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Acta Cryst. (2002). E58, m588-m589  [ doi:10.1107/S1600536802017300 ]

trans-Bis(isothiocyanato)tetrapyridineruthenium(II) dichloromethane disolvate

J. Chen, L. Han and Z. Chen

Abstract: The title compound, trans-[Ru(NCS)2(C5H5N)4]·2CH2Cl2, was prepared by the reaction between trans-dichlorotetrapyridineruthenium(II) and excess KSCN in refluxing aqueous pyridine. The Ru atom is in a pseudo-octahedral environment, with two N-donors from two monodentate NCS groups and four N-donors from the pyridine ligands. The complex molecule lies on a crystallographic twofold rotation axis, passing through Ru and the two pyridine ligands

Online 27 September 2002


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