![[HTML version]](/e/graphics/htmlborder.gif)
![[PDF version]](/e/graphics/pdfborder.gif)
![[CIF]](/e/graphics/cifborder.gif)
![[3d view]](/e/graphics/3dviewborder.gif)
![[Structure Factors]](/e/graphics/structurefactorsborder.gif)
![[CIF check Report]](/e/graphics/checkcifborder.gif)
![[Issue contents]](/e/graphics/issuecontentsborder.gif)
![[Buy article online]](/logos/buy.gif)
Acta Cryst. (2003). E59, i14-i16 [ doi:10.1107/S160053680300117X ]
Abstract: (NH4)0.926K2.074[H(PO3F)2] crystallized from aqueous solution after mixing stoichiometric amounts of (NH4)2PO3F and K2PO3F in a 1:1 ratio. The structure contains two sites that are occupied by symmetry-independent cations; one site is occupied by potassium and ammonium in an approximate 1:1 ratio, while the other cation site is occupied exclusively by K. The anions are connected by a very short symmetry-restricted O
HO hydrogen bond (
2.47 Å) into pairs [H(PO3F)2]3-. Ammonium is connected to anion O atoms by two- and three-centred N-HO hydrogen bonds. Fluorines do not take part in the hydrogen-bond pattern.
Online 24 January 2003
Copyright © International Union of Crystallography
IUCr Webmaster