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Acta Cryst. (2002). E58, o1008-o1009 [ doi:10.1107/S1600536802014782 ]
Abstract: The tetracation of bis(2-ammonioethyl)piperazin-1,4-ium tetraperchlorate tetrahydrate, C8H24N44+·4ClO4-·4H2O, lies over a center of symmetry and the piperazinyl ring adopts a chair conformation. Four ammonium N atoms, perchlorate anions and lattice water molecules are linked by hydrogen bonds into an infinite three-dimensional framework.
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