The crystals of the title compound, {[Co(en)2(MeCN)]2(μ-O2)}(CF3SO3)4 or [Co2(O2)(C2H3N)2(C2H8N2)4](CF3O3S)4, are built of binuclear tetracations and trifluoromethanesulfonate anions. The cation occupies a special position on the inversion center; the separation between the Co atoms, which have a slightly distorted octahedral coordination, is 4.4966 (7) Å, with Co—N(MeCN), Co—O, and average Co—N(en) distances of 1.938 (2), 1.8736 (17), and 1.950 Å, respectively. Both acetonitriles are trans to the O—O bridge, the O—O distance being 1.496 (3) Å. The [Co(en)2] moieties have δδ and the inversion-related λλ conformations.
Supporting information
CCDC reference: 183762
Key indicators
- Single-crystal X-ray study
- T = 100 K
- Mean (C-C) = 0.004 Å
- R factor = 0.040
- wR factor = 0.100
- Data-to-parameter ratio = 13.3
checkCIF results
No syntax errors found
ADDSYM reports no extra symmetry
General Notes
FORMU_01 There is a discrepancy between the atom counts in the
_chemical_formula_sum and _chemical_formula_moiety. This is
usually due to the moiety formula being in the wrong format.
Atom count from _chemical_formula_sum: C16 H38 Co2 F12 N10 O14 S4
Atom count from _chemical_formula_moiety:C13 H38 Co2 F3 N10 O5 S4
Data collection: SMART (Bruker, 2000); cell refinement: SMART and SAINT; data reduction: SAINT (Bruker, 2000); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXTL.
µ-Peroxo-bis[acetonitrilebis(ethylenediamine)cobalt(III)] tetratriflate
top
Crystal data top
[Co2(O2)(C2H3N)2(C2H8N2)4](CF3O3S)4 | F(000) = 1084 |
Mr = 1068.64 | Dx = 1.809 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 13.164 (1) Å | Cell parameters from 6714 reflections |
b = 8.3883 (7) Å | θ = 2.3–32.2° |
c = 17.939 (2) Å | µ = 1.18 mm−1 |
β = 97.869 (2)° | T = 100 K |
V = 1962.2 (3) Å3 | Plate, brown |
Z = 2 | 0.35 × 0.13 × 0.04 mm |
Data collection top
Bruker CCD area-detector diffractometer | 4487 independent reflections |
Radiation source: fine-focus sealed tube | 3403 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.053 |
Detector resolution: 8.333 pixels mm-1 | θmax = 27.5°, θmin = 1.8° |
ω scans | h = −17→17 |
Absorption correction: multi-scan (SADABS; Sheldrick, 2001) | k = −10→10 |
Tmin = 0.661, Tmax = 0.954 | l = −23→23 |
