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Acta Cryst. (2002). E58, o772-o773 [ doi:10.1107/S1600536802010620 ]
5-diazaphosphole-2-thiolateAbstract: The reaction of chlorodithiophoshoric acid pyridinium betaine, PyPS2Cl, with 2,3-diaminonaphthalene yields the title compound, (PyH)(C10H8N2)PS2 or C5H6N+·C10H8N2PS2-. The P atom is coordinated by both N atoms of 2,3-diaminonaphthalene with the formation of a five-membered ring.
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