Acta Cryst. (2002). E58, m70-m71  [ doi:10.1107/S1600536802001356 ]

Tetracarbonylbis[(pentafluoroethyl)diphenylphosphine]chromium(0)

R. G. Peters, M. V. Golynskiy and R. G. Baughman

Abstract: In the title complex, [Cr(C₁₄H₁₀F₅P)₂(CO)₄], a slightly distorted octahedral geometry is present about the Cr atom which sits at a center of inversion, while the groups about the P atom are in a slightly distorted tetrahedral arrangement. The Cr-P-C angles are larger than the C-P-C angles of the ligand. The -C₂F₅ groups are in the E configuration across the center of inversion.

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