Acta Cryst. (2002). E58, m469-m470  [ doi:10.1107/S1600536802013776 ]

(4,6-Dimethylpyrimidine-2-thiolato)(triphenylphosphine)gold(I)

E. Schulz Lang, R. M. Fernandes Jr, S. S. Lemos, L. Schulz Lang and R. A. Burrow

Abstract: The title compound, [Au(4,6-Me₂pymS)(PPh₃)] or [Au(C₆H₇N₂S)(C₁₈H₁₅P)], exhibits a linear Au atom S-Au-P geometry, with Au-P = 2.247  (2)  Å, Au-S = 2.289  (2)  Å and P-Au-S = 178.19  (11)°. There is an intramolecular interaction between one N atom of the 4,6-Me₂pymS ligand and the Au atom, with an AuN distance of 3.154  (8)  Å.

Online 9 August 2002

Copyright © International Union of Crystallography
IUCr Webmaster