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Acta Cryst. (2003). E59, m119-m121  [ doi:10.1107/S1600536803003386 ]

Twinned bis[tris(1,2-ethanediamine-[kappa]2N,N')manganese(II)] pentaselenodiantimonate(III)

C. Näther, F. Wendland and W. Bensch

Abstract: The crystal structure of the title compound, [Mn(C2H8N2)3]2[Sb2Se5], consists of discrete [Mn(en)3]2+ complex cations and [Sb2Se5]4- anions. There are two crystallographically independent cations and two crystallographically independent anions in the asymmetric unit. The cations occupy general positions whereas the anions are each located on a twofold axis. Between the Se atoms of the anions and the H atoms of the amino groups, short intermolecular distances are observed, which indicate hydrogen bonding.

Online 21 February 2003


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