Acta Cryst. (2003). E59, o124-o126  [ doi:10.1107/S1600536802023620 ]

N-[N-(Furan-2-carbonyl)hydrazinothiocarbonyl]benzamide

B. M. Yamin and M. S. M. Yusof

Abstract: The title compound, C₁₃H₁₁N₃O₃S, adopts a cis-trans conformation, where the furoyl moiety and the benzoyl group lie respectively cis and trans relative to the S atom across the thiourea C-N bonds. Both H atoms belonging to the hydrazine moiety participate in intramolecular hydrogen bonds; one of them forms an N-HO bond and closes the six-membered pseudo-ring, whereas the other one participates in N-HO and N-HS bonds, forming two five-membered pseudo-rings. The molecules in the crystal are linked by N-HO and C-HO intermolecular hydrogen bonds involving the amide and phenyl H atoms and the O atoms of the furoyl and benzoyl groups. The intermolecular hydrogen bonds give rise to infinite chains running along the c axis of the crystal.

Online 10 January 2003

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