17919 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.040 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.100 | All H-atom parameters refined |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0534P)2] where P = (Fo2 + 2Fc2)/3 |
4487 reflections | (Δ/σ)max < 0.001 |
338 parameters | Δρmax = 1.49 e Å−3 |
0 restraints | Δρmin = −0.46 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. There is a large peak (1.493) between O atoms of a
trifluoromethanesulfonate anion. This was not modeled for disorder. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Co1 | 0.95240 (3) | 0.47270 (4) | 0.614997 (19) | 0.01424 (11) | |
N1 | 0.87235 (17) | 0.6585 (3) | 0.57791 (14) | 0.0188 (5) | |
H1C | 0.8891 (19) | 0.742 (3) | 0.6075 (15) | 0.011 (7)* | |
H1D | 0.887 (2) | 0.674 (4) | 0.5330 (18) | 0.030 (9)* | |
N2 | 0.82478 (17) | 0.3506 (3) | 0.59154 (13) | 0.0184 (5) | |
H2C | 0.829 (2) | 0.252 (4) | 0.5700 (16) | 0.027 (8)* | |
H2D | 0.797 (2) | 0.324 (4) | 0.6311 (18) | 0.032 (9)* | |
N3 | 1.07747 (17) | 0.5956 (3) | 0.63948 (14) | 0.0210 (5) | |
H3C | 1.084 (2) | 0.649 (4) | 0.6009 (19) | 0.033 (9)* | |
H3D | 1.074 (2) | 0.669 (4) | 0.6781 (18) | 0.028 (8)* | |
N4 | 1.03347 (19) | 0.2871 (3) | 0.65166 (14) | 0.0203 (5) | |
H4C | 1.004 (2) | 0.226 (3) | 0.6725 (16) | 0.016 (8)* | |
H4D | 1.057 (2) | 0.245 (4) | 0.6161 (18) | 0.027 (9)* | |
N5 | 0.91739 (17) | 0.5045 (2) | 0.71539 (12) | 0.0165 (5) | |
O1 | 0.98294 (14) | 0.4264 (2) | 0.51833 (10) | 0.0179 (4) | |
C1 | 0.7616 (2) | 0.6199 (3) | 0.57373 (17) | 0.0235 (6) | |
H1A | 0.722 (2) | 0.695 (3) | 0.5432 (16) | 0.023 (8)* | |
H1B | 0.740 (2) | 0.625 (3) | 0.6209 (16) | 0.015 (7)* | |
C1S | 0.6427 (2) | 0.0119 (3) | 0.43952 (18) | 0.0277 (7) | |
C2 | 0.7480 (2) | 0.4502 (3) | 0.54432 (16) | 0.0227 (6) | |
H2A | 0.678 (2) | 0.412 (3) | 0.5469 (15) | 0.017 (7)* | |
H2B | 0.764 (2) | 0.441 (3) | 0.4952 (16) | 0.011 (7)* | |
C2S | 1.0129 (2) | 0.9958 (4) | 0.84590 (19) | 0.0323 (7) | |
C3 | 1.1653 (2) | 0.4865 (4) | 0.66262 (18) | 0.0249 (6) | |
H3A | 1.215 (2) | 0.544 (3) | 0.6899 (18) | 0.026 (8)* | |
H3B | 1.192 (2) | 0.460 (3) | 0.6205 (18) | 0.019 (7)* | |
C4 | 1.1261 (2) | 0.3428 (4) | 0.70069 (16) | 0.0248 (6) | |
H4A | 1.177 (2) | 0.263 (4) | 0.7093 (16) | 0.031 (8)* | |
H4B | 1.107 (2) | 0.369 (3) | 0.7438 (16) | 0.016 (7)* | |
