Acta Cryst. (2002). E58, m658-m660  [ doi:10.1107/S1600536802018573 ]

-Ferrio-bis{carbonyl[-2,2',2''-nitrilotriethanethiolato(3-)-N,S,S',S'':S,S']iron(II)} benzene solvate

S. C. Davies, M. C. Smith, D. L. Hughes and D. J. Evans

Abstract: The neutral title complex, [{Fe({SCH₂CH₂}₃N)(CO)-S,S'}₂(-Fe)]·C₆H₆ or [Fe₃(C₆H₁₂NS₃)₂(CO)₂]·C₆H₆, contains two trigonal bipyramidally coordinated Fe^II atoms bridged by a tetrahedral Fe^II atom. There is disorder in one {SCH₂CH₂}₃N ligand and in the solvent benzene present in the crystal structure. Dimensions in the complex are comparable to those in other five-coordinate metal-({SCH₂CH₂}₃N) complexes.

Online 25 October 2002

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