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Acta Cryst. (2002). E58, m203-m205  [ doi:10.1107/S1600536802006396 ]

Bis(3-amino-2-chloropyridine-[kappa]N)silver(I) perchlorate

W. Li, M.-L. Tong, X.-M. Chen, J.-X. Yuan and M.-L. Hu

Abstract: In the title compound, [Ag(C5H5ClN2)2]ClO4, the AgI atom is surrounded by two pyridyl N atoms [2.197  (4) and 2.199  (4)  Å] in a linear AgN2 geometry. Adjacent mononuclear [Ag(3-amino-2-chloropyridine)2]+ species are interlinked through weak Ag...N(amine) and Ag...O(perchlorate) coordination contacts and extensive hydrogen-bonding and [pi]-[pi] interactions, resulting in a three-dimensional supramolecular network in the solid.

Online 19 April 2002


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