C5 | 0.8905 (2) | 0.5083 (3) | 0.77336 (15) | 0.0173 (5) | |
C6 | 0.8576 (2) | 0.5081 (4) | 0.84776 (16) | 0.0243 (6) | |
H6A | 0.880 (3) | 0.403 (4) | 0.8718 (19) | 0.044 (10)* | |
H6B | 0.784 (3) | 0.528 (4) | 0.839 (2) | 0.047 (11)* | |
H6C | 0.897 (3) | 0.598 (4) | 0.876 (2) | 0.050 (11)* | |
S1 | 0.78269 (6) | 0.00307 (8) | 0.45621 (4) | 0.02356 (17) | |
S2 | 0.91535 (5) | 0.96188 (8) | 0.76462 (4) | 0.01970 (16) | |
O2 | 0.80552 (16) | 0.0201 (2) | 0.53733 (12) | 0.0301 (5) | |
O3 | 0.81203 (17) | 0.1364 (3) | 0.41367 (14) | 0.0426 (6) | |
O4 | 0.80549 (15) | −0.1526 (2) | 0.42878 (11) | 0.0271 (5) | |
O5 | 0.88520 (15) | 1.1223 (2) | 0.74171 (12) | 0.0272 (5) | |
O6 | 0.83780 (15) | 0.8702 (2) | 0.79523 (11) | 0.0261 (4) | |
O7 | 0.97052 (17) | 0.8776 (2) | 0.71217 (12) | 0.0360 (5) | |
F1 | 0.60858 (14) | 0.1520 (2) | 0.46152 (13) | 0.0497 (6) | |
F2 | 0.60654 (16) | −0.0094 (3) | 0.36709 (11) | 0.0493 (6) | |
F3 | 0.59947 (12) | −0.10182 (19) | 0.47735 (9) | 0.0277 (4) | |
F4 | 0.97413 (15) | 1.0742 (3) | 0.90026 (11) | 0.0528 (6) | |
F5 | 1.09024 (13) | 1.0846 (2) | 0.82679 (11) | 0.0409 (5) | |
F6 | 1.05254 (19) | 0.8615 (3) | 0.87451 (14) | 0.0733 (8) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Co1 | 0.01937 (19) | 0.01210 (18) | 0.01308 (18) | −0.00017 (13) | 0.00877 (13) | 0.00023 (13) |
N1 | 0.0249 (12) | 0.0147 (11) | 0.0188 (12) | 0.0002 (9) | 0.0107 (10) | 0.0005 (10) |
N2 | 0.0238 (12) | 0.0159 (11) | 0.0175 (12) | −0.0028 (9) | 0.0102 (10) | −0.0018 (9) |
N3 | 0.0256 (13) | 0.0207 (12) | 0.0192 (12) | −0.0040 (9) | 0.0123 (10) | −0.0024 (10) |
N4 | 0.0263 (13) | 0.0194 (12) | 0.0183 (12) | 0.0013 (10) | 0.0141 (10) | 0.0021 (10) |
N5 | 0.0211 (11) | 0.0125 (11) | 0.0168 (11) | −0.0003 (8) | 0.0053 (9) | −0.0002 (8) |
O1 | 0.0280 (10) | 0.0134 (9) | 0.0149 (9) | −0.0018 (7) | 0.0131 (8) | −0.0001 (7) |
C1 | 0.0213 (14) | 0.0228 (15) | 0.0286 (16) | 0.0057 (11) | 0.0117 (12) | 0.0052 (12) |
C1S | 0.0295 (16) | 0.0245 (15) | 0.0294 (16) | 0.0028 (12) | 0.0045 (13) | 0.0060 (12) |
C2 | 0.0205 (14) | 0.0286 (16) | 0.0203 (15) | −0.0009 (12) | 0.0077 (11) | −0.0004 (12) |
C2S | 0.0267 (16) | 0.0337 (18) | 0.0358 (18) | −0.0033 (12) | 0.0017 (14) | 0.0077 (14) |
C3 | 0.0205 (14) | 0.0318 (16) | 0.0235 (15) | −0.0014 (12) | 0.0070 (12) | −0.0044 (13) |
