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Acta Cryst. (2003). E59, m55-m56 [ doi:10.1107/S1600536803000138 ]
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4-Sulfido-bis(2-phenylthiolato)tetrakis(tricarbonyliron)Abstract: The title complex, C24H10Fe4O12S3, contains two Fe2(PhS)(CO)6 subclusters connected through an inorganic spiro 4-S atom. Each iron atom is coordinated by three carbonyl C atoms [Fe-C 1.786 (9)-1.826 (9) Å], one thiophenyl S atom [Fe-S 2.267 (2)-2.286 (2) Å], one 4-S atom [Fe-S 2.235 (2)-2.249 (2) Å], and one Fe-Fe bond [2.526 (16), 2.532 (16) Å], in a distorted octahedral geometry.
Online 17 January 2003
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