Acta Cryst. (2002). E58, m484-m485  [ doi:10.1107/S1600536802013557 ]

Aquachlorodimethylphenyltin-18-crown-6 (2/1)

M. M. Amini, A. Azadmehr, S. H. Abadi and S. W. Ng

Abstract: In the crystal structure of the title compound, [SnCl(CH₃)₂(C₆H₅)(H₂O)]₂·C₁₂H₂₄O₈, the crown ether, which lies on a center of inversion, interacts with the five-coordinate trans-C₃SnClO trigonal-bipyramidal aquachlorodimethylphenyltin moieties; the coordinated water molecule, at a distance of 2.445  (4)  Å from Sn, forms two hydrogen bonds with the O atoms of the crown ether [O_waterO_crown = 2.851  (6) and 2.884  (5)  Å].

Online 16 August 2002

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