A hexa­carbonyl­dicobalt(0) complex of a `magazine-rack' mol­ecule, [(η2-C32H20)Co2(CO)6]·CH2Cl2

Orita, A.; Jiang, L.; Ye, F.; Imai, N.; Akashi, H.; Otera, J.

doi:10.1107/S1600536802019281

A hexacarbonyldicobalt(0) complex of a `magazine-rack' molecule, [(η²-C₃₂H₂₀)Co₂(CO)₆]·CH₂Cl₂

A. Orita, L. Jiang, F. Ye, N. Imai, H. Akashi and J. Otera

The title compound, μ-pentacyclo[26.4.0.0^9,14.0^17,22.0^25,30]dotriaconta-1,3,5,9,11,13,15,17,19,21,25,27,29,31-tetradecaene-7,24-diyne-bis(tricarbonylcobalt) dichloromethane solvate, [Co₂(η²-C₃₂H₂₀)(CO)₆]·CH₂Cl₂, has been prepared by treatment of a dehydrobenzoannulene with octacarbonyldicobalt. This cobalt complex is chiral in the solid state and exhibits alternate arrays of P- and M-conformations.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802019281/wn6120sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536802019281/wn6120Isup2.hkl Contains datablock I

CCDC reference: 200742

checkCIF report

Key indicators

Single-crystal X-ray study
T = 113 K
Mean (C-C) = 0.002 Å
R factor = 0.026
wR factor = 0.089
Data-to-parameter ratio = 16.2

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level B:



PLAT_733  Alert B Torsion Calc   -56.13(8), Rep    -56.1(4) ....       5.00 su-Ratio
                     C36 -CO2 -CO1 -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert B Torsion Calc    89.36(8), Rep     89.4(4) ....       5.00 su-Ratio
                     C36 -CO2 -CO1 -C35    1.555   1.555   1.555   1.555

PLAT_733  Alert B Torsion Calc  -42.30(11), Rep    -42.2(5) ....       4.55 su-Ratio
                     C36 -CO2 -CO1 -C33    1.555   1.555   1.555   1.555

PLAT_733  Alert B Torsion Calc  -163.42(8), Rep   -163.4(4) ....       5.00 su-Ratio
                     C36 -CO2 -CO1 -C34    1.555   1.555   1.555   1.555

PLAT_733  Alert B Torsion Calc   177.44(4), Rep    177.5(2) ....       5.00 su-Ratio
                     C36 -CO2 -C1  -CO1    1.555   1.555   1.555   1.555

PLAT_733  Alert B Torsion Calc   161.30(4), Rep    161.3(2) ....       5.00 su-Ratio
                     C33 -CO1 -C1  -CO2    1.555   1.555   1.555   1.555


 Alert Level C:



PLAT_371  Alert C Long   C(sp2)-C(sp1) Bond  C(16)  -   C(17)  =       1.44 Ang.

PLAT_371  Alert C Long   C(sp2)-C(sp1) Bond  C(18)  -   C(19)  =       1.43 Ang.

PLAT_703  Alert C Torsion Calc   177.44(4), Rep    177.5(2), Dev.      1.50 Sigma
                     C36 -CO2 -C1  -CO1    1.555   1.555   1.555   1.555

PLAT_703  Alert C Torsion Calc    77.43(6), Rep     77.5(2), Dev.      1.17 Sigma
                     C37 -CO2 -C1  -CO1    1.555   1.555   1.555   1.555

PLAT_703  Alert C Torsion Calc  -172.86(5), Rep   -172.8(2), Dev.      1.20 Sigma
                     C33 -CO1 -C2  -CO2    1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     26
                   CO1 -CO2 -C36 -O4    -61.60  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     27
                   C38 -CO2 -C36 -O4    155.00  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     28
                   C2  -CO2 -C36 -O4   -104.50  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     29
                   C37 -CO2 -C36 -O4     46.80  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     30
                   C1  -CO2 -C36 -O4    -65.40  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     31
                   CO1 -CO2 -C38 -O6    -52.50  0.30   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     32
                   C36 -CO2 -C38 -O6    108.70  0.30   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     33
                   C2  -CO2 -C38 -O6     -0.70  0.30   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     34
                   C37 -CO2 -C38 -O6   -150.10  0.30   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     35
                   C1  -CO2 -C38 -O6     -5.00  0.30   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     51
                   CO1 -CO2 -C37 -O5     -9.80  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     52
                   C36 -CO2 -C37 -O5   -159.70  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     53
                   C38 -CO2 -C37 -O5     94.50  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     54
                   C2  -CO2 -C37 -O5    -28.80  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     55
                   C1  -CO2 -C37 -O5    -60.00  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     86
                   CO2 -CO1 -C35 -O3    -31.30  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     87
                   C2  -CO1 -C35 -O3     10.30  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     88
                   C33 -CO1 -C35 -O3    125.60  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     89
                   C1  -CO1 -C35 -O3     21.10  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     90
                   C34 -CO1 -C35 -O3   -130.10  0.40   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     91
                   CO2 -CO1 -C33 -O1    -23.80  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     92
                   C2  -CO1 -C33 -O1    -12.80  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     93
                   C35 -CO1 -C33 -O1   -155.00  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     94
                   C1  -CO1 -C33 -O1    -53.00  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #     95
                   C34 -CO1 -C33 -O1     96.20  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    111
                   CO2 -CO1 -C34 -O2      7.80  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    112
                   C2  -CO1 -C34 -O2    -44.10  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    113
                   C35 -CO1 -C34 -O2    109.30  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    114
                   C33 -CO1 -C34 -O2   -145.60  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    115
                   C1  -CO1 -C34 -O2    -19.90  0.60   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    164
                   C24 -C19 -C18 -C17    51.20  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    165
                   C20 -C19 -C18 -C17  -129.40  0.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    168
                   C11 -C16 -C17 -C18    -5.90  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    169
                   C15 -C16 -C17 -C18   173.00  0.70   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 (CIF) Linear Torsion Angle #    177
                   C16 -C17 -C18 -C19   -13.80  1.00   1.555   1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc  117.94(17), Rep   117.94(8) ....       2.12 su-Ratio
                     C5   -C6   -H3      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc  121.91(17), Rep   121.88(8) ....       2.12 su-Ratio
                     C7   -C6   -H3      1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc  106.75(16), Rep   106.76(7) ....       2.29 su-Ratio
                     CL2  -C39  -H21     1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc    105.0(2), Rep   105.03(7) ....       2.86 su-Ratio
                     CL1  -C39  -H21     1.555   1.555   1.555