C4 | 0.0273 (15) | 0.0342 (17) | 0.0139 (14) | 0.0063 (13) | 0.0072 (12) | 0.0006 (12) |
C5 | 0.0198 (13) | 0.0142 (13) | 0.0184 (13) | 0.0002 (10) | 0.0045 (10) | 0.0003 (10) |
C6 | 0.0312 (16) | 0.0266 (16) | 0.0175 (14) | 0.0005 (12) | 0.0119 (12) | 0.0011 (12) |
S1 | 0.0255 (4) | 0.0192 (4) | 0.0277 (4) | −0.0005 (3) | 0.0102 (3) | 0.0002 (3) |
S2 | 0.0223 (3) | 0.0162 (3) | 0.0227 (3) | −0.0011 (3) | 0.0104 (3) | 0.0000 (3) |
O2 | 0.0316 (12) | 0.0278 (11) | 0.0314 (12) | −0.0005 (9) | 0.0063 (9) | −0.0089 (9) |
O3 | 0.0387 (13) | 0.0385 (13) | 0.0538 (16) | −0.0055 (10) | 0.0176 (11) | 0.0166 (11) |
O4 | 0.0353 (12) | 0.0247 (11) | 0.0247 (11) | 0.0028 (9) | 0.0161 (9) | −0.0056 (8) |
O5 | 0.0260 (11) | 0.0200 (10) | 0.0363 (12) | −0.0009 (8) | 0.0067 (9) | 0.0071 (9) |
O6 | 0.0281 (11) | 0.0215 (10) | 0.0316 (11) | −0.0057 (8) | 0.0145 (9) | 0.0008 (9) |
O7 | 0.0412 (13) | 0.0302 (12) | 0.0425 (13) | −0.0048 (10) | 0.0264 (11) | −0.0099 (10) |
F1 | 0.0362 (11) | 0.0256 (10) | 0.0891 (17) | 0.0111 (8) | 0.0146 (11) | 0.0045 (10) |
F2 | 0.0410 (12) | 0.0779 (16) | 0.0270 (10) | −0.0075 (10) | −0.0026 (9) | 0.0205 (10) |
F3 | 0.0255 (9) | 0.0320 (9) | 0.0269 (9) | −0.0012 (7) | 0.0075 (7) | 0.0050 (7) |
F4 | 0.0451 (12) | 0.0852 (16) | 0.0304 (11) | −0.0267 (11) | 0.0135 (9) | −0.0165 (11) |
F5 | 0.0212 (9) | 0.0542 (12) | 0.0480 (12) | −0.0091 (8) | 0.0071 (8) | 0.0023 (10) |
F6 | 0.0690 (16) | 0.0571 (15) | 0.0842 (18) | 0.0029 (12) | −0.0241 (14) | 0.0390 (13) |
Geometric parameters (Å, º) top
Co1—O1 | 1.8736 (17) | C1S—F1 | 1.336 (3) |
Co1—N5 | 1.938 (2) | C1S—F3 | 1.342 (3) |
Co1—N3 | 1.941 (2) | C1S—S1 | 1.827 (3) |
Co1—N1 | 1.947 (2) | C2—H2A | 0.98 (3) |
Co1—N4 | 1.950 (2) | C2—H2B | 0.94 (3) |
Co1—N2 | 1.963 (2) | C2S—F6 | 1.316 (4) |
N1—C1 | 1.485 (4) | C2S—F4 | 1.334 (4) |
N1—H1C | 0.89 (3) | C2S—F5 | 1.343 (3) |
N1—H1D | 0.87 (3) | C2S—S2 | 1.828 (3) |
N2—C2 | 1.485 (4) | C3—C4 | 1.511 (4) |
N2—H2C | 0.92 (3) | C3—H3A | 0.90 (3) |
N2—H2D | 0.87 (3) | C3—H3B | 0.90 (3) |
N3—C3 | 1.489 (4) | C4—H4A | 0.95 (3) |
N3—H3C | 0.84 (3) | C4—H4B | 0.87 (3) |
N3—H3D | 0.93 (3) | C5—C6 | 1.459 (4) |
N4—C4 | 1.478 (4) | C6—H6A | 1.01 (3) |
N4—H4C | 0.77 (3) | C6—H6B | 0.97 (4) |
N4—H4D | 0.83 (3) | C6—H6C | 1.01 (4) |
N5—C5 | 1.144 (3) | S1—O3 | 1.436 (2) |
