Acta Cryst. (2002). E58, m245-m247  [ doi:10.1107/S1600536802007237 ]

(4-tert-Butyl-2-methylthiosemicarbazido)(O-methyldithiophosphato)palladium(II)

M. Janca, J. Taraba and J. Príhoda

Abstract: The title Pd complex, [Pd(C₆H₁₄N₃S)(CH₃O₂PS₂)], is formed from Pd(acetate)₂ and 5-tert-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2⁵-thiadiazaphospholan-5-onium, (1), in methanol. The Pd atom is coordinated to two different ligands which are generated in situ as a result of methanolysis of the starting compound (1). Thus, Pd is complexed by the O-methyldithiophosphate ligand and by 2-methyl-4-tert-butylthiosemicarbazide. Two molecules of the Pd chelate are linked by two intermolecular N-HO hydrogen bonds, the NO distances of which are 3.361 and 2.827  Å.

Online 11 May 2002

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