PLAT_732  Alert C Angle   Calc  106.48(19), Rep   106.45(7) ....       2.71 su-Ratio
                     CL2  -C39  -H22     1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    -4.82(8), Rep     -4.8(3) ....       3.75 su-Ratio
                     C36 -CO2 -CO1 -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    87.40(6), Rep     87.4(2) ....       3.33 su-Ratio
                     C38 -CO2 -CO1 -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -127.10(6), Rep   -127.1(2) ....       3.33 su-Ratio
                     C38 -CO2 -CO1 -C35    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   138.72(6), Rep    138.7(2) ....       3.33 su-Ratio
                     C38 -CO2 -CO1 -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -19.88(6), Rep    -19.9(2) ....       3.33 su-Ratio
                     C38 -CO2 -CO1 -C34    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -165.43(7), Rep   -165.4(2) ....       2.86 su-Ratio
                     C37 -CO2 -CO1 -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -19.94(6), Rep    -19.9(2) ....       3.33 su-Ratio
                     C37 -CO2 -CO1 -C35    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -114.12(6), Rep   -114.1(2) ....       3.33 su-Ratio
                     C37 -CO2 -CO1 -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    87.28(6), Rep     87.3(2) ....       3.33 su-Ratio
                     C37 -CO2 -CO1 -C34    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -37.48(9), Rep    -37.5(2) ....       2.22 su-Ratio
                     C1  -CO2 -CO1 -C33    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   152.67(5), Rep    152.7(2) ....       4.00 su-Ratio
                     C36 -CO2 -C2  -CO1    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    78.93(9), Rep     79.0(2) ....       2.22 su-Ratio
                     C36 -CO2 -C2  -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -71.76(14), Rep    -71.8(3) ....       2.14 su-Ratio
                     C36 -CO2 -C2  -C3     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -175.31(9), Rep   -175.3(2) ....       2.22 su-Ratio
                     C38 -CO2 -C2  -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   34.01(14), Rep     34.0(3) ....       2.14 su-Ratio
                     C38 -CO2 -C2  -C3     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   24.45(11), Rep     24.5(3) ....       2.73 su-Ratio
                     C37 -CO2 -C2  -CO1    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -49.30(13), Rep    -49.3(3) ....       2.31 su-Ratio
                     C37 -CO2 -C2  -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  160.02(12), Rep    160.0(3) ....       2.50 su-Ratio
                     C37 -CO2 -C2  -C3     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc -135.55(13), Rep   -135.6(3) ....       2.31 su-Ratio
                     CO1 -CO2 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -109.52(8), Rep   -109.5(2) ....       2.50 su-Ratio
                     C36 -CO2 -C1  -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   41.89(13), Rep     41.9(3) ....       2.31 su-Ratio
                     C36 -CO2 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -66.38(8), Rep    -66.4(3) ....       3.75 su-Ratio
                     C38 -CO2 -C1  -CO1    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    6.66(12), Rep      6.7(3) ....       2.50 su-Ratio
                     C38 -CO2 -C1  -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    77.43(6), Rep     77.5(2) ....       3.33 su-Ratio
                     C37 -CO2 -C1  -CO1    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   150.47(8), Rep    150.5(2) ....       2.50 su-Ratio
                     C37 -CO2 -C1  -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -58.12(14), Rep    -58.1(3) ....       2.14 su-Ratio
                     C37 -CO2 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -56.35(9), Rep    -56.4(3) ....       3.33 su-Ratio
                     C35 -CO1 -C2  -CO2    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   16.71(13), Rep     16.7(3) ....       2.31 su-Ratio
                     C35 -CO1 -C2  -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -172.86(5), Rep   -172.8(2) ....       4.00 su-Ratio
                     C33 -CO1 -C2  -CO2    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -99.81(9), Rep    -99.8(2) ....       2.22 su-Ratio
                     C33 -CO1 -C2  -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   52.52(14), Rep     52.5(3) ....       2.14 su-Ratio
                     C33 -CO1 -C2  -C3     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    83.75(5), Rep     83.7(2) ....       4.00 su-Ratio
                     C34 -CO1 -C2  -CO2    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   156.80(8), Rep    156.8(2) ....       2.50 su-Ratio
                     C34 -CO1 -C2  -C1     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -50.87(14), Rep    -50.9(3) ....       2.14 su-Ratio
                     C34 -CO1 -C2  -C3     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  135.94(13), Rep    136.0(3) ....       2.31 su-Ratio
                     CO2 -CO1 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   -94.86(5), Rep    -94.9(2) ....       4.00 su-Ratio
                     C35 -CO1 -C1  -CO2    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -168.73(8), Rep   -168.7(2) ....       2.50 su-Ratio
                     C35 -CO1 -C1  -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc   41.08(13), Rep     41.1(3) ....       2.31 su-Ratio
                     C35 -CO1 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    87.44(9), Rep     87.5(2) ....       2.22 su-Ratio
                     C33 -CO1 -C1  -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -62.76(12), Rep    -62.7(3) ....       2.50 su-Ratio
                     C33 -CO1 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc    36.15(9), Rep     36.1(3) ....       3.33 su-Ratio
                     C34 -CO1 -C1  -CO2    1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  -37.71(12), Rep    -37.8(3) ....       2.50 su-Ratio
                     C34 -CO1 -C1  -C2     1.555   1.555   1.555   1.555

PLAT_733  Alert C Torsion Calc  172.09(10), Rep    172.1(3) ....       3.00 su-Ratio
                     C34 -CO1 -C1  -C32    1.555   1.555   1.555   1.555

PLAT_742  Alert C Angle   Calc    121.7(3), Rep      121.67 ....    Missing su
                     H21  -C39  -H22     1.555   1.555   1.555

PLAT_744  Alert C Contact Calc  0.9856(18), Rep     0.98500 ....    Missing su
                     C5   -H2      1.555   1.555

PLAT_744  Alert C Contact Calc  0.9733(16), Rep     0.97400 ....    Missing su
                     C9   -H5      1.555   1.555

PLAT_744  Alert C Contact Calc  0.9504(16), Rep     0.95000 ....    Missing su
                     C30  -H19     1.555   1.555

PLAT_744  Alert C Contact Calc  0.9788(19), Rep     0.97900 ....    Missing su
                     C26  -H16     1.555   1.555

PLAT_744  Alert C Contact Calc  0.9597(16), Rep     0.96000 ....    Missing su
                     C6   -H3      1.555   1.555

PLAT_744  Alert C Contact Calc  0.9884(19), Rep     0.98900 ....    Missing su
                     C7   -H4      1.555   1.555

PLAT_744  Alert C Contact Calc    0.970(3), Rep     0.97000 ....    Missing su
                     C20  -H11     1.555   1.555

PLAT_744  Alert C Contact Calc  0.9518(16), Rep     0.95200 ....    Missing su
                     C25  -H15     1.555   1.555

PLAT_744  Alert C Contact Calc  0.9557(19), Rep     0.95500 ....    Missing su
                     C4   -H1      1.555   1.555

PLAT_744  Alert C Contact Calc  0.9826(17), Rep     0.98300 ....    Missing su
                     C10  -H6      1.555   1.555

PLAT_744  Alert C Contact Calc  0.9426(18), Rep     0.94200 ....    Missing su
                     C14  -H9      1.555   1.555

PLAT_744  Alert C Contact Calc    0.982(2), Rep     0.98200 ....    Missing su
                     C29  -H18     1.555   1.555

PLAT_744  Alert C Contact Calc    0.986(2), Rep     0.98600 ....    Missing su
                     C15  -H10     1.555   1.555

PLAT_744  Alert C Contact Calc  0.9483(18), Rep     0.94900 ....    Missing su
                     C13  -H8      1.555   1.555

PLAT_744  Alert C Contact Calc    0.983(2), Rep     0.98300 ....    Missing su
                     C23  -H14     1.555   1.555

PLAT_744  Alert C Contact Calc    0.944(2), Rep     0.94400 ....    Missing su
                     C21  -H12     1.555   1.555

PLAT_744  Alert C Contact Calc  0.9696(19), Rep     0.97000 ....    Missing su
                     C28  -H17     1.555   1.555

PLAT_744  Alert C Contact Calc    0.974(2), Rep     0.97400 ....    Missing su
                     C31  -H20     1.555   1.555

PLAT_744  Alert C Contact Calc    1.015(2), Rep     1.01400 ....    Missing su
                     C12  -H7      1.555   1.555

PLAT_744  Alert C Contact Calc    0.985(2), Rep     0.98500 ....    Missing su
                     C22  -H13     1.555   1.555

PLAT_744  Alert C Contact Calc    0.912(2), Rep     0.91200 ....    Missing su
                     C39  -H21     1.555   1.555

PLAT_744  Alert C Contact Calc    0.996(3), Rep     0.99600 ....    Missing su
                     C39  -H22     1.555   1.555

PLAT_744  Alert C Contact Calc    1.667(3), Rep     1.66700 ....    Missing su
                     H21  -H22     1.555   1.555


 0 Alert Level A = Potentially serious problem

 6 Alert Level B = Potential problem

 112 Alert Level C = Please check

Computing details top

Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO; data reduction: TEXSAN (Rigaku, 1999); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1998); software used to prepare material for publication: CrystalStructure (Molecular Structure Corporation & Rigaku, 2001).

µ-pentacyclo[26.4.0.0^9,14.0^17,22.0^25,30]dotriaconta- 1,3,5,9,11,13,15,17,19,21,25,27,29,31-tetradecaene-7,24-diyne- bis(tricarbonylcobalt) dichloromethane solvate top

Crystal data top

[Co₂(C₃₂H₂₀)(CO)₆]·CH₂Cl₂	D_x = 1.510 Mg m⁻³
M_r = 775.37	Mo Kα radiation, λ = 0.7107 Å
Monoclinic, P2₁/c	Cell parameters from 9554 reflections
a = 13.0348 (3) Å	θ = 2.9–27.5°
b = 10.9999 (3) Å	µ = 1.18 mm⁻¹
c = 23.8599 (5) Å	T = 113 K
β = 94.584 (1)°	Plate, dark purple
V = 3410.1 (1) Å³	0.30 × 0.15 × 0.10 mm
Z = 4

Data collection top

Rigaku R-AXIS-IV diffractometer	6460 reflections with F² > 2σ(F²)
Detector resolution: 10.00 pixels mm^-1	R_int = 0.019
ω scans	θ_max = 27.5°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −16→16
T_min = 0.719, T_max = 0.889	k = −14→14
18119 measured reflections	l = −21→30
7873 independent reflections

Refinement top

Refinement on F²	All H-atom parameters refined
R[F² > 2σ(F²)] = 0.026	w = 1/[0.002F_o² + σ²(F_o)]/(4F_o²)
wR(F²) = 0.089	(Δ/σ)_max < 0.001
S = 0.90	Δρ_max = 0.44 e Å⁻³
7523 reflections	Δρ_min = −0.72 e Å⁻³
464 parameters

