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Acta Cryst. (2002). E58, m510-m512  [ doi:10.1107/S1600536802015660 ]

Bis[(1R,2R)-(-)-1,2-bis(trimethylsilylamino)cyclohexane(2-)-[kappa]2N,N']zirconium(IV)

J.-F. Li, L.-H. Weng, S.-P. Huang, H.-B. Tong and D.-S. Liu

Abstract: The title complex, [(1R,2R)-(-)-1,2-(NSiMe3)2-C6H10]2Zr or [Zr(C12H28N2Si2)2], can be viewed as a tetrahedron located on a non-crystallographic twofold axis, which passes through the Zr atom and between the two N atoms of each cyclohexane-based ligand. The amide N atoms form two almost perpendicular planes with the central Zr atom, with a dihedral angle of 87.23  (18)°.

Online 6 September 2002


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