Acta Cryst. (2002). E58, m349-m351  [ doi:10.1107/S160053680201070X ]

Bis(tetraethylammonium) bis[cyanocuprate(I)]tetrathiomolybdate(VI) hydrate

W. Clegg, A. Beheshti and M. H. Sadr

Abstract: The title complex, (C₈H₂₀N)₂[MoS₄(CuCN)₂]·H₂O, contains an anion in which Cu atoms bridge two opposite SS edges of the central MoS₄ unit. The Mo atom retains tetrahedral coordination geometry, while each Cu is trigonal planar coordinated by two bridging sulfides and a terminal cyano ligand. The anions are linked together into chains by hydrogen bonding to ordered water molecules.

Online 21 June 2002

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