O1—O1i | 1.496 (3) | S1—O4 | 1.4417 (19) |
C1—C2 | 1.520 (4) | S1—O2 | 1.452 (2) |
C1—H1A | 0.95 (3) | S2—O6 | 1.4451 (19) |
C1—H1B | 0.93 (3) | S2—O5 | 1.446 (2) |
C1S—F2 | 1.333 (4) | S2—O7 | 1.449 (2) |
| | | |
O1—Co1—N5 | 175.78 (8) | F2—C1S—F3 | 106.1 (2) |
O1—Co1—N3 | 92.10 (9) | F1—C1S—F3 | 107.0 (2) |
N5—Co1—N3 | 91.08 (10) | F2—C1S—S1 | 111.8 (2) |
O1—Co1—N1 | 91.39 (9) | F1—C1S—S1 | 111.1 (2) |
N5—Co1—N1 | 91.20 (9) | F3—C1S—S1 | 112.11 (19) |
N3—Co1—N1 | 93.13 (10) | N2—C2—C1 | 106.8 (2) |
O1—Co1—N4 | 88.27 (9) | N2—C2—H2A | 111.1 (16) |
N5—Co1—N4 | 89.16 (10) | C1—C2—H2A | 110.8 (16) |
N3—Co1—N4 | 86.55 (11) | N2—C2—H2B | 105.7 (16) |
N1—Co1—N4 | 179.52 (11) | C1—C2—H2B | 111.8 (16) |
O1—Co1—N2 | 88.82 (9) | H2A—C2—H2B | 110 (2) |
N5—Co1—N2 | 88.03 (9) | F6—C2S—F4 | 107.9 (3) |
N3—Co1—N2 | 178.98 (10) | F6—C2S—F5 | 107.5 (3) |
N1—Co1—N2 | 86.39 (10) | F4—C2S—F5 | 107.0 (3) |
N4—Co1—N2 | 93.93 (10) | F6—C2S—S2 | 112.1 (2) |
C1—N1—Co1 | 108.92 (17) | F4—C2S—S2 | 111.3 (2) |
C1—N1—H1C | 111.4 (17) | F5—C2S—S2 | 110.9 (2) |
Co1—N1—H1C | 110.2 (17) | N3—C3—C4 | 108.4 (2) |
C1—N1—H1D | 109 (2) | N3—C3—H3A | 107.6 (19) |
Co1—N1—H1D | 105 (2) | C4—C3—H3A | 116.6 (19) |
H1C—N1—H1D | 112 (3) | N3—C3—H3B | 106.9 (18) |
C2—N2—Co1 | 108.95 (17) | C4—C3—H3B | 112.2 (18) |
C2—N2—H2C | 110.3 (18) | H3A—C3—H3B | 105 (3) |
Co1—N2—H2C | 117.2 (18) | N4—C4—C3 | 106.8 (2) |
C2—N2—H2D | 106 (2) | N4—C4—H4A | 112.6 (18) |
Co1—N2—H2D | 114 (2) | C3—C4—H4A | 111.0 (19) |
H2C—N2—H2D | 100 (3) | N4—C4—H4B | 107.4 (18) |
C3—N3—Co1 | 109.79 (18) | C3—C4—H4B | 110.6 (18) |
C3—N3—H3C | 113 (2) | H4A—C4—H4B | 108 (2) |
Co1—N3—H3C | 106 (2) | N5—C5—C6 | 178.1 (3) |
C3—N3—H3D | 108.2 (19) | C5—C6—H6A | 107 (2) |
Co1—N3—H3D | 113.1 (18) | C5—C6—H6B | 106 (2) |
H3C—N3—H3D | 106 (3) | H6A—C6—H6B | 116 (3) |
C4—N4—Co1 | 108.48 (18) | C5—C6—H6C | 105 (2) |
C4—N4—H4C | 110 (2) | H6A—C6—H6C | 110 (3) |
Co1—N4—H4C | 114 (2) | H6B—C6—H6C | 112 (3) |
C4—N4—H4D | 103 (2) | O3—S1—O4 | 116.12 (13) |
Co1—N4—H4D | 109 (2) | O3—S1—O2 | 114.97 (14) |
H4C—N4—H4D | 111 (3) | O4—S1—O2 | 114.02 (12) |
C5—N5—Co1 | 172.5 (2) | O3—S1—C1S | 102.69 (14) |
O1i—O1—Co1 | 110.57 (16) | O4—S1—C1S | 103.50 (13) |
N1—C1—C2 | 106.9 (2) | O2—S1—C1S | 103.06 (14) |
N1—C1—H1A | 109.9 (17) | O6—S2—O5 | 114.98 (12) |
