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Acta Cryst. (2003). E59, m87-m90  [ doi:10.1107/S1600536803001922 ]

Bis([mu]-8-hydroxy-7-iodoquinoline-5-sulfonato-[kappa]3N,O:O')bis[triaquazinc(II)] tetrahydrate

S. Francis, P. T. Muthiah, G. Bocelli and A. Cantoni

Abstract: In the title compound, [Zn2(C9H4INO4S)2(H2O)6]·4H2O, the coordination geometry around the ZnII atom is a distorted octahedron, formed by three water molecules, the N and deprotonated O atoms of the quinolinol ring and one of the O atoms of the sulfonate group. In the centrosymmetric binuclear complex, there is a [pi]-[pi]-stacking interaction between the quinolinol rings. The water molecules of crystallization play an important role in the hydrogen-bonding patterns of the three-dimensional network.

Online 31 January 2003


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