Acta Cryst. (2002). E58, m519-m520 [ doi:10.1107/S1600536802015787 ]
Abstract: The title compound, [Ti(C21H26N2O2S)Cl2], crystallizes as a centrosymmetric dimer, with an eight-membered ring derived from the monomer sub-units by the formation of two Ti-(N,O)-S-O head-to-tail sequences around a crystallographic inversion centre. The titanium atoms each have a distorted octahedral geometry through the nitrogen and one oxygen of the sulfonamido group [Ti1-O1, Ti-N1 2.280 (3), 2.091 (3) Å], one oxygen from the adjacent sulfonamide [Ti-O2 2.170 (3) Å], a dimethylamido nitrogen and two chlorides.
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