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Acta Cryst. (2002). E58, m86-m87  [ doi:10.1107/S1600536802002064 ]

(N,N-Diethyldithiocarbamato)[tris(p-methoxyphenyl)phosphine]gold(I)

S. Y. Ho and E. R. T. Tiekink

Abstract: Sulfur- and phosphorus-donor atoms define an approximately linear geometry about the Au atom in the title compound, [Au(S2CNEt2){(p-MeO-C6H4)3P}]. The key geometric parameters are Au-S 2.3350  (8)  Å, Au-P 2.2528  (7)  Å and an S-Au-P angle of 169.80  (3)°. The deviation from linearity is ascribed to a close intramolecular Au...S contact of 3.0564  (8)  Å.

Online 8 February 2002


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