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Acta Cryst. (2002). E58, m265-m266 [ doi:10.1107/S1600536802007808 ]
Abstract: The title complex, tris(O-methyldithiocarbonato)iron(III), [Fe(S2COCH3)3], has an approximate threefold rotation axis passing through the Fe atom. The Fe atom is coordinated by six S atoms in a distorted octahedral arrangement. The six Fe-S distances range from 2.299 (1) to 2.319 (1) Å, with an average of 2.307 (3) Å, showing that the Fe atom is in a low-spin state with short Fe-S distances.
Online 11 May 2002
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