Special details top

Refinement. Refinement using reflections with F² > -10.0 σ(F²). The weighted R-factor (wR) and goodness of fit (S) are based on F². R-factor (gt) are based on F. The threshold expression of F² > 2.0 σ(F²) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Co2	0.60244 (1)	0.22766 (2)	0.25522 (1)	0.00941 (5)
Co1	0.78790 (1)	0.22461 (2)	0.24426 (1)	0.00919 (5)
Cl2	0.99652 (4)	−0.01472 (4)	0.33300 (2)	0.0325 (1)
Cl1	1.13388 (5)	0.15243 (6)	0.39717 (2)	0.0476 (2)
O4	0.43698 (9)	0.2141 (1)	0.33198 (5)	0.0218 (3)
O3	0.81523 (9)	−0.0418 (1)	0.23569 (5)	0.0213 (3)
O6	0.5283 (1)	0.4054 (1)	0.16804 (5)	0.0247 (3)
O5	0.57228 (9)	−0.0168 (1)	0.20608 (5)	0.0235 (3)
O2	0.76828 (9)	0.3211 (1)	0.12809 (5)	0.0217 (3)
O1	0.99545 (9)	0.3089 (1)	0.28370 (5)	0.0260 (3)
C36	0.4995 (1)	0.2228 (1)	0.30198 (7)	0.0148 (3)
C38	0.5540 (1)	0.3345 (1)	0.20055 (6)	0.0152 (3)
C2	0.7110 (1)	0.3369 (1)	0.28991 (6)	0.0099 (3)
C5	0.7665 (1)	0.6661 (1)	0.26161 (6)	0.0147 (3)
C35	0.8069 (1)	0.0610 (1)	0.23801 (6)	0.0139 (3)
C9	0.6240 (1)	0.4545 (1)	0.38526 (6)	0.0114 (3)
C33	0.9162 (1)	0.2746 (1)	0.26805 (7)	0.0158 (4)
C24	0.9252 (1)	0.3705 (1)	0.51209 (6)	0.0155 (3)
C37	0.5817 (1)	0.0774 (1)	0.22537 (6)	0.0150 (3)
C30	0.6971 (1)	−0.0243 (1)	0.41968 (7)	0.0156 (3)
C1	0.7172 (1)	0.2270 (1)	0.31466 (6)	0.0094 (3)
C27	0.7948 (1)	0.2042 (1)	0.41536 (6)	0.0114 (3)
C26	0.8448 (1)	0.3233 (1)	0.41202 (6)	0.0128 (3)
C6	0.7265 (1)	0.7235 (1)	0.30691 (7)	0.0152 (4)
C19	0.8790 (1)	0.4392 (1)	0.55320 (7)	0.0179 (4)
C7	0.6799 (1)	0.6552 (1)	0.34695 (6)	0.0143 (3)
C16	0.6306 (1)	0.6489 (1)	0.50363 (6)	0.0163 (3)
C20	0.9183 (1)	0.4315 (2)	0.60972 (7)	0.0245 (4)
C17	0.7198 (1)	0.5783 (1)	0.52245 (7)	0.0189 (4)
C8	0.6722 (1)	0.5282 (1)	0.34325 (6)	0.0108 (3)
C25	0.8944 (1)	0.3923 (1)	0.45170 (6)	0.0148 (3)
C34	0.7781 (1)	0.2835 (1)	0.17277 (7)	0.0139 (3)
C18	0.7934 (1)	0.5169 (2)	0.53704 (7)	0.0189 (4)
C11	0.5652 (1)	0.6082 (1)	0.45731 (6)	0.0147 (3)
C4	0.7599 (1)	0.5404 (1)	0.25687 (6)	0.0127 (3)
C10	0.5823 (1)	0.4863 (1)	0.43248 (6)	0.0137 (3)
C14	0.5197 (1)	0.8228 (1)	0.51384 (7)	0.0222 (4)
C32	0.7349 (1)	0.1586 (1)	0.36750 (6)	0.0102 (3)
C29	0.7534 (1)	0.0213 (1)	0.46718 (7)	0.0174 (4)
C15	0.6068 (1)	0.7568 (1)	0.53144 (7)	0.0205 (4)
C13	0.4555 (1)	0.7838 (1)	0.46792 (7)	0.0213 (4)
C23	1.0085 (1)	0.2949 (1)	0.52898 (7)	0.0200 (4)
C21	1.0006 (1)	0.3556 (2)	0.62549 (7)	0.0266 (4)
C28	0.8015 (1)	0.1337 (1)	0.46471 (6)	0.0160 (3)
C3	0.7141 (1)	0.4697 (1)	0.29699 (6)	0.0102 (3)
C31	0.6880 (1)	0.0439 (1)	0.37089 (6)	0.0131 (3)
C12	0.4784 (1)	0.6771 (1)	0.44009 (7)	0.0186 (4)
C22	1.0454 (1)	0.2868 (2)	0.58558 (8)	0.0238 (4)
C39	1.0448 (1)	0.0331 (2)	0.40046 (8)	0.0310 (5)
H10	0.6538 (1)	0.7764 (1)	0.56466 (7)	0.025 (1)*
H9	0.5030 (1)	0.8931 (1)	0.53379 (7)	0.027 (1)*
H8	0.3963 (1)	0.8308 (1)	0.45691 (7)	0.026 (1)*
H7	0.4283 (1)	0.6481 (1)	0.40815 (7)	0.023 (1)*
H3	0.7280 (1)	0.8107 (1)	0.30806 (7)	0.019 (1)*
H4	0.6570 (1)	0.6946 (1)	0.38103 (6)	0.018 (1)*
H6	0.5571 (1)	0.4194 (1)	0.45497 (6)	0.017 (1)*
H5	0.6247 (1)	0.3674 (1)	0.37811 (6)	0.013 (1)*
H2	0.7997 (1)	0.7166 (1)	0.23412 (6)	0.018 (1)*
H1	0.7906 (1)	0.4991 (1)	0.22719 (6)	0.016 (1)*
H16	0.8358 (1)	0.3629 (1)	0.37522 (6)	0.015 (1)*
H15	0.9160 (1)	0.4704 (1)	0.44013 (6)	0.018 (1)*
H11	0.8901 (1)	0.4852 (2)	0.63685 (7)	0.029 (1)*
H12	1.0242 (1)	0.3542 (2)	0.66393 (7)	0.031 (1)*
H13	1.1046 (1)	0.2315 (2)	0.59223 (8)	0.027 (1)*
H14	1.0454 (1)	0.2536 (1)	0.50009 (7)	0.023 (1)*
H17	0.8351 (1)	0.1683 (1)	0.49877 (6)	0.019 (1)*
H18	0.7596 (1)	−0.0328 (1)	0.49999 (7)	0.021 (1)*
H19	0.6646 (1)	−0.1016 (1)	0.42010 (7)	0.019 (1)*
H20	0.6484 (1)	0.0192 (1)	0.33641 (6)	0.016 (1)*
H21	0.9908 (1)	0.0660 (2)	0.41726 (8)	0.037 (1)*
H22	1.0852 (1)	−0.0363 (2)	0.41754 (8)	0.038 (1)*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Co2	0.0094 (1)	0.0089 (1)	0.0098 (1)	−0.00041 (7)	−0.00002 (7)	−0.00090 (7)
Co1	0.0101 (1)	0.0083 (1)	0.0093 (1)	0.00068 (7)	0.00192 (7)	−0.00007 (7)
Cl2	0.0403 (3)	0.0282 (2)	0.0270 (2)	0.0046 (2)	−0.0103 (2)	0.0017 (2)
Cl1	0.0493 (3)	0.0489 (3)	0.0410 (3)	−0.0151 (3)	−0.0190 (3)	0.0102 (3)
O4	0.0188 (6)	0.0255 (6)	0.0219 (6)	−0.0022 (5)	0.0069 (5)	−0.0006 (5)
O3	0.0254 (6)	0.0118 (5)	0.0274 (6)	0.0026 (5)	0.0066 (5)	0.0001 (5)
O6	0.0262 (6)	0.0264 (6)	0.0211 (6)	0.0088 (5)	−0.0010 (5)	0.0077 (5)
O5	0.0240 (6)	0.0151 (6)	0.0307 (7)	−0.0027 (5)	−0.0026 (5)	−0.0077 (5)
O2	0.0250 (6)	0.0257 (6)	0.0144 (6)	0.0018 (5)	0.0017 (5)	0.0042 (5)
O1	0.0154 (6)	0.0341 (7)	0.0280 (7)	−0.0074 (5)	−0.0014 (5)	0.0043 (6)
C36	0.0148 (7)	0.0131 (7)	0.0159 (7)	−0.0001 (5)	−0.0018 (6)	−0.0010 (5)
C38	0.0123 (7)	0.0174 (7)	0.0160 (7)	0.0010 (6)	0.0012 (5)	−0.0038 (6)
C2	0.0092 (6)	0.0114 (6)	0.0092 (6)	−0.0008 (5)	0.0019 (5)	−0.0020 (5)
C5	0.0173 (7)	0.0121 (7)	0.0149 (7)	−0.0031 (6)	0.0032 (6)	0.0020 (6)
C35	0.0143 (7)	0.0151 (7)	0.0127 (6)	0.0007 (5)	0.0036 (5)	0.0001 (6)
C9	0.0113 (6)	0.0094 (6)	0.0134 (7)	−0.0007 (5)	0.0012 (5)	0.0006 (5)
C33	0.0178 (8)	0.0153 (7)	0.0149 (7)	0.0024 (6)	0.0050 (6)	0.0032 (6)
C24	0.0146 (7)	0.0150 (7)	0.0162 (7)	−0.0084 (6)	−0.0037 (6)	0.0035 (6)
C37	0.0126 (7)	0.0175 (7)	0.0148 (7)	−0.0007 (6)	−0.0004 (5)	0.0001 (6)
C30	0.0206 (7)	0.0089 (6)	0.0173 (7)	−0.0028 (6)	0.0014 (6)	0.0017 (6)
C1	0.0079 (6)	0.0102 (6)	0.0103 (6)	−0.0010 (5)	0.0017 (5)	−0.0024 (5)
C27	0.0108 (6)	0.0107 (6)	0.0125 (7)	−0.0015 (5)	0.0008 (5)	0.0010 (5)
C26	0.0116 (6)	0.0124 (7)	0.0142 (7)	−0.0014 (5)	−0.0008 (5)	0.0028 (6)
C6	0.0200 (8)	0.0089 (7)	0.0170 (8)	−0.0008 (5)	0.0036 (6)	−0.0002 (5)
C19	0.0138 (7)	0.0239 (8)	0.0159 (7)	−0.0077 (6)	−0.0003 (6)	0.0054 (6)
C7	0.0180 (7)	0.0111 (7)	0.0142 (7)	0.0000 (6)	0.0041 (6)	−0.0020 (5)
C16	0.0162 (7)	0.0194 (7)	0.0143 (7)	−0.0028 (6)	0.0073 (6)	0.0002 (6)
C20	0.0216 (8)	0.038 (1)	0.0136 (7)	−0.0088 (7)	0.0019 (6)	0.0055 (7)
C17	0.0187 (7)	0.0241 (8)	0.0144 (7)	−0.0053 (6)	0.0040 (6)	−0.0025 (6)
C8	0.0110 (6)	0.0112 (6)	0.0102 (6)	0.0001 (5)	0.0009 (5)	0.0004 (5)
C25	0.0149 (7)	0.0132 (7)	0.0156 (7)	−0.0043 (6)	−0.0019 (5)	0.0027 (6)
C34	0.0129 (7)	0.0124 (7)	0.0168 (7)	0.0009 (5)	0.0026 (6)	−0.0020 (6)
C18	0.0175 (7)	0.0242 (8)	0.0156 (7)	−0.0063 (6)	0.0035 (6)	−0.0004 (6)
C11	0.0172 (7)	0.0160 (7)	0.0118 (7)	−0.0009 (6)	0.0070 (5)	0.0007 (6)
C4	0.0157 (7)	0.0112 (7)	0.0117 (7)	0.0004 (6)	0.0033 (5)	−0.0004 (5)
C10	0.0149 (7)	0.0141 (7)	0.0123 (7)	−0.0008 (5)	0.0025 (5)	0.0020 (5)
C14	0.0299 (9)	0.0169 (7)	0.0213 (8)	−0.0024 (7)	0.0120 (7)	−0.0036 (7)
C32	0.0097 (6)	0.0103 (6)	0.0107 (6)	0.0016 (5)	0.0019 (5)	0.0002 (5)
C29	0.0217 (8)	0.0153 (7)	0.0148 (7)	−0.0032 (6)	−0.0008 (6)	0.0057 (6)
C15	0.0249 (8)	0.0201 (8)	0.0177 (8)	−0.0069 (7)	0.0082 (7)	−0.0039 (6)
C13	0.0261 (9)	0.0203 (8)	0.0183 (8)	0.0066 (7)	0.0078 (7)	0.0029 (6)
C23	0.0202 (8)	0.0158 (7)	0.0224 (8)	−0.0051 (6)	−0.0075 (6)	0.0019 (6)
C21	0.0230 (8)	0.040 (1)	0.0153 (8)	−0.0123 (8)	−0.0055 (6)	0.0125 (7)
C28	0.0195 (7)	0.0151 (7)	0.0127 (7)	−0.0041 (6)	−0.0036 (6)	0.0017 (6)
C3	0.0113 (6)	0.0088 (6)	0.0105 (6)	−0.0004 (5)	0.0002 (5)	−0.0006 (5)
C31	0.0152 (7)	0.0109 (7)	0.0134 (7)	−0.0012 (5)	0.0012 (5)	−0.0017 (6)
C12	0.0214 (8)	0.0215 (8)	0.0134 (7)	0.0013 (6)	0.0053 (6)	0.0006 (6)
C22	0.0215 (8)	0.0225 (8)	0.0255 (9)	−0.0082 (7)	−0.0103 (7)	0.0098 (7)
C39	0.0277 (9)	0.043 (1)	0.0224 (9)	0.0016 (9)	0.0036 (7)	−0.0016 (8)

