Acta Cryst. (2002). E58, m293-m295  [ doi:10.1107/S1600536802008681 ]

catena-Poly[[[1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene]silver(I)] nitrate]

Y.-J. Shi, Y.-Z. Li, W.-J. Tong, X.-T. Chen and X.-Z. You

Abstract: The bipyridyl-base ligand 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene (L) has been used in the synthesis of a new organometallic polymer. The reaction between AgNO₃ and L afforded a one-dimensional chain structure of the cation of the title compound, {[Ag(C₁₂N₄H₁₀)]NO₃}_n. The Ag^I ion lies on a twofold axis and is in a linear environment with respect to the two terminal N atoms of pyridyl rings. Weak interactions between H and nitrate O atoms, and between the Ag and nitrate O atoms, generate a three-dimensional framework.

Online 24 May 2002

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