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Acta Cryst. (2002). E58, m571-m573  [ doi:10.1107/S1600536802016768 ]

Nonacarbonyl-[mu]-hydrido-([mu]3,[eta]2-triisopropylsilylethynyl)triruthenium

E. Delgado, B. Donnadieu, E. Hernandez, M. P. Martin and F. Zamora

Abstract: The structure of the title compound, [Ru3(CO)9([mu]-H)([mu]3-C2SiiPr3)], consists of an almost equilateral triangular Ru3 core, with the acetylide ligand [sigma]-bonded to one Ru atom and [pi]-bonded to the other two Ru atoms. The hydride atom is located between the two Ru atoms that are [pi]-bonded to the acetylide. Three terminal carbonyls around each ruthenium atom complete the structure.

Online 27 September 2002


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