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Acta Cryst. (2002). E58, m125-m126  [ doi:10.1107/S1600536802003070 ]

unsym-fac-(exo-OH)-[Co(dien)(dapo)(N3)][ZnCl4]

R. J. Browne, D. A. Buckingham, A. G. Blackman and C. R. Clark

Abstract: Structural analysis of the title compound, [N-(2-aminoethyl)-1,2-ethanediamine]azido(2-hydroxy-1,3-propanediamine)cobalt(III) tetrachlorozincate(II), unsym-fac-(exo-OH)-[Co(dien)(dapo)N3]ZnCl4 or [Co(N3)(C4H13N3)(C3H10N2O)][ZnCl4], confirms both the facial configuration of the N-(2-aminoethyl)-1,2-ethanediamine (dien) ligand and the exo stereochemistry of the OH substituent of the 2-hydroxy-1,3-propanediamine (dapo) ligand relative to the azide ligand.

Online 22 February 2002


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