Geometric parameters (Å, º) top

Co2—Co1	2.4524 (3)	C6—C7	1.392 (2)
Co2—C36	1.8136 (16)	C6—H3	0.960 (2)
Co2—C38	1.8305 (16)	C19—C20	1.406 (2)
Co2—C2	1.9859 (14)	C19—C18	1.434 (2)
Co2—C37	1.8120 (16)	C7—C8	1.403 (2)
Co2—C1	1.9773 (15)	C7—H4	0.989 (2)
Co1—C2	1.9731 (13)	C16—C17	1.440 (2)
Co1—C35	1.8241 (15)	C16—C11	1.413 (2)
Co1—C33	1.8081 (17)	C16—C15	1.407 (2)
Co1—C1	1.9798 (14)	C20—C21	1.388 (3)
Co1—C34	1.8193 (16)	C20—H11	0.970 (3)
Cl2—C39	1.761 (2)	C17—C18	1.201 (2)
Cl1—C39	1.758 (2)	C8—C3	1.4239 (19)
O4—C36	1.130 (2)	C25—H15	0.952 (2)
O3—C35	1.1382 (19)	C11—C10	1.489 (2)
O6—C38	1.131 (2)	C11—C12	1.396 (2)
O5—C37	1.1356 (19)	C4—C3	1.4022 (19)
O2—C34	1.142 (2)	C4—H1	0.955 (2)
O1—C33	1.135 (2)	C10—H6	0.983 (2)
C2—C1	1.346 (2)	C14—C15	1.384 (3)
C2—C3	1.4707 (19)	C14—C13	1.392 (3)
C5—C6	1.389 (2)	C14—H9	0.942 (3)
C5—C4	1.389 (2)	C32—C31	1.4072 (19)
C5—H2	0.985 (2)	C29—C28	1.389 (2)
C9—C8	1.4691 (19)	C29—H18	0.982 (2)
C9—C10	1.336 (2)	C15—H10	0.986 (2)
C9—H5	0.974 (2)	C13—C12	1.393 (2)
C24—C19	1.411 (2)	C13—H8	0.949 (2)
C24—C25	1.484 (2)	C23—C22	1.400 (2)
C24—C23	1.400 (2)	C23—H14	0.983 (2)
C30—C29	1.393 (2)	C21—C22	1.382 (3)
C30—C31	1.381 (2)	C21—H12	0.944 (3)
C30—H19	0.950 (2)	C28—H17	0.970 (3)
C1—C32	1.4703 (19)	C31—H20	0.974 (3)
C27—C26	1.4681 (19)	C12—H7	1.014 (3)
C27—C32	1.423 (2)	C22—H13	0.985 (3)
C27—C28	1.407 (2)	C39—H21	0.912 (3)
C26—C25	1.339 (2)	C39—H22	0.996 (3)
C26—H16	0.979 (2)

