forms a pair of hydrogen bonds to the polyether to furnish a linear hydrogen-bonded chain structure. There are two half-molecules of each component in the asymmetric unit, with the Sn atoms and the centres of the crown ethers lying on inversion centres.
Online 31 January 2002
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