C2—C1—H1A | 113.4 (17) | O6—S2—O7 | 115.49 (12) |
N1—C1—H1B | 111.3 (17) | O5—S2—O7 | 114.31 (13) |
C2—C1—H1B | 108.6 (17) | O6—S2—C2S | 103.61 (13) |
H1A—C1—H1B | 107 (2) | O5—S2—C2S | 102.54 (13) |
F2—C1S—F1 | 108.4 (2) | O7—S2—C2S | 103.54 (15) |
| | | |
O1—Co1—N1—C1 | 104.30 (18) | N1—C1—C2—N2 | 50.9 (3) |
N5—Co1—N1—C1 | −72.37 (19) | Co1—N3—C3—C4 | −31.6 (3) |
N3—Co1—N1—C1 | −163.52 (19) | Co1—N4—C4—C3 | −42.0 (3) |
N2—Co1—N1—C1 | 15.58 (18) | N3—C3—C4—N4 | 48.0 (3) |
O1—Co1—N2—C2 | −78.47 (17) | F2—C1S—S1—O3 | 63.2 (2) |
N5—Co1—N2—C2 | 104.33 (18) | F1—C1S—S1—O3 | −58.1 (2) |
N1—Co1—N2—C2 | 13.00 (18) | F3—C1S—S1—O3 | −177.8 (2) |
N4—Co1—N2—C2 | −166.65 (18) | F2—C1S—S1—O4 | −58.0 (2) |
O1—Co1—N3—C3 | −81.52 (18) | F1—C1S—S1—O4 | −179.3 (2) |
N5—Co1—N3—C3 | 95.71 (19) | F3—C1S—S1—O4 | 61.0 (2) |
N1—Co1—N3—C3 | −173.03 (19) | F2—C1S—S1—O2 | −177.06 (19) |
N4—Co1—N3—C3 | 6.62 (19) | F1—C1S—S1—O2 | 61.6 (2) |
O1—Co1—N4—C4 | 112.44 (18) | F3—C1S—S1—O2 | −58.0 (2) |
N5—Co1—N4—C4 | −70.90 (18) | F6—C2S—S2—O6 | 61.6 (3) |
N3—Co1—N4—C4 | 20.24 (19) | F4—C2S—S2—O6 | −59.4 (2) |
N2—Co1—N4—C4 | −158.86 (18) | F5—C2S—S2—O6 | −178.3 (2) |
N3—Co1—O1—O1i | −46.18 (19) | F6—C2S—S2—O5 | −178.5 (2) |
N1—Co1—O1—O1i | 47.01 (18) | F4—C2S—S2—O5 | 60.6 (2) |
N4—Co1—O1—O1i | −132.65 (19) | F5—C2S—S2—O5 | −58.4 (2) |
N2—Co1—O1—O1i | 133.38 (18) | F6—C2S—S2—O7 | −59.3 (3) |
Co1—N1—C1—C2 | −40.1 (3) | F4—C2S—S2—O7 | 179.7 (2) |
Co1—N2—C2—C1 | −37.9 (2) | F5—C2S—S2—O7 | 60.7 (2) |
Symmetry code: (i) −x+2, −y+1, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N1—H1C···O7 | 0.89 (3) | 2.33 (3) | 3.162 (3) | 157 (2) |
N1—H1D···O1i | 0.87 (3) | 2.22 (3) | 2.832 (3) | 128 (3) |
N1—H1D···O4ii | 0.87 (3) | 2.49 (3) | 3.130 (3) | 131 (3) |
N2—H2C···O2 | 0.92 (3) | 2.04 (3) | 2.937 (3) | 164 (3) |
N2—H2D···O6iii | 0.87 (3) | 2.38 (3) | 3.150 (3) | 147 (3) |
N3—H3C···O1i | 0.84 (3) | 2.29 (3) | 2.840 (3) | 123 (3) |
N3—H3C···O3i | 0.84 (3) | 2.29 (3) | 2.908 (3) | 130 (3) |
N3—H3D···O7 | 0.93 (3) | 2.35 (3) | 3.127 (3) | 141 (2) |
N4—H4C···O5iv | 0.77 (3) | 2.30 (3) | 3.032 (3) | 160 (3) |
N4—H4D···O4v | 0.83 (3) | 2.22 (3) | 2.947 (3) | 147 (3) |
Symmetry codes: (i) −x+2, −y+1, −z+1; (ii) x, y+1, z; (iii) −x+3/2, y−1/2, −z+3/2; (iv) x, y−1, z; (v) −x+2, −y, −z+1. |