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Acta Cryst. (2002). E58, o489-o491 [ doi:10.1107/S1600536802005378 ]
Abstract: The title compound, C14H13N2O+·Br-, in the solid state, has a zigzag packing of the azaaromatic molecules in the c direction, forming positively charged columns for the Br- anions. The C-N-C angle at the substituted N atom [122.7 (5)°] is significantly larger than that at the unprotonated N atom [115.8 (5)°]. As for previously known azaaromatic halides and polyhalides, the title compound also has a short H
Br distance for the C-H
Br interaction.
Online 5 April 2002
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