Acta Cryst. (2003). E59, m6-m7  [ doi:10.1107/S1600536802022158 ]

[(R)-(+)-1,1-Binaphthyl-2,2'-diamine](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate diethyl ether disolvate

M. D. Jones, F. A. Almeida Paz, J. E. Davies and B. F. G. Johnson

Online 7 December 2002

Key indicators

• Single-crystal X-ray study
• T = 180 K
• Mean (C-C) = 0.006 Å
• R factor = 0.038
• wR factor = 0.083
• Data-to-parameter ratio = 14.8

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level B:



PLAT_360  Alert B Short  C(sp3)-C(sp3) Bond  C(35)  -   C(36)  =       1.32 Ang.

General Notes



REFLT_03                                                                        
         From the CIF: _diffrn_reflns_theta_max           25.03                 
         From the CIF: _reflns_number_total               6615                  
         Count of symmetry unique reflns         3720                           
         Completeness (_total/calc)            177.82%                          
         TEST3: Check Friedels for noncentro structure                          
         Estimate of Friedel pairs measured      2895                           
         Fraction of Friedel pairs measured     0.778                           
         Are heavy atom types Z>Si present          yes                         
          Please check that the estimate of the number of Friedel pairs is      
          correct. If it is not, please give the correct count in the           
          _publ_section_exptl_refinement section of the submitted CIF.          


 0 Alert Level A = Potentially serious problem

 1 Alert Level B = Potential problem

 0 Alert Level C = Please check

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