Co2···Co1	2.4524 (3)	C19···C17	2.635 (2)
Co2···O4	2.9426 (11)	C19···C25	2.500 (2)
Co2···O6	2.9600 (12)	C19···C25ⁱⁱⁱ	3.496 (2)
Co2···O5	2.9469 (11)	C19···C18	1.434 (2)
Co2···C36	1.8136 (16)	C19···C23	2.420 (2)
Co2···C38	1.8305 (16)	C19···C21	2.428 (2)
Co2···C2	1.9859 (14)	C19···C22	2.801 (2)
Co2···C35	3.2875 (15)	C19···H15	2.799 (2)
Co2···C37	1.8120 (16)	C19···H15ⁱⁱⁱ	2.844 (2)
Co2···C1	1.9773 (15)	C19···H11	2.053 (2)
Co2···C34	3.1947 (15)	C19···H12	3.261 (2)
Co2···C32	3.1617 (14)	C19···H14	3.304 (2)
Co2···C3	3.1577 (14)	C19···H17	3.282 (2)
Co2···C31	3.5291 (15)	C7···C8	1.403 (2)
Co2···H5	3.3028 (15)	C7···C11	3.173 (2)
Co2···H20	3.0307 (15)	C7···C4	2.768 (2)
Co1···O3	2.9613 (11)	C7···C10	3.107 (2)
Co1···O2	2.9602 (11)	C7···C3	2.423 (2)
Co1···O1	2.9423 (12)	C7···C12	3.581 (2)
Co1···C38	3.3672 (15)	C7···H3	2.067 (2)
Co1···C2	1.9731 (13)	C7···H4	0.989
Co1···C35	1.8241 (15)	C7···H5	3.344 (2)
Co1···C33	1.8081 (17)	C7···H2	3.288 (2)
Co1···C37	3.1397 (15)	C7···H13ⁱⁱⁱ	3.301 (2)
Co1···C1	1.9798 (14)	C7···H19^x	3.209 (2)
Co1···C34	1.8193 (16)	C16···C17	1.440 (2)
Co1···C4	3.5079 (15)	C16···C18	2.641 (2)
Co1···C32	3.1584 (14)	C16···C11	1.413 (2)
Co1···C3	3.1575 (14)	C16···C10	2.511 (2)
Co1···H1	3.0475 (15)	C16···C10^vi	3.593 (2)
Co1···H16	3.4868 (15)	C16···C14	2.422 (2)
Cl2···Cl1	2.9142 (7)	C16···C15	1.407 (2)
Cl2···O3	3.1917 (14)	C16···C13	2.797 (2)
Cl2···O1ⁱ	3.4021 (14)	C16···C12	2.418 (2)
Cl2···C35	3.3231 (16)	C16···H10	2.027 (2)
Cl2···C33ⁱ	3.5942 (15)	C16···H9	3.270 (2)
Cl2···C39	1.761 (2)	C16···H7	3.344 (2)
Cl2···H1ⁱ	3.2287 (15)	C16···H4	3.015 (2)
Cl2···H13ⁱⁱ	3.3139 (17)	C16···H6	2.908 (2)
Cl2···H21	2.204 (2)	C16···H6^vi	2.812 (2)
Cl2···H22	2.256 (2)	C16···H19^x	3.442 (2)
Cl1···O1	3.5731 (14)	C20···C17	3.574 (2)
Cl1···C39	1.758 (2)	C20···C25ⁱⁱⁱ	3.526 (2)
Cl1···H10ⁱⁱⁱ	2.9498 (18)	C20···C34^xi	3.411 (2)
Cl1···H2ⁱ	3.3902 (16)	C20···C18	2.467 (2)
Cl1···H14	3.009 (2)	C20···C23	2.778 (3)
Cl1···H18ⁱⁱ	3.0224 (17)	C20···C21	1.388 (3)
Cl1···H21	2.181 (2)	C20···C22	2.401 (3)
Cl1···H22	2.236 (2)	C20···H15ⁱⁱⁱ	2.767 (2)
O4···O6^iv	3.4258 (17)	C20···H11	0.970
O4···O5^v	3.0962 (16)	C20···H12	2.004 (2)
O4···C36	1.130 (2)	C20···H13	3.328 (3)
O4···C5^iv	3.370 (2)	C17···C25	3.581 (2)
O4···C15^vi	3.368 (2)	C17···C18	1.201 (2)
O4···H10^vi	2.821 (2)	C17···C11	2.467 (2)
O4···H9^vi	3.444 (2)	C17···C10	2.869 (2)
O4···H5	3.1007 (19)	C17···C15	2.475 (2)
O4···H2^iv	3.351 (2)	C17···H10	2.578 (2)
O4···H20	3.4862 (19)	C17···H6	3.099 (2)
O3···O5	3.2009 (17)	C17···H15	3.550 (2)
O3···O1ⁱ	3.0304 (16)	C17···H11	3.529 (2)
O3···C5^vii	3.3427 (18)	C8···C11	3.276 (2)
O3···C35	1.1382 (19)	C8···C4	2.438 (2)
O3···C37	3.3053 (19)	C8···C10	2.553 (2)
O3···C6^vii	3.3474 (19)	C8···C3	1.4239 (19)
O3···C20^viii	3.599 (2)	C8···H3	3.315 (2)
O3···H3^vii	2.6869 (19)	C8···H4	2.057 (2)
O3···H2^vii	2.6657 (18)	C8···H6	3.381 (2)
O3···H11^viii	2.696 (2)	C8···H5	2.0707 (19)
O3···H20	3.4339 (18)	C8···H1	3.291 (2)
O6···O5^v	3.4787 (18)	C8···H16	2.859 (2)
O6···O2	3.4687 (17)	C25···C18	2.861 (2)
O6···C36^v	3.5886 (19)	C25···C23	2.514 (2)
O6···C38	1.131 (2)	C25···C28	3.118 (2)
O6···C37^v	3.5615 (19)	C25···H16	1.948 (2)
O6···C30^v	3.554 (2)	C25···H15	0.952
O6···C34	3.5147 (19)	C25···H14	2.678 (2)
O6···C13^iv	3.531 (2)	C25···H17	2.841 (2)
O6···C31^v	3.2726 (19)	C34···C4	3.485 (2)
O6···C12^iv	3.597 (2)	C34···C21^viii	3.543 (2)
O6···H8^iv	3.316 (2)	C34···H7^iv	3.515 (2)
O6···H7^iv	3.435 (2)	C34···H1	2.703 (2)
O6···H3^iv	3.588 (2)	C34···H11^viii	3.435 (2)
O6···H4^iv	3.482 (2)	C34···H12^viii	3.569 (2)
O6···H19^v	3.147 (2)	C34···H22^ix	3.516 (2)
O6···H20^v	2.6157 (18)	C18···C11	3.545 (2)
O5···C36^iv	3.0144 (18)	C18···C10	3.579 (2)
O5···C38^iv	3.3067 (19)	C18···C15	3.585 (3)
O5···C35	3.2086 (19)	C18···H10	3.477 (2)
O5···C9^iv	3.2411 (19)	C18···H15	2.958 (2)
O5···C37	1.1356 (19)	C18···H11	2.627 (2)
O5···C8^iv	3.3448 (19)	C18···H14ⁱⁱⁱ	3.446 (2)
O5···H7^iv	3.273 (2)	C11···C10	1.489 (2)
O5···H3^vii	3.585 (2)	C11···C10^vi	3.536 (2)
O5···H5^iv	3.3809 (18)	C11···C14	2.806 (2)
O5···H20	3.212 (2)	C11···C15	2.438 (2)
O2···C38	3.4038 (18)	C11···C13	2.428 (2)
O2···C20^viii	3.446 (2)	C11···C12	1.396 (2)
O2···C34	1.142 (2)	C11···H10	3.293 (2)
O2···C13^iv	3.586 (2)	C11···H8	3.293 (2)
O2···C39^ix	3.479 (2)	C11···H7	2.102 (2)
O2···H8^iv	2.834 (2)	C11···H4	2.448 (2)
O2···H7^iv	3.253 (2)	C11···H6	2.080 (2)
O2···H1	3.0660 (19)	C11···H6^vi	2.747 (2)
O2···H17^viii	3.2743 (19)	C11···H5	3.380 (2)
O2···H22^ix	2.761 (2)	C11···H19^x	3.584 (2)
O1···C33	1.135 (2)	C4···C3	1.4022 (19)
O1···H2ⁱ	2.9197 (19)	C4···H3	3.254 (2)
O1···H1	3.5710 (19)	C4···H2	2.089 (2)
O1···H16	3.1903 (19)	C4···H1	0.955
O1···H11ⁱⁱⁱ	3.240 (2)	C4···H16	3.509 (2)
O1···H12^viii	3.420 (2)	C4···H12ⁱⁱⁱ	3.463 (2)
C36···C38	2.854 (2)	C10···C12	2.511 (2)
C36···C2	3.063 (2)	C10···H7	2.710 (2)
C36···C9	3.544 (2)	C10···H4	2.810 (2)
C36···C37	2.714 (2)	C10···H6	0.983
C36···C1	2.830 (2)	C10···H6^vi	3.516 (3)
C36···C32	3.405 (2)	C10···H5	1.953 (2)
C36···C31	3.460 (2)	C14···C15	1.384 (3)
C36···H5	2.832 (2)	C14···C13	1.392 (3)
C36···H20	3.034 (2)	C14···C12	2.409 (2)
C38···C2	2.835 (2)	C14···H10	2.108 (3)
C38···C37	2.907 (2)	C14···H9	0.942
C38···C1	3.523 (2)	C14···H9^xii	3.330 (3)
C38···C34	3.098 (2)	C14···H8	2.023 (3)
C38···C3	3.331 (2)	C14···H7	3.315 (2)
C38···H7^iv	3.328 (2)	C14···H6^vi	2.962 (2)
C38···H4^iv	3.586 (2)	C14···H18^x	3.546 (2)
C38···H1	3.589 (2)	C14···H19^x	3.153 (2)
C38···H20^v	3.390 (2)	C32···C29	2.811 (2)
C2···C35	3.543 (2)	C32···C28	2.426 (2)
C2···C9	2.9233 (19)	C32···C31	1.4072 (19)
C2···C33	2.850 (2)	C32···H5	2.7314 (19)
C2···C37	3.598 (2)	C32···H16	2.604 (2)
C2···C1	1.346 (2)	C32···H17	3.297 (2)
C2···C27	3.430 (2)	C32···H19	3.284 (2)
C2···C26	3.278 (2)	C32···H20	2.010 (2)
C2···C8	2.5309 (19)	C32···H21	3.597 (2)
C2···C34	3.052 (2)	C29···C28	1.389 (2)
C2···C4	2.473 (2)	C29···C31	2.399 (2)
C2···C32	2.698 (2)	C29···H9^vi	3.470 (2)
C2···C3	1.4707 (19)	C29···H8^vi	3.209 (2)
C2···H5	2.4864 (19)	C29···H17	2.046 (2)
C2···H1	2.598 (2)	C29···H18	0.982
C2···H16	2.519 (2)	C29···H19	2.054 (2)
C5···C6	1.389 (2)	C29···H20	3.305 (2)
C5···C7	2.409 (2)	C29···H21	3.439 (2)
C5···C8	2.826 (2)	C29···H22ⁱⁱ	3.331 (3)
C5···C4	1.389 (2)	C15···C13	2.407 (3)
C5···C3	2.436 (2)	C15···C12	2.782 (2)
C5···H3	2.025 (2)	C15···H10	0.986
C5···H4	3.303 (2)	C15···H9	2.023 (2)
C5···H2	0.985	C15···H8	3.252 (3)
C5···H1	2.046 (2)	C15···H6^vi	2.922 (2)
C5···H12ⁱⁱⁱ	3.142 (2)	C15···H18^x	3.182 (2)
C35···C33	2.810 (2)	C15···H19^x	3.221 (2)
C35···C37	2.933 (2)	C13···C12	1.393 (2)
C35···C1	2.896 (2)	C13···H10	3.325 (3)
C35···C20^viii	3.492 (2)	C13···H9	2.036 (2)
C35···C34	2.908 (2)	C13···H9^xii	3.596 (2)
C35···C32	3.470 (2)	C13···H8	0.949
C35···H3^vii	3.422 (2)	C13···H7	2.075 (2)
C35···H11^viii	2.771 (2)	C13···H6^vi	2.908 (2)
C35···H12^viii	3.580 (2)	C13···H19^x	3.290 (2)
C35···H20	3.282 (2)	C23···C21	2.408 (3)
C9···C1	3.3023 (19)	C23···C28	3.481 (2)
C9···C27	3.578 (2)	C23···C22	1.400 (2)
C9···C26	3.238 (2)	C23···H15	3.044 (2)
C9···C7	2.520 (2)	C23···H15ⁱⁱⁱ	2.839 (2)
C9···C16	3.538 (2)	C23···H12	3.276 (2)
C9···C8	1.4691 (19)	C23···H13	2.008 (2)
C9···C11	2.571 (2)	C23···H14	0.983
C9···C10	1.336 (2)	C23···H17	2.703 (2)
C9···C3	2.498 (2)	C23···H22ⁱⁱ	3.385 (3)
C9···C12	3.421 (2)	C21···C22	1.382 (3)
C9···H7	3.400 (2)	C21···H15ⁱⁱⁱ	2.751 (2)
C9···H4	2.679 (2)	C21···H11	2.060 (3)
C9···H6	1.977 (2)	C21···H12	0.944
C9···H5	0.974	C21···H13	2.122 (3)
C9···H16	2.967 (2)	C21···H14	3.291 (3)
C33···C1	2.950 (2)	C28···C31	2.765 (2)
C33···C34	2.787 (2)	C28···H8^vi	3.326 (2)
C33···C4	3.562 (2)	C28···H16	3.357 (2)
C33···C3	3.509 (2)	C28···H14	3.483 (2)
C33···H1	3.079 (2)	C28···H17	0.970
C33···H16	3.002 (2)	C28···H18	2.106 (2)
C33···H12^viii	3.274 (2)	C28···H19	3.272 (2)
C24···C24ⁱⁱⁱ	3.526 (3)	C28···H21	2.894 (2)
C24···C27	3.307 (2)	C28···H22ⁱⁱ	3.250 (2)
C24···C26	2.582 (2)	C3···H4	3.307 (2)
C24···C19	1.411 (2)	C3···H5	2.595 (2)
C24···C20	2.433 (2)	C3···H2	3.337 (2)
C24···C17	3.544 (2)	C3···H1	2.0336 (19)
C24···C25	1.484 (2)	C3···H16	2.628 (2)
C24···C25ⁱⁱⁱ	3.571 (2)	C31···H9^vi	3.571 (2)
C24···C18	2.463 (2)	C31···H3^vii	3.037 (2)
C24···C23	1.400 (2)	C31···H18	3.258 (2)
C24···C21	2.808 (2)	C31···H19	2.022 (2)
C24···C28	3.221 (2)	C31···H20	0.974
C24···C22	2.437 (2)	C12···H9	3.261 (2)
C24···H16	3.380 (2)	C12···H8	2.058 (2)
C24···H15	2.034 (2)	C12···H7	1.014
C24···H15ⁱⁱⁱ	2.875 (2)	C12···H4	2.822 (2)
C24···H11	3.299 (2)	C12···H6	3.025 (2)
C24···H13	3.278 (2)	C12···H6^vi	2.792 (2)
C24···H14	2.064 (2)	C12···H19^x	3.498 (2)
C24···H17	2.523 (2)	C22···H15ⁱⁱⁱ	2.795 (2)
C37···C1	3.125 (2)	C22···H11	3.280 (3)
C37···H7^iv	3.272 (2)	C22···H12	2.050 (3)
C37···H20	2.796 (2)	C22···H13	0.985
C30···C27	2.823 (2)	C22···H14	2.072 (3)
C30···C32	2.436 (2)	C22···H17	3.549 (2)
C30···C29	1.393 (2)	C22···H22ⁱⁱ	3.236 (3)
C30···C28	2.406 (2)	C39···H13ⁱⁱ	3.514 (3)
C30···C31	1.381 (2)	C39···H14	3.395 (3)
C30···H9^vi	3.253 (2)	C39···H17ⁱⁱ	3.541 (3)
C30···H3^vii	3.274 (2)	C39···H18ⁱⁱ	3.343 (3)
C30···H4^vii	3.257 (2)	C39···H21	0.912
C30···H13ⁱⁱ	3.475 (2)	C39···H22	0.996
C30···H17	3.277 (2)	H10···H9	2.412 (3)
C30···H18	2.024 (2)	H10···H6^vi	3.494 (2)
C30···H19	0.950	H10···H18^x	3.005 (2)
C30···H20	2.092 (2)	H9···H9^xii	2.849 (3)
C1···C27	2.544 (2)	H9···H8	2.316 (3)
C1···C26	2.944 (2)	H9···H8^xii	3.310 (2)
C1···C8	3.443 (2)	H9···H6^vi	3.541 (2)
C1···C34	3.593 (2)	H9···H18^x	3.597 (2)
C1···C32	1.4703 (19)	H9···H19^x	3.566 (2)
C1···C3	2.7033 (19)	H9···H19^vi	3.410 (2)
C1···C31	2.466 (2)	H8···H7	2.376 (2)
C1···H5	2.5340 (19)	H8···H6^vi	3.487 (2)
C1···H16	2.522 (2)	H8···H17^vi	3.274 (2)
C1···H20	2.524 (2)	H8···H18^vi	3.234 (2)
C27···C26	1.4681 (19)	H7···H4	3.141 (2)
C27···C25	2.558 (2)	H7···H6	3.177 (2)
C27···C32	1.423 (2)	H7···H6^vi	3.340 (2)
C27···C29	2.444 (2)	H3···H4	2.404 (2)
C27···C28	1.407 (2)	H3···H2	2.307 (2)
C27···C31	2.437 (2)	H3···H13ⁱⁱⁱ	3.132 (2)
C27···H5	2.935 (2)	H3···H19^x	3.019 (2)
C27···H16	2.082 (2)	H3···H20^x	2.628 (2)
C27···H15	3.357 (2)	H4···H13ⁱⁱⁱ	3.227 (2)
C27···H17	2.055 (2)	H4···H19^x	2.427 (2)
C27···H18	3.352 (2)	H6···H6^vi	3.238 (3)
C27···H20	3.280 (2)	H6···H5	2.174 (2)
C27···H21	2.970 (2)	H5···H16	2.7582 (19)
C26···C19	3.596 (2)	H2···H1	2.400 (2)
C26···C8	3.500 (2)	H2···H12ⁱⁱⁱ	3.302 (2)
C26···C25	1.339 (2)	H16···H15	2.152 (2)
C26···C32	2.494 (2)	H15···H15ⁱⁱⁱ	3.519 (3)
C26···C23	3.389 (2)	H15···H11ⁱⁱⁱ	3.278 (2)
C26···C28	2.523 (2)	H15···H12ⁱⁱⁱ	3.287 (2)
C26···C3	3.505 (2)	H15···H13ⁱⁱⁱ	3.374 (2)
C26···H5	2.958 (2)	H15···H14	3.193 (2)
C26···H16	0.979	H15···H14ⁱⁱⁱ	3.375 (2)
C26···H15	1.957 (2)	H11···H12	2.317 (3)
C26···H14	3.310 (2)	H12···H13	2.476 (3)
C26···H17	2.692 (2)	H13···H14	2.284 (2)
C26···H21	3.407 (3)	H13···H19ⁱⁱ	3.365 (2)
C6···C7	1.392 (2)	H13···H21ⁱⁱ	3.502 (3)
C6···C8	2.442 (2)	H13···H22ⁱⁱ	3.269 (3)
C6···C4	2.399 (2)	H14···H17	2.895 (2)
C6···C3	2.805 (2)	H14···H18ⁱⁱ	3.515 (2)
C6···H3	0.960	H14···H21	2.906 (3)
C6···H4	2.075 (2)	H17···H18	2.422 (2)
C6···H2	2.048 (2)	H17···H21	3.131 (2)
C6···H1	3.265 (2)	H17···H22ⁱⁱ	2.616 (3)
C6···H12ⁱⁱⁱ	3.378 (2)	H18···H19	2.315 (2)
C6···H13ⁱⁱⁱ	3.168 (2)	H18···H22ⁱⁱ	2.812 (3)
C6···H19^x	3.464 (2)	H19···H20	2.393 (2)
C6···H20^x	3.497 (2)	H21···H22	1.667
C19···C20	1.406 (2)

Co1—Co2—C36	148.16 (5)	C20—C19—C18	120.62 (15)
Co1—Co2—C38	102.69 (5)	C6—C7—C8	121.77 (13)
C36—Co2—C38	103.12 (7)	C6—C7—H4	120.37 (9)
Co1—Co2—C2	51.49 (4)	C8—C7—H4	117.61 (8)
C36—Co2—C2	107.38 (6)	C17—C16—C11	119.64 (14)
C38—Co2—C2	95.86 (6)	C17—C16—C15	120.74 (15)
Co1—Co2—C37	93.61 (5)	C11—C16—C15	119.61 (15)
C36—Co2—C37	96.93 (7)	C19—C20—C21	120.68 (17)
C38—Co2—C37	105.88 (7)	C19—C20—H11	118.39 (11)
C2—Co2—C37	142.66 (6)	C21—C20—H11	120.8 (1)
Co1—Co2—C1	51.75 (4)	C16—C17—C18	178.10 (17)
C36—Co2—C1	96.50 (6)	C9—C8—C7	122.61 (13)
C38—Co2—C1	135.39 (6)	C9—C8—C3	119.41 (13)
C2—Co2—C1	39.70 (6)	C7—C8—C3	117.97 (13)
C37—Co2—C1	111.03 (6)	C24—C25—C26	132.23 (14)
Co2—Co1—C2	51.96 (4)	C24—C25—H15	111.39 (8)
Co2—Co1—C35	99.43 (5)	C26—C25—H15	116.37 (9)
C2—Co1—C35	137.84 (6)	Co1—C34—O2	177.58 (13)
Co2—Co1—C33	149.01 (5)	C19—C18—C17	177.53 (17)
C2—Co1—C33	97.73 (6)	C16—C11—C10	119.76 (14)
C35—Co1—C33	101.36 (7)	C16—C11—C12	118.83 (14)
Co2—Co1—C1	51.65 (4)	C10—C11—C12	120.95 (14)
C2—Co1—C1	39.81 (6)	C5—C4—C3	121.54 (13)
C35—Co1—C1	99.08 (6)	C5—C4—H1	120.37 (8)
C33—Co1—C1	102.20 (6)	C3—C4—H1	117.96 (8)
Co2—Co1—C34	95.67 (5)	C9—C10—C11	130.91 (14)
C2—Co1—C34	107.09 (6)	C9—C10—H6	116.15 (9)
C35—Co1—C34	105.92 (7)	C11—C10—H6	112.93 (8)
C33—Co1—C34	100.39 (7)	C15—C14—C13	120.25 (15)
C1—Co1—C34	142.01 (6)	C15—C14—H9	119.6 (1)
Co2—C36—O4	176.47 (14)	C13—C14—H9	120.1 (1)
Co2—C38—O6	175.91 (14)	C1—C32—C27	123.12 (12)
Co2—C2—Co1	76.55 (5)	C1—C32—C31	117.95 (13)
Co2—C2—C1	69.81 (8)	C27—C32—C31	118.91 (13)
Co1—C2—C1	70.37 (8)	C30—C29—C28	119.70 (14)
Co2—C2—C3	131.4 (1)	C30—C29—H18	115.79 (9)
Co1—C2—C3	132.4 (1)	C28—C29—H18	124.38 (9)
C1—C2—C3	147.39 (14)	C16—C15—C14	120.40 (16)
C6—C5—C4	119.39 (13)	C16—C15—H10	114.7 (1)
C6—C5—H2	118.29 (8)	C14—C15—H10	124.8 (1)
C4—C5—H2	122.31 (8)	C14—C13—C12	119.80 (16)
Co1—C35—O3	176.84 (13)	C14—C13—H8	118.3 (1)
C8—C9—C10	130.99 (14)	C12—C13—H8	121.9 (1)
C8—C9—H5	114.39 (8)	C24—C23—C22	120.96 (16)
C10—C9—H5	114.58 (9)	C24—C23—H14	119.0 (1)
Co1—C33—O1	177.93 (14)	C22—C23—H14	119.80 (11)
C19—C24—C25	119.38 (14)	C20—C21—C22	120.21 (16)
C19—C24—C23	118.82 (14)	C20—C21—H12	117.3 (1)
C25—C24—C23	121.26 (14)	C22—C21—H12	122.5 (1)
Co2—C37—O5	177.49 (14)	C27—C28—C29	121.90 (14)
C29—C30—C31	119.66 (13)	C27—C28—H17	118.56 (9)
C29—C30—H19	121.29 (9)	C29—C28—H17	119.28 (9)
C31—C30—H19	119.06 (9)	C2—C3—C8	121.93 (13)
Co2—C1—Co1	76.60 (5)	C2—C3—C4	118.80 (13)
Co2—C1—C2	70.49 (9)	C8—C3—C4	119.27 (13)
Co1—C1—C2	69.83 (8)	C30—C31—C32	121.74 (14)
Co2—C1—C32	132.5 (1)	C30—C31—H20	124.37 (9)
Co1—C1—C32	132.0 (1)	C32—C31—H20	113.88 (8)
C2—C1—C32	146.72 (13)	C11—C12—C13	121.10 (16)
C26—C27—C32	119.26 (13)	C11—C12—H7	120.59 (9)
C26—C27—C28	122.66 (13)	C13—C12—H7	118.2 (1)
C32—C27—C28	118.06 (13)	C23—C22—C21	119.86 (16)
C27—C26—C25	131.23 (14)	C23—C22—H13	113.55 (11)
C27—C26—H16	115.11 (8)	C21—C22—H13	126.6 (1)
C25—C26—H16	113.43 (9)	Cl2—C39—Cl1	111.79 (11)
C5—C6—C7	120.04 (13)	Cl2—C39—H21	106.76 (7)
C5—C6—H3	117.94 (8)	Cl1—C39—H21	105.03 (7)
C7—C6—H3	121.88 (8)	Cl2—C39—H22	106.45 (7)
C24—C19—C20	119.46 (15)	Cl1—C39—H22	105.16 (7)
C24—C19—C18	119.92 (14)	H21—C39—H22	121.674

C36—Co2—Co1—C2	−56.1 (4)	C2—Co1—C1—Co2	73.9 (1)
C36—Co2—Co1—C35	89.4 (4)	C2—Co1—C1—C2	0.0 (1)
C36—Co2—Co1—C33	−42.2 (5)	C2—Co1—C1—C32	−150.2 (3)
C36—Co2—Co1—C1	−4.8 (3)	C35—Co1—C1—Co2	−94.9 (2)
C36—Co2—Co1—C34	−163.4 (4)	C35—Co1—C1—C2	−168.7 (2)
C38—Co2—Co1—C2	87.4 (2)	C35—Co1—C1—C32	41.1 (3)
C38—Co2—Co1—C35	−127.1 (2)	C33—Co1—C1—Co2	161.3 (2)
C38—Co2—Co1—C33	101.3 (2)	C33—Co1—C1—C2	87.5 (2)
C38—Co2—Co1—C1	138.7 (2)	C33—Co1—C1—C32	−62.7 (3)
C38—Co2—Co1—C34	−19.9 (2)	C34—Co1—C1—Co2	36.1 (3)
C2—Co2—Co1—C2	0.0 (1)	C34—Co1—C1—C2	−37.8 (3)
C2—Co2—Co1—C35	145.5 (1)	C34—Co1—C1—C32	172.1 (3)
C2—Co2—Co1—C33	13.9 (2)	Co2—Co1—C34—O2	7.8 (6)
C2—Co2—Co1—C1	51.3 (1)	C2—Co1—C34—O2	−44.1 (6)
C2—Co2—Co1—C34	−107.3 (1)	C35—Co1—C34—O2	109.3 (6)
C37—Co2—Co1—C2	−165.4 (2)	C33—Co1—C34—O2	−145.6 (6)
C37—Co2—Co1—C35	−19.9 (2)	C1—Co1—C34—O2	−19.9 (6)
C37—Co2—Co1—C33	−151.6 (1)	Co2—C2—C1—Co2	0.00 (2)
C37—Co2—Co1—C1	−114.1 (2)	Co2—C2—C1—Co1	82.42 (4)
C37—Co2—Co1—C34	87.3 (2)	Co2—C2—C1—C32	−139.9 (3)
C1—Co2—Co1—C2	−51.3 (1)	Co1—C2—C1—Co2	−82.42 (4)
C1—Co2—Co1—C35	94.2 (1)	Co1—C2—C1—Co1	0.00 (2)
C1—Co2—Co1—C33	−37.5 (2)	Co1—C2—C1—C32	137.6 (3)
C1—Co2—Co1—C1	0.0 (1)	C3—C2—C1—Co2	137.1 (3)
C1—Co2—Co1—C34	−158.6 (1)	C3—C2—C1—Co1	−140.4 (3)
Co1—Co2—C36—O4	−61.6 (4)	C3—C2—C1—C32	−2.8 (6)
C38—Co2—C36—O4	155.0 (4)	Co2—C2—C3—C8	84.8 (2)
C2—Co2—C36—O4	−104.5 (4)	Co2—C2—C3—C4	−95.2 (2)
C37—Co2—C36—O4	46.8 (4)	Co1—C2—C3—C8	−162.5 (1)
C1—Co2—C36—O4	−65.4 (4)	Co1—C2—C3—C4	17.5 (2)
Co1—Co2—C38—O6	−52.5 (3)	C1—C2—C3—C8	−36.9 (4)
C36—Co2—C38—O6	108.7 (3)	C1—C2—C3—C4	143.1 (3)
C2—Co2—C38—O6	−0.7 (3)	C4—C5—C6—C7	−0.3 (3)
C37—Co2—C38—O6	−150.1 (3)	C6—C5—C4—C3	−0.4 (3)
C1—Co2—C38—O6	−5.0 (3)	C10—C9—C8—C7	−1.4 (4)
Co1—Co2—C2—Co1	0.00 (2)	C10—C9—C8—C3	177.9 (2)
Co1—Co2—C2—C1	−73.7 (1)	C8—C9—C10—C11	3.7 (4)
Co1—Co2—C2—C3	135.5 (3)	C25—C24—C19—C20	−170.8 (2)
C36—Co2—C2—Co1	152.7 (2)	C25—C24—C19—C18	8.6 (3)
C36—Co2—C2—C1	79.0 (2)	C23—C24—C19—C20	0.9 (3)
C36—Co2—C2—C3	−71.8 (3)	C23—C24—C19—C18	−179.7 (2)
C38—Co2—C2—Co1	−101.6 (1)	C19—C24—C25—C26	−113.5 (3)
C38—Co2—C2—C1	−175.3 (2)	C23—C24—C25—C26	75.1 (3)
C38—Co2—C2—C3	34.0 (3)	C19—C24—C23—C22	0.2 (3)
C37—Co2—C2—Co1	24.5 (3)	C25—C24—C23—C22	171.8 (2)
C37—Co2—C2—C1	−49.3 (3)	C31—C30—C29—C28	−1.3 (3)
C37—Co2—C2—C3	160.0 (3)	C29—C30—C31—C32	0.6 (3)
C1—Co2—C2—Co1	73.7 (1)	Co2—C1—C32—C27	−151.1 (1)
C1—Co2—C2—C1	0.0 (1)	Co2—C1—C32—C31	27.3 (2)
C1—Co2—C2—C3	−150.7 (3)	Co1—C1—C32—C27	95.3 (2)
Co1—Co2—C37—O5	−9.8 (5)	Co1—C1—C32—C31	−86.3 (2)
C36—Co2—C37—O5	−159.7 (5)	C2—C1—C32—C27	−26.4 (4)
C38—Co2—C37—O5	94.5 (5)	C2—C1—C32—C31	152.0 (3)
C2—Co2—C37—O5	−28.8 (6)	C32—C27—C26—C25	171.3 (2)
C1—Co2—C37—O5	−60.0 (5)	C28—C27—C26—C25	−7.1 (4)
Co1—Co2—C1—Co1	0.00 (2)	C26—C27—C32—C1	−2.1 (3)
Co1—Co2—C1—C2	73.0 (1)	C26—C27—C32—C31	179.5 (2)
Co1—Co2—C1—C32	−135.6 (3)	C28—C27—C32—C1	176.3 (2)
C36—Co2—C1—Co1	177.5 (2)	C28—C27—C32—C31	−2.1 (3)
C36—Co2—C1—C2	−109.5 (2)	C26—C27—C28—C29	179.8 (2)
C36—Co2—C1—C32	41.9 (3)	C32—C27—C28—C29	1.4 (3)
C38—Co2—C1—Co1	−66.4 (3)	C27—C26—C25—C24	6.2 (4)
C38—Co2—C1—C2	6.7 (3)	C5—C6—C7—C8	0.3 (3)
C38—Co2—C1—C32	158.1 (2)	C24—C19—C20—C21	−1.2 (3)
C2—Co2—C1—Co1	−73.0 (1)	C18—C19—C20—C21	179.4 (2)
C2—Co2—C1—C2	0.0 (1)	C24—C19—C18—C17	51.2 (5)
C2—Co2—C1—C32	151.4 (3)	C20—C19—C18—C17	−129.4 (5)
C37—Co2—C1—Co1	77.5 (2)	C6—C7—C8—C9	179.5 (2)
C37—Co2—C1—C2	150.5 (2)	C6—C7—C8—C3	0.2 (3)
C37—Co2—C1—C32	−58.1 (3)	C11—C16—C17—C18	−5.9 (7)
Co2—Co1—C2—Co2	0.00 (2)	C15—C16—C17—C18	173.0 (7)
Co2—Co1—C2—C1	73.0 (1)	C17—C16—C11—C10	6.9 (3)
Co2—Co1—C2—C3	−134.7 (3)	C17—C16—C11—C12	179.3 (2)
C35—Co1—C2—Co2	−56.4 (3)	C15—C16—C11—C10	−172.0 (2)
C35—Co1—C2—C1	16.7 (3)	C15—C16—C11—C12	0.3 (3)
C35—Co1—C2—C3	169.0 (2)	C17—C16—C15—C14	−178.6 (2)
C33—Co1—C2—Co2	−172.8 (2)	C11—C16—C15—C14	0.3 (3)
C33—Co1—C2—C1	−99.8 (2)	C19—C20—C21—C22	0.3 (4)
C33—Co1—C2—C3	52.5 (3)	C16—C17—C18—C19	−13.8 (10)
C1—Co1—C2—Co2	−73.0 (1)	C9—C8—C3—C2	−0.2 (3)
C1—Co1—C2—C1	0.0 (1)	C9—C8—C3—C4	179.8 (2)
C1—Co1—C2—C3	152.3 (3)	C7—C8—C3—C2	179.2 (2)
C34—Co1—C2—Co2	83.7 (2)	C7—C8—C3—C4	−0.8 (3)
C34—Co1—C2—C1	156.8 (2)	C16—C11—C10—C9	−103.8 (3)
C34—Co1—C2—C3	−50.9 (3)	C12—C11—C10—C9	84.0 (3)
Co2—Co1—C35—O3	−31.3 (4)	C16—C11—C12—C13	−0.4 (3)
C2—Co1—C35—O3	10.3 (4)	C10—C11—C12—C13	171.9 (2)
C33—Co1—C35—O3	125.6 (4)	C5—C4—C3—C2	−179.1 (2)
C1—Co1—C35—O3	21.1 (4)	C5—C4—C3—C8	0.9 (3)
C34—Co1—C35—O3	−130.1 (4)	C13—C14—C15—C16	−0.8 (3)
Co2—Co1—C33—O1	−23.8 (7)	C15—C14—C13—C12	0.8 (3)
C2—Co1—C33—O1	−12.8 (7)	C1—C32—C31—C30	−177.3 (2)
C35—Co1—C33—O1	−155.0 (7)	C27—C32—C31—C30	1.1 (3)
C1—Co1—C33—O1	−53.0 (7)	C30—C29—C28—C27	0.3 (3)
C34—Co1—C33—O1	96.2 (7)	C14—C13—C12—C11	−0.2 (3)
Co2—Co1—C1—Co2	0.00 (2)	C24—C23—C22—C21	−1.1 (3)
Co2—Co1—C1—C2	−73.9 (1)	C20—C21—C22—C23	0.8 (4)
Co2—Co1—C1—C32	136.0 (3)

Symmetry codes: (i) −x+2, y−1/2, −z+1/2; (ii) −x+2, −y, −z+1; (iii) −x+2, −y+1, −z+1; (iv) −x+1, y−1/2, −z+1/2; (v) −x+1, y+1/2, −z+1/2; (vi) −x+1, −y+1, −z+1; (vii) x, y−1, z; (viii) x, −y+1/2, z−1/2; (ix) −x+2, y+1/2, −z+1/2; (x) x, y+1, z; (xi) x, −y+1/2, z+1/2; (xii) −x+1, −y+2, −z+1.

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A hexa­carbonyl­dicobalt(0) complex of a `magazine-rack' mol­ecule, [(η2-C32H20)Co2(CO)6]·CH2Cl2

Supporting information

Key indicators

checkCIF results

A hexacarbonyldicobalt(0) complex of a `magazine-rack' molecule, [(η²-C₃₂H₂₀)Co₂(CO)₆]·CH₂Cl₂