Acta Cryst. (2002). E58, m169-m171  [ doi:10.1107/S1600536802005524 ]

Aquanitro(,,,-tetraphenylporphyrinato)cobalt(III) dichloromethane solvate

S. Ohba and H. Seki

Abstract: In the crystal structure of the title compound, [Co(NO₂)(C₄₄H₂₈N₄)(H₂O)]·CH₂Cl₂, the Co^III atom has a distorted octahedral coordination, with the water molecule trans to the nitro ligand. The Co-N(nitro) and Co-O(aqua) bond distances are 1.863  (8) and 2.114  (8)  Å, respectively. There is no intermolecular hydrogen bond involving the aqua ligand.

Online 5 April 2002

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