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Acta Cryst. (2002). E58, i114-i116 [ doi:10.1107/S1600536802020536 ]
Abstract: The new polyoxomolybdovanadate, hexapotassium hexamolybdodivanadate tetrahydrate, K6[Mo6V2O26]·4H2O, has been isolated from a solution of potassium molybdate and ammonium vanadate. The polyoxoanion, with crystallographically imposed 2/m symmetry, is built up of six MoO6 and two VO6 edge-sharing distorted octahedra.
Online 